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Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4. / Mikheylis, A. V.; Grivin, V. P.; Pozdnyakov, I. P. et al.

In: High Energy Chemistry, Vol. 57, No. Suppl 3, 12.2023, p. S433-S440.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikheylis, AV, Grivin, VP, Pozdnyakov, IP, Melnikov, AA, Melnikov, AR, Sadykov, EK & Artem’ev, AV 2023, 'Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4', High Energy Chemistry, vol. 57, no. Suppl 3, pp. S433-S440. https://doi.org/10.1134/S0018143923090096

APA

Mikheylis, A. V., Grivin, V. P., Pozdnyakov, I. P., Melnikov, A. A., Melnikov, A. R., Sadykov, E. K., & Artem’ev, A. V. (2023). Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4. High Energy Chemistry, 57(Suppl 3), S433-S440. https://doi.org/10.1134/S0018143923090096

Vancouver

Mikheylis AV, Grivin VP, Pozdnyakov IP, Melnikov AA, Melnikov AR, Sadykov EK et al. Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4. High Energy Chemistry. 2023 Dec;57(Suppl 3):S433-S440. doi: 10.1134/S0018143923090096

Author

Mikheylis, A. V. ; Grivin, V. P. ; Pozdnyakov, I. P. et al. / Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4. In: High Energy Chemistry. 2023 ; Vol. 57, No. Suppl 3. pp. S433-S440.

BibTeX

@article{2147b4be9d724de7bb857ab519fc3f38,
title = "Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4",
abstract = "The nature of the photoprocess for a Ni(Se2P(C6H5)2)2 = Ni(dsepi)2 complex in CCl4 and CH3CN has been determined by the EPR, steady-state and time-resolved optical spectroscopy methods. In both cases, the ultrafast relaxation of the excited state of Ni(dsepi)2 molecules are observed; however, the occurrence of a photochemical reaction, in addition to the above process, has been detected in CCl4 solutions. The photolysis mechanism of Ni(dsepi)2 includes the ClNi(dsepi)(•dsepi) species formation stage initiated by electron transfer from the photoexcited complex to the halocarbon and subsequent fast reactions involving these intermediates. The final products of the photoreaction are the ((C6H5)2PSe)Se2 diselenide and the NiCl2 salt.",
author = "Mikheylis, {A. V.} and Grivin, {V. P.} and Pozdnyakov, {I. P.} and Melnikov, {A. A.} and Melnikov, {A. R.} and Sadykov, {E. Kh} and Artem{\textquoteright}ev, {A. V.}",
note = "This work was supported by the Russian Science Foundation, project no. 23-13-00226. Публикация для корректировки.",
year = "2023",
month = dec,
doi = "10.1134/S0018143923090096",
language = "English",
volume = "57",
pages = "S433--S440",
journal = "High Energy Chemistry",
issn = "0018-1439",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "Suppl 3",

}

RIS

TY - JOUR

T1 - Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4

AU - Mikheylis, A. V.

AU - Grivin, V. P.

AU - Pozdnyakov, I. P.

AU - Melnikov, A. A.

AU - Melnikov, A. R.

AU - Sadykov, E. Kh

AU - Artem’ev, A. V.

N1 - This work was supported by the Russian Science Foundation, project no. 23-13-00226. Публикация для корректировки.

PY - 2023/12

Y1 - 2023/12

N2 - The nature of the photoprocess for a Ni(Se2P(C6H5)2)2 = Ni(dsepi)2 complex in CCl4 and CH3CN has been determined by the EPR, steady-state and time-resolved optical spectroscopy methods. In both cases, the ultrafast relaxation of the excited state of Ni(dsepi)2 molecules are observed; however, the occurrence of a photochemical reaction, in addition to the above process, has been detected in CCl4 solutions. The photolysis mechanism of Ni(dsepi)2 includes the ClNi(dsepi)(•dsepi) species formation stage initiated by electron transfer from the photoexcited complex to the halocarbon and subsequent fast reactions involving these intermediates. The final products of the photoreaction are the ((C6H5)2PSe)Se2 diselenide and the NiCl2 salt.

AB - The nature of the photoprocess for a Ni(Se2P(C6H5)2)2 = Ni(dsepi)2 complex in CCl4 and CH3CN has been determined by the EPR, steady-state and time-resolved optical spectroscopy methods. In both cases, the ultrafast relaxation of the excited state of Ni(dsepi)2 molecules are observed; however, the occurrence of a photochemical reaction, in addition to the above process, has been detected in CCl4 solutions. The photolysis mechanism of Ni(dsepi)2 includes the ClNi(dsepi)(•dsepi) species formation stage initiated by electron transfer from the photoexcited complex to the halocarbon and subsequent fast reactions involving these intermediates. The final products of the photoreaction are the ((C6H5)2PSe)Se2 diselenide and the NiCl2 salt.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85186117109&origin=inward&txGid=758bfe602e8657ddfc74790826a3f0e6

UR - https://www.mendeley.com/catalogue/65884da1-7bb5-34c0-acf6-7dd2b6759297/

U2 - 10.1134/S0018143923090096

DO - 10.1134/S0018143923090096

M3 - Article

VL - 57

SP - S433-S440

JO - High Energy Chemistry

JF - High Energy Chemistry

SN - 0018-1439

IS - Suppl 3

ER -

ID: 59727608