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Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores. / Ishchenko, Roman A.; Kargapolova, Irina Yu; Orlova, Natalia et al.

In: Journal of Fluorine Chemistry, Vol. 248, 109841, 08.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Ishchenko, RA, Kargapolova, IY, Orlova, N, Shelkovnikov, VV, Maksimov, A, Ryazanov, ND, Berezhnaya, VN & Chernonosov, A 2021, 'Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores', Journal of Fluorine Chemistry, vol. 248, 109841. https://doi.org/10.1016/j.jfluchem.2021.109841

APA

Ishchenko, R. A., Kargapolova, I. Y., Orlova, N., Shelkovnikov, V. V., Maksimov, A., Ryazanov, N. D., Berezhnaya, V. N., & Chernonosov, A. (2021). Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores. Journal of Fluorine Chemistry, 248, [109841]. https://doi.org/10.1016/j.jfluchem.2021.109841

Vancouver

Ishchenko RA, Kargapolova IY, Orlova N, Shelkovnikov VV, Maksimov A, Ryazanov ND et al. Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores. Journal of Fluorine Chemistry. 2021 Aug;248:109841. doi: 10.1016/j.jfluchem.2021.109841

Author

Ishchenko, Roman A. ; Kargapolova, Irina Yu ; Orlova, Natalia et al. / Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores. In: Journal of Fluorine Chemistry. 2021 ; Vol. 248.

BibTeX

@article{b2e0c471528840c68a435a3ef32d0b4b,
title = "Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores",
abstract = "A series of novel donor-acceptor chromophores were synthesized using formylated derivatives of polyfluorinated triarylpyrazolines with branched moieties as donor blocks and dicyanoisophorone as acceptor. The nucleophilic substitution of fluorine with 4-hydroxypiperidine in decafluoropyrazoline was used to further functionalize the chromophore molecule. An existing method for introducing the dendroid moiety was improved. The properties of the final chromophores were estimated by DFT calculations.",
keywords = "Dendroid moieties, DFT calculations, Donor-acceptor chromophores, Polyfluorinated pyrazolines, UV/Vis-spectra",
author = "Ishchenko, {Roman A.} and Kargapolova, {Irina Yu} and Natalia Orlova and Shelkovnikov, {Vladimir V.} and Alexander Maksimov and Ryazanov, {Nikita D.} and Berezhnaya, {Viktoria N.} and Alexander Chernonosov",
note = "Funding Information: Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements and Information Technology Center of Novosibirsk State University for computational resources to perform quantum chemistry calculations. Publisher Copyright: {\textcopyright} 2021",
year = "2021",
month = aug,
doi = "10.1016/j.jfluchem.2021.109841",
language = "English",
volume = "248",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores

AU - Ishchenko, Roman A.

AU - Kargapolova, Irina Yu

AU - Orlova, Natalia

AU - Shelkovnikov, Vladimir V.

AU - Maksimov, Alexander

AU - Ryazanov, Nikita D.

AU - Berezhnaya, Viktoria N.

AU - Chernonosov, Alexander

N1 - Funding Information: Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements and Information Technology Center of Novosibirsk State University for computational resources to perform quantum chemistry calculations. Publisher Copyright: © 2021

PY - 2021/8

Y1 - 2021/8

N2 - A series of novel donor-acceptor chromophores were synthesized using formylated derivatives of polyfluorinated triarylpyrazolines with branched moieties as donor blocks and dicyanoisophorone as acceptor. The nucleophilic substitution of fluorine with 4-hydroxypiperidine in decafluoropyrazoline was used to further functionalize the chromophore molecule. An existing method for introducing the dendroid moiety was improved. The properties of the final chromophores were estimated by DFT calculations.

AB - A series of novel donor-acceptor chromophores were synthesized using formylated derivatives of polyfluorinated triarylpyrazolines with branched moieties as donor blocks and dicyanoisophorone as acceptor. The nucleophilic substitution of fluorine with 4-hydroxypiperidine in decafluoropyrazoline was used to further functionalize the chromophore molecule. An existing method for introducing the dendroid moiety was improved. The properties of the final chromophores were estimated by DFT calculations.

KW - Dendroid moieties

KW - DFT calculations

KW - Donor-acceptor chromophores

KW - Polyfluorinated pyrazolines

KW - UV/Vis-spectra

UR - http://www.scopus.com/inward/record.url?scp=85110104516&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2021.109841

DO - 10.1016/j.jfluchem.2021.109841

M3 - Article

AN - SCOPUS:85110104516

VL - 248

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

M1 - 109841

ER -

ID: 33981113