Research output: Contribution to journal › Article › peer-review
Polymorphism in SmSc3(BO3)4: Crystal structure, luminescent and SHG properties. / Kuznetsov, Artem B.; Kokh, Konstantin A.; Kononova, Nadezda G. et al.
In: Journal of Alloys and Compounds, Vol. 851, 156825, 15.01.2021.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Polymorphism in SmSc3(BO3)4: Crystal structure, luminescent and SHG properties
AU - Kuznetsov, Artem B.
AU - Kokh, Konstantin A.
AU - Kononova, Nadezda G.
AU - Shevchenko, Vyacheslav S.
AU - Rashchenko, Sergey V.
AU - Ezhov, Dmitry M.
AU - Jamous, Ammar Y.
AU - Bolatov, Asset
AU - Uralbekov, Bolat
AU - Svetlichnyi, Valery A.
AU - Kokh, Aleksander E.
N1 - Publisher Copyright: © 2020 Elsevier B.V.
PY - 2021/1/15
Y1 - 2021/1/15
N2 - Low temperature C2/c and high temperature P321 modifications of SmxSc4-x (BO3)4 solid solutions were grown from LiBO2–LiF flux. These borates have typical luminescence for Sm3+ containing crystals with the two strongest peaks at 602 and 645 nm, which correspond to 4G5∕2 → 6H7∕2, 6H5∕2 electron transitions. In addition, the compounds were characterized by IR and Raman spectroscopy. SHG intensity for trigonal modification was found to be three times higher than that of KDP revealing its high potential for various NLO applications.
AB - Low temperature C2/c and high temperature P321 modifications of SmxSc4-x (BO3)4 solid solutions were grown from LiBO2–LiF flux. These borates have typical luminescence for Sm3+ containing crystals with the two strongest peaks at 602 and 645 nm, which correspond to 4G5∕2 → 6H7∕2, 6H5∕2 electron transitions. In addition, the compounds were characterized by IR and Raman spectroscopy. SHG intensity for trigonal modification was found to be three times higher than that of KDP revealing its high potential for various NLO applications.
KW - Crystal growth
KW - Luminescence
KW - Rare earth borate
KW - SHG
KW - Solid state synthesis
KW - Structure
KW - COOPERATIVE OPTICAL-TRANSITIONS
KW - UV
KW - SERIES
KW - SPECTROSCOPIC PROPERTIES
KW - DOPED INORGANIC MATERIALS
KW - GLASS
KW - ALKALINE-EARTH
KW - GROWTH
KW - ENERGY-TRANSFER
UR - http://www.scopus.com/inward/record.url?scp=85090004994&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2020.156825
DO - 10.1016/j.jallcom.2020.156825
M3 - Article
AN - SCOPUS:85090004994
VL - 851
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
M1 - 156825
ER -
ID: 25288411