Research output: Contribution to journal › Article › peer-review
Photooxidation of p-arsanilic acid in aqueous solution by UV/persulfate process. / Shen, Xiangyi; Xu, Jing; Pozdnyakov, Ivan P. et al.
In: Applied Sciences (Switzerland), Vol. 8, No. 4, 615, 13.04.2018.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Photooxidation of p-arsanilic acid in aqueous solution by UV/persulfate process
AU - Shen, Xiangyi
AU - Xu, Jing
AU - Pozdnyakov, Ivan P.
AU - Liu, Zizheng
N1 - Publisher Copyright: © 2018 by the authors.
PY - 2018/4/13
Y1 - 2018/4/13
N2 - Used as a kind of feed additive, p-arsanilic acid can pose a potential risk to organisms when abandoned in the environment. The photodegradation of p-ASA was investigated under UV-C irradiation in the presence of persulfate (PS) in this work. The addition of PS facilitated the decomposition of p-ASA and notably, the presence of 50 mmol PS brought about a nearly complete mineralization after 3 h, while an insignificant total organic carbon (TOC) removal was observed under UV irradiation (λ = 254 nm) only. Experimental results proved that sulfate radical (SO4•-) was responsible for the promotion effect. The cleavage of As-C bond released inorganic arsenic and caused the occurrence of various organic products, for example, hydroxybenzaldehyde, nitrobenzene, benzenediol sulfate, and biphenylarsinic acid. The application of PS with UV-C light may throw a light on thorough treatment for p-ASA containing wastewater.
AB - Used as a kind of feed additive, p-arsanilic acid can pose a potential risk to organisms when abandoned in the environment. The photodegradation of p-ASA was investigated under UV-C irradiation in the presence of persulfate (PS) in this work. The addition of PS facilitated the decomposition of p-ASA and notably, the presence of 50 mmol PS brought about a nearly complete mineralization after 3 h, while an insignificant total organic carbon (TOC) removal was observed under UV irradiation (λ = 254 nm) only. Experimental results proved that sulfate radical (SO4•-) was responsible for the promotion effect. The cleavage of As-C bond released inorganic arsenic and caused the occurrence of various organic products, for example, hydroxybenzaldehyde, nitrobenzene, benzenediol sulfate, and biphenylarsinic acid. The application of PS with UV-C light may throw a light on thorough treatment for p-ASA containing wastewater.
KW - P-arsanilic acid
KW - Photodegradation
KW - Sulfate radical
KW - UV/persulfate system
KW - photodegradation
KW - p-arsanilic acid
KW - HETEROGENEOUS CATALYSIS
KW - MASS-SPECTROMETRY
KW - ADVANCED OXIDATION PROCESSES
KW - POULTRY LITTER
KW - KINETICS
KW - PHOTODEGRADATION
KW - DEGRADATION
KW - BISPHENOL-A
KW - sulfate radical
KW - ACTIVATED PERSULFATE
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85045636202&partnerID=8YFLogxK
U2 - 10.3390/app8040615
DO - 10.3390/app8040615
M3 - Article
AN - SCOPUS:85045636202
VL - 8
JO - Applied Sciences (Switzerland)
JF - Applied Sciences (Switzerland)
SN - 2076-3417
IS - 4
M1 - 615
ER -
ID: 12690868