Standard

Porous nickel-based catalysts for tri-reforming of methane to synthesis gas : Preparation and characterization. / Fedorova, Z. A.; Danilova, M. M.; Zaikovskii, V. I. et al.

In: Materials Letters, Vol. 263, 127156, 15.03.2020.

Research output: Contribution to journalArticlepeer-review

Harvard

APA

Vancouver

Fedorova ZA, Danilova MM, Zaikovskii VI, Krieger TA. Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Preparation and characterization. Materials Letters. 2020 Mar 15;263:127156. doi: 10.1016/j.matlet.2019.127156

Author

BibTeX

@article{0cb29ca9eebd4fea9a429a9255193c46,
title = "Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Preparation and characterization",
abstract = "The effect of synthesis conditions on the phase composition and texture of porous nickel ribbon with a MgO underlayer and of nickel catalysts supported on it was studied. The MgO underlayer was prepared by impregnation of a nickel ribbon with a Mg(NO3)2 or Mg(CH3COO)2 water solutions and subsequent calcination at 750 °C in H2. The formation of more dispersed MgO was observed with the use of Mg(NO3)2 as precursor. Catalysts were prepared by supporting of nickel onto nickel ribbon with MgO underlayer by its impregnation with a mixture of solutions of Ni(NO3)2 and Mg(NO3)2 followed by thermal pre-treatment in N2 or in He. Under reduction the formation of highly dispersed nickel crystallites (3–5 nm) epitaxially bound to MgO was observed in the catalysts with MgO underlayer prepared from Mg(NO3)2 with thermal pre-treatment of the precursor of active component in N2 or He. The supported nickel catalysts showed stable activity in tri-reforming of methane throughout the test period (9 h).",
keywords = "Epitaxy, MgO underlayer, Nickel catalysts, Solid solution, HYDROGEN, STEAM, SYNGAS",
author = "Fedorova, {Z. A.} and Danilova, {M. M.} and Zaikovskii, {V. I.} and Krieger, {T. A.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2020",
month = mar,
day = "15",
doi = "10.1016/j.matlet.2019.127156",
language = "English",
volume = "263",
journal = "Materials Letters",
issn = "0167-577X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Porous nickel-based catalysts for tri-reforming of methane to synthesis gas

T2 - Preparation and characterization

AU - Fedorova, Z. A.

AU - Danilova, M. M.

AU - Zaikovskii, V. I.

AU - Krieger, T. A.

N1 - Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2020/3/15

Y1 - 2020/3/15

N2 - The effect of synthesis conditions on the phase composition and texture of porous nickel ribbon with a MgO underlayer and of nickel catalysts supported on it was studied. The MgO underlayer was prepared by impregnation of a nickel ribbon with a Mg(NO3)2 or Mg(CH3COO)2 water solutions and subsequent calcination at 750 °C in H2. The formation of more dispersed MgO was observed with the use of Mg(NO3)2 as precursor. Catalysts were prepared by supporting of nickel onto nickel ribbon with MgO underlayer by its impregnation with a mixture of solutions of Ni(NO3)2 and Mg(NO3)2 followed by thermal pre-treatment in N2 or in He. Under reduction the formation of highly dispersed nickel crystallites (3–5 nm) epitaxially bound to MgO was observed in the catalysts with MgO underlayer prepared from Mg(NO3)2 with thermal pre-treatment of the precursor of active component in N2 or He. The supported nickel catalysts showed stable activity in tri-reforming of methane throughout the test period (9 h).

AB - The effect of synthesis conditions on the phase composition and texture of porous nickel ribbon with a MgO underlayer and of nickel catalysts supported on it was studied. The MgO underlayer was prepared by impregnation of a nickel ribbon with a Mg(NO3)2 or Mg(CH3COO)2 water solutions and subsequent calcination at 750 °C in H2. The formation of more dispersed MgO was observed with the use of Mg(NO3)2 as precursor. Catalysts were prepared by supporting of nickel onto nickel ribbon with MgO underlayer by its impregnation with a mixture of solutions of Ni(NO3)2 and Mg(NO3)2 followed by thermal pre-treatment in N2 or in He. Under reduction the formation of highly dispersed nickel crystallites (3–5 nm) epitaxially bound to MgO was observed in the catalysts with MgO underlayer prepared from Mg(NO3)2 with thermal pre-treatment of the precursor of active component in N2 or He. The supported nickel catalysts showed stable activity in tri-reforming of methane throughout the test period (9 h).

KW - Epitaxy

KW - MgO underlayer

KW - Nickel catalysts

KW - Solid solution

KW - HYDROGEN

KW - STEAM

KW - SYNGAS

UR - http://www.scopus.com/inward/record.url?scp=85076878791&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2019.127156

DO - 10.1016/j.matlet.2019.127156

M3 - Article

AN - SCOPUS:85076878791

VL - 263

JO - Materials Letters

JF - Materials Letters

SN - 0167-577X

M1 - 127156

ER -

ID: 23054503