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Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination. / Demidova, Yu S.; Suslov, E. V.; Simakova, I. L. et al.

In: Molecular Catalysis, Vol. 433, 05.2017, p. 414-419.

Research output: Contribution to journal › Article › peer-review

Harvard

Demidova, YS, Suslov, EV, Simakova, IL, Volcho, KP, Smolentseva, E, Salakhutdinov, NF, Simakov, A & Murzin, DY 2017, 'Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination', Molecular Catalysis, vol. 433, pp. 414-419. https://doi.org/10.1016/j.mcat.2017.02.040

APA

Demidova, Y. S., Suslov, E. V., Simakova, I. L., Volcho, K. P., Smolentseva, E., Salakhutdinov, N. F., Simakov, A., & Murzin, D. Y. (2017). Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination. Molecular Catalysis, 433, 414-419. https://doi.org/10.1016/j.mcat.2017.02.040

Vancouver

Demidova YS, Suslov EV, Simakova IL, Volcho KP, Smolentseva E, Salakhutdinov NF et al. Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination. Molecular Catalysis. 2017 May;433:414-419. doi: 10.1016/j.mcat.2017.02.040

Author

Demidova, Yu S. ; Suslov, E. V. ; Simakova, I. L. et al. / Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination. In: Molecular Catalysis. 2017 ; Vol. 433. pp. 414-419.

BibTeX

@article{bd1e12f69f22464481d0a0e14b691997,
title = "Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination",
abstract = "The one-pot myrtenol amination with aniline was performed over Au (3 wt.%)/ZrO2 catalyst using methanol, 2-propanol or formic acid as hydrogen donors with the aim to enhance the target amine yield. It was found that addition of small amounts of 2-propanol or formic acid (additive/myrtenol ratio equals to 0.5 and 0.25, respectively) led to the increase of the target amine yield up to 68 and 65%, respectively, compared with 52% amine yield in the absence of additives. However, further increase of additive amount decreased amine formation: 2-propanol interacted with aniline competing with myrtenol; formic acid introduction into the reaction mixture suppressed activity of Au/ZrO2 catalyst due to strong adsorption of formic acid and decomposition products on the support basic sites strongly required for the initial alcohol activation. Methanol was found not to be effective as a hydrogen donor for one-pot alcohol amination.",
keywords = "2-propanol, Formic acid, Gold, Hydrogen donor, One-pot alcohol amination, SELECTIVE N-ALKYLATION, DECOMPOSITION, 2 propanol, HETEROGENEOUS CATALYSIS, ANALGESIC ACTIVITY, SUPPORTED GOLD CATALYST, ALUMINA, AMINES, HYDROGEN-PRODUCTION, Hydrogen donora, DERIVATIVES, METAL-OXIDES",
author = "Demidova, {Yu S.} and Suslov, {E. V.} and Simakova, {I. L.} and Volcho, {K. P.} and E. Smolentseva and Salakhutdinov, {N. F.} and A. Simakov and Murzin, {D. Yu}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2017",
month = may,
doi = "10.1016/j.mcat.2017.02.040",
language = "English",
volume = "433",
pages = "414--419",
journal = "Molecular Catalysis",
issn = "2468-8231",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Promoting effect of alcohols and formic acid on Au-catalyzed one-pot myrtenol amination

AU - Demidova, Yu S.

AU - Suslov, E. V.

AU - Simakova, I. L.

AU - Volcho, K. P.

AU - Smolentseva, E.

AU - Salakhutdinov, N. F.

AU - Simakov, A.

AU - Murzin, D. Yu

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017/5

Y1 - 2017/5

N2 - The one-pot myrtenol amination with aniline was performed over Au (3 wt.%)/ZrO2 catalyst using methanol, 2-propanol or formic acid as hydrogen donors with the aim to enhance the target amine yield. It was found that addition of small amounts of 2-propanol or formic acid (additive/myrtenol ratio equals to 0.5 and 0.25, respectively) led to the increase of the target amine yield up to 68 and 65%, respectively, compared with 52% amine yield in the absence of additives. However, further increase of additive amount decreased amine formation: 2-propanol interacted with aniline competing with myrtenol; formic acid introduction into the reaction mixture suppressed activity of Au/ZrO2 catalyst due to strong adsorption of formic acid and decomposition products on the support basic sites strongly required for the initial alcohol activation. Methanol was found not to be effective as a hydrogen donor for one-pot alcohol amination.

AB - The one-pot myrtenol amination with aniline was performed over Au (3 wt.%)/ZrO2 catalyst using methanol, 2-propanol or formic acid as hydrogen donors with the aim to enhance the target amine yield. It was found that addition of small amounts of 2-propanol or formic acid (additive/myrtenol ratio equals to 0.5 and 0.25, respectively) led to the increase of the target amine yield up to 68 and 65%, respectively, compared with 52% amine yield in the absence of additives. However, further increase of additive amount decreased amine formation: 2-propanol interacted with aniline competing with myrtenol; formic acid introduction into the reaction mixture suppressed activity of Au/ZrO2 catalyst due to strong adsorption of formic acid and decomposition products on the support basic sites strongly required for the initial alcohol activation. Methanol was found not to be effective as a hydrogen donor for one-pot alcohol amination.

KW - 2-propanol

KW - Formic acid

KW - Gold

KW - Hydrogen donor

KW - One-pot alcohol amination

KW - SELECTIVE N-ALKYLATION

KW - DECOMPOSITION

KW - 2 propanol

KW - HETEROGENEOUS CATALYSIS

KW - ANALGESIC ACTIVITY

KW - SUPPORTED GOLD CATALYST

KW - ALUMINA

KW - AMINES

KW - HYDROGEN-PRODUCTION

KW - Hydrogen donora

KW - DERIVATIVES

KW - METAL-OXIDES

UR - http://www.scopus.com/inward/record.url?scp=85029626878&partnerID=8YFLogxK

U2 - 10.1016/j.mcat.2017.02.040

DO - 10.1016/j.mcat.2017.02.040

M3 - Article

AN - SCOPUS:85029626878

VL - 433

SP - 414

EP - 419

JO - Molecular Catalysis

JF - Molecular Catalysis

SN - 2468-8231

ER -

ID: 8968286