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Production of hydrogen-rich gas by oxidative steam reforming of dimethoxymethane over CuO-CeO2/γ-Al2O3 catalyst. / Badmaev, Sukhe; Sobyanin, Vladimir.

In: Energies, Vol. 13, No. 14, 3684, 17.07.2020.

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@article{7223ccc77a194f42aaf5e8dd3016d376,
title = "Production of hydrogen-rich gas by oxidative steam reforming of dimethoxymethane over CuO-CeO2/γ-Al2O3 catalyst",
abstract = "The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h-1 gcat-1 at 280 ◦C, GHSV (gas hourly space velocity) = 15,000 h-1 and DMM:O2:H2O:N2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.",
keywords = "Copper catalyst, CuO-CeO/γ-AlO, Dimethoxymethane, Fuel cell, Hydrogen production, Oxidative steam reforming, Partial oxidation, dimethoxymethane, gamma-Al2O3, METHANOL, CuO-CeO2, oxidative steam reforming, PERFORMANCE, DIMETHYL ETHER, partial oxidation, FUEL-CELLS, STATE, H-2, hydrogen production, fuel cell, CUZNAL CATALYSTS, SELECTIVE PRODUCTION, copper catalyst, FEEDSTOCKS",
author = "Sukhe Badmaev and Vladimir Sobyanin",
year = "2020",
month = jul,
day = "17",
doi = "10.3390/en13143684",
language = "English",
volume = "13",
journal = "Energies",
issn = "1996-1073",
publisher = "MDPI AG",
number = "14",

}

RIS

TY - JOUR

T1 - Production of hydrogen-rich gas by oxidative steam reforming of dimethoxymethane over CuO-CeO2/γ-Al2O3 catalyst

AU - Badmaev, Sukhe

AU - Sobyanin, Vladimir

PY - 2020/7/17

Y1 - 2020/7/17

N2 - The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h-1 gcat-1 at 280 ◦C, GHSV (gas hourly space velocity) = 15,000 h-1 and DMM:O2:H2O:N2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.

AB - The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h-1 gcat-1 at 280 ◦C, GHSV (gas hourly space velocity) = 15,000 h-1 and DMM:O2:H2O:N2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.

KW - Copper catalyst

KW - CuO-CeO/γ-AlO

KW - Dimethoxymethane

KW - Fuel cell

KW - Hydrogen production

KW - Oxidative steam reforming

KW - Partial oxidation

KW - dimethoxymethane

KW - gamma-Al2O3

KW - METHANOL

KW - CuO-CeO2

KW - oxidative steam reforming

KW - PERFORMANCE

KW - DIMETHYL ETHER

KW - partial oxidation

KW - FUEL-CELLS

KW - STATE

KW - H-2

KW - hydrogen production

KW - fuel cell

KW - CUZNAL CATALYSTS

KW - SELECTIVE PRODUCTION

KW - copper catalyst

KW - FEEDSTOCKS

UR - http://www.scopus.com/inward/record.url?scp=85089822164&partnerID=8YFLogxK

U2 - 10.3390/en13143684

DO - 10.3390/en13143684

M3 - Article

AN - SCOPUS:85089822164

VL - 13

JO - Energies

JF - Energies

SN - 1996-1073

IS - 14

M1 - 3684

ER -

ID: 25288212