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Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile. / Grivin, Vjacheslav P.; Matveeva, Svetlana G.; Fedunov, Roman G. et al.

In: Photochemical and Photobiological Sciences, Vol. 23, No. 4, 04.2024, p. 747-755.

Research output: Contribution to journal › Article › peer-review

Harvard

Grivin, VP, Matveeva, SG, Fedunov, RG, Yanshole, VV, Vasilchenko, DB & Glebov, EM 2024, 'Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile', Photochemical and Photobiological Sciences, vol. 23, no. 4, pp. 747-755. https://doi.org/10.1007/s43630-024-00550-5

APA

Grivin, V. P., Matveeva, S. G., Fedunov, R. G., Yanshole, V. V., Vasilchenko, D. B., & Glebov, E. M. (2024). Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile. Photochemical and Photobiological Sciences, 23(4), 747-755. https://doi.org/10.1007/s43630-024-00550-5

Vancouver

Grivin VP, Matveeva SG, Fedunov RG, Yanshole VV, Vasilchenko DB, Glebov EM. Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile. Photochemical and Photobiological Sciences. 2024 Apr;23(4):747-755. doi: 10.1007/s43630-024-00550-5

Author

Grivin, Vjacheslav P. ; Matveeva, Svetlana G. ; Fedunov, Roman G. et al. / Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile. In: Photochemical and Photobiological Sciences. 2024 ; Vol. 23, No. 4. pp. 747-755.

BibTeX

@article{6dc41e028bee4601a88b751b4a227780,
title = "Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile",
abstract = "Photochemistry of the (n-Bu4N)2[Pt(NO3)6] complex in acetonitrile was studied by means of stationary photolysis and nanosecond laser flash photolysis. The primary photochemical process was found to be an intramolecular electron transfer followed by an escape of an •NO3 radical to the solution bulk. The spectra of two successive Pt(III) intermediates were detected in the microsecond time domain, and their spectral and kinetic characteristics were determined. These intermediates were identified as PtIII(NO3)52− and PtIII(NO3)4− complexes. Disproportionation of Pt(III) species resulted in formation of final Pt(II) products. Graphical Abstract: (Figure presented.)",
keywords = "Acetonitrile, Laser flash photolysis, NO3• radical, Photochemistry, Platinum(IV) complexes",
author = "Grivin, {Vjacheslav P.} and Matveeva, {Svetlana G.} and Fedunov, {Roman G.} and Yanshole, {Vadim V.} and Vasilchenko, {Danila B.} and Glebov, {Evgeni M.}",
note = "VY is grateful to the Ministry of Science and Higher Education of the Russian Federation (Project No. AAAA-A21-121012290043-3). HR-ESI-MS was performed at the Center of Collective Use \u201CMass spectrometric investigations\u201D SB RAS. The current work is funded by the Russian Science Foundation (Grant No. 23-201313-00226).",
year = "2024",
month = apr,
doi = "10.1007/s43630-024-00550-5",
language = "English",
volume = "23",
pages = "747--755",
journal = "Photochemical and Photobiological Sciences",
issn = "1474-905X",
publisher = "Royal Society of Chemistry",
number = "4",

}

RIS

TY - JOUR

T1 - Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile

AU - Grivin, Vjacheslav P.

AU - Matveeva, Svetlana G.

AU - Fedunov, Roman G.

AU - Yanshole, Vadim V.

AU - Vasilchenko, Danila B.

AU - Glebov, Evgeni M.

N1 - VY is grateful to the Ministry of Science and Higher Education of the Russian Federation (Project No. AAAA-A21-121012290043-3). HR-ESI-MS was performed at the Center of Collective Use \u201CMass spectrometric investigations\u201D SB RAS. The current work is funded by the Russian Science Foundation (Grant No. 23-201313-00226).

PY - 2024/4

Y1 - 2024/4

N2 - Photochemistry of the (n-Bu4N)2[Pt(NO3)6] complex in acetonitrile was studied by means of stationary photolysis and nanosecond laser flash photolysis. The primary photochemical process was found to be an intramolecular electron transfer followed by an escape of an •NO3 radical to the solution bulk. The spectra of two successive Pt(III) intermediates were detected in the microsecond time domain, and their spectral and kinetic characteristics were determined. These intermediates were identified as PtIII(NO3)52− and PtIII(NO3)4− complexes. Disproportionation of Pt(III) species resulted in formation of final Pt(II) products. Graphical Abstract: (Figure presented.)

AB - Photochemistry of the (n-Bu4N)2[Pt(NO3)6] complex in acetonitrile was studied by means of stationary photolysis and nanosecond laser flash photolysis. The primary photochemical process was found to be an intramolecular electron transfer followed by an escape of an •NO3 radical to the solution bulk. The spectra of two successive Pt(III) intermediates were detected in the microsecond time domain, and their spectral and kinetic characteristics were determined. These intermediates were identified as PtIII(NO3)52− and PtIII(NO3)4− complexes. Disproportionation of Pt(III) species resulted in formation of final Pt(II) products. Graphical Abstract: (Figure presented.)

KW - Acetonitrile

KW - Laser flash photolysis

KW - NO3• radical

KW - Photochemistry

KW - Platinum(IV) complexes

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85186401807&origin=inward&txGid=5291277ea3728cae893826de174678c6

UR - https://www.mendeley.com/catalogue/1a4091e9-605c-3fd4-a2bf-c7cf256b4352/

U2 - 10.1007/s43630-024-00550-5

DO - 10.1007/s43630-024-00550-5

M3 - Article

C2 - 38430371

VL - 23

SP - 747

EP - 755

JO - Photochemical and Photobiological Sciences

JF - Photochemical and Photobiological Sciences

SN - 1474-905X

IS - 4

ER -

ID: 61085224