Research output: Contribution to journal › Article › peer-review
Prereforming of Arctic Diesel Fuel into Syngas. / Samoilov, A. V.; Kirillov, V. A.; Shigarov, A. B. et al.
In: Catalysis in Industry, Vol. 10, No. 4, 01.10.2018, p. 321-327.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Prereforming of Arctic Diesel Fuel into Syngas
AU - Samoilov, A. V.
AU - Kirillov, V. A.
AU - Shigarov, A. B.
AU - Brayko, A. S.
AU - Potemkin, D. I.
AU - Shoinkhorova, T. B.
AU - Snytnikov, P. V.
AU - Uskov, S. I.
AU - Pechenkin, A. A.
AU - Belyaev, V. D.
AU - Sobyanin, V. A.
PY - 2018/10/1
Y1 - 2018/10/1
N2 - The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.
AB - The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.
KW - diesel
KW - magnesium oxide
KW - nickel
KW - prereforming
KW - syngas
KW - LIQUID HYDROCARBONS
KW - METHANE
KW - CATALYST
UR - http://www.scopus.com/inward/record.url?scp=85060173753&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/757fa72f-2671-33cf-991c-70dc0605867f/
U2 - 10.1134/S207005041804013X
DO - 10.1134/S207005041804013X
M3 - Article
AN - SCOPUS:85060173753
VL - 10
SP - 321
EP - 327
JO - Catalysis in Industry
JF - Catalysis in Industry
SN - 2070-0504
IS - 4
ER -
ID: 18290714