Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural

Standard

Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural. / Selishcheva, S. A.; Smirnov, A. A.; Fedorov, A. V. et al.

In: Catalysis in Industry, Vol. 11, No. 3, 01.07.2019, p. 216-223.

Research output: Contribution to journal › Article › peer-review

Harvard

Selishcheva, SA, Smirnov, AA, Fedorov, AV, Ermakov, DY, Gulyaeva, YK & Yakovlev, VA 2019, 'Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural', Catalysis in Industry, vol. 11, no. 3, pp. 216-223. https://doi.org/10.1134/S2070050419030103

APA

Selishcheva, S. A., Smirnov, A. A., Fedorov, A. V., Ermakov, D. Y., Gulyaeva, Y. K., & Yakovlev, V. A. (2019). Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural. Catalysis in Industry, 11(3), 216-223. https://doi.org/10.1134/S2070050419030103

Vancouver

Selishcheva SA, Smirnov AA, Fedorov AV, Ermakov DY, Gulyaeva YK, Yakovlev VA. Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural. Catalysis in Industry. 2019 Jul 1;11(3):216-223. doi: 10.1134/S2070050419030103

Author

Selishcheva, S. A. ; Smirnov, A. A. ; Fedorov, A. V. et al. / Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural. In: Catalysis in Industry. 2019 ; Vol. 11, No. 3. pp. 216-223.

BibTeX

@article{39196bc913ac4239a536f8cbcc9d1df5,

title = "Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural",

abstract = "Cu- and Fe-containing catalysts are studied in the reaction of selective hydrogenation of furfural to furfuryl alcohol (FA). The catalysts are prepared by alloying the respective metal nitrates and reduced before the reaction directly in the reactor at 250°C. The process is conducted in a batch reactor at 150°C and 6.0 MPa of hydrogen pressure. It is shown that the most active catalyst is Cu20Fe66Al14, the furfural conversion and selectivity toward FA in the presence of which are 96 and 97 mol %, respectively. Inside a continuous-flow reactor in the presence of this catalyst, 100% furfural conversion can be attained at a selectivity toward FA of up to 95 mol % at 160°C and 5 MPa of hydrogen pressure. The resulting catalyst remains active for 30 h of continuous operation. The high activity of the copper–iron catalyst is likely due to the presence of stabilized finely divided copper particles in it.",

keywords = "copper–iron catalysts, furfural, furfuryl alcohol, hydrogenation, copper-iron catalysts, CONVERSION, CO",

author = "Selishcheva, {S. A.} and Smirnov, {A. A.} and Fedorov, {A. V.} and Ermakov, {D. Yu} and Gulyaeva, {Yu K.} and Yakovlev, {V. A.}",

year = "2019",

month = jul,

day = "1",

doi = "10.1134/S2070050419030103",

language = "English",

volume = "11",

pages = "216--223",

journal = "Catalysis in Industry",

issn = "2070-0504",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "3",

}

RIS

TY - JOUR

T1 - Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural

AU - Selishcheva, S. A.

AU - Smirnov, A. A.

AU - Fedorov, A. V.

AU - Ermakov, D. Yu

AU - Gulyaeva, Yu K.

AU - Yakovlev, V. A.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Cu- and Fe-containing catalysts are studied in the reaction of selective hydrogenation of furfural to furfuryl alcohol (FA). The catalysts are prepared by alloying the respective metal nitrates and reduced before the reaction directly in the reactor at 250°C. The process is conducted in a batch reactor at 150°C and 6.0 MPa of hydrogen pressure. It is shown that the most active catalyst is Cu20Fe66Al14, the furfural conversion and selectivity toward FA in the presence of which are 96 and 97 mol %, respectively. Inside a continuous-flow reactor in the presence of this catalyst, 100% furfural conversion can be attained at a selectivity toward FA of up to 95 mol % at 160°C and 5 MPa of hydrogen pressure. The resulting catalyst remains active for 30 h of continuous operation. The high activity of the copper–iron catalyst is likely due to the presence of stabilized finely divided copper particles in it.

AB - Cu- and Fe-containing catalysts are studied in the reaction of selective hydrogenation of furfural to furfuryl alcohol (FA). The catalysts are prepared by alloying the respective metal nitrates and reduced before the reaction directly in the reactor at 250°C. The process is conducted in a batch reactor at 150°C and 6.0 MPa of hydrogen pressure. It is shown that the most active catalyst is Cu20Fe66Al14, the furfural conversion and selectivity toward FA in the presence of which are 96 and 97 mol %, respectively. Inside a continuous-flow reactor in the presence of this catalyst, 100% furfural conversion can be attained at a selectivity toward FA of up to 95 mol % at 160°C and 5 MPa of hydrogen pressure. The resulting catalyst remains active for 30 h of continuous operation. The high activity of the copper–iron catalyst is likely due to the presence of stabilized finely divided copper particles in it.

KW - copper–iron catalysts

KW - furfural

KW - furfuryl alcohol

KW - hydrogenation

KW - copper-iron catalysts

KW - CONVERSION

KW - CO

UR - http://www.scopus.com/inward/record.url?scp=85073189369&partnerID=8YFLogxK

U2 - 10.1134/S2070050419030103

DO - 10.1134/S2070050419030103

M3 - Article

AN - SCOPUS:85073189369

VL - 11

SP - 216

EP - 223

JO - Catalysis in Industry

JF - Catalysis in Industry

SN - 2070-0504

IS - 3

ER -

ID: 21861147