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Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange. / Spiridonov, Kirill A.; Kozinenko, Vitaly P.; Nikovsky, Igor A. et al.

In: Mendeleev Communications, Vol. 31, No. 4, 01.07.2021, p. 475-477.

Research output: Contribution to journalArticlepeer-review

Harvard

Spiridonov, KA, Kozinenko, VP, Nikovsky, IA, Pavlov, AA, Vol'khina, TN, Nelyubina, YV, Kiryutin, AS, Yurkovskaya, AV, Polezhaev, AA, Novikov, VV & Ivanov, KL 2021, 'Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange', Mendeleev Communications, vol. 31, no. 4, pp. 475-477. https://doi.org/10.1016/j.mencom.2021.07.012

APA

Spiridonov, K. A., Kozinenko, V. P., Nikovsky, I. A., Pavlov, A. A., Vol'khina, T. N., Nelyubina, Y. V., Kiryutin, A. S., Yurkovskaya, A. V., Polezhaev, A. A., Novikov, V. V., & Ivanov, K. L. (2021). Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange. Mendeleev Communications, 31(4), 475-477. https://doi.org/10.1016/j.mencom.2021.07.012

Vancouver

Spiridonov KA, Kozinenko VP, Nikovsky IA, Pavlov AA, Vol'khina TN, Nelyubina YV et al. Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange. Mendeleev Communications. 2021 Jul 1;31(4):475-477. doi: 10.1016/j.mencom.2021.07.012

Author

Spiridonov, Kirill A. ; Kozinenko, Vitaly P. ; Nikovsky, Igor A. et al. / Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange. In: Mendeleev Communications. 2021 ; Vol. 31, No. 4. pp. 475-477.

BibTeX

@article{d8f4b137bed74562a3cc0db3671a1a28,
title = "Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange",
abstract = "Two new iridium complexes with an N-heterocyclic carbine and phosphite ligands have been synthesized and characterized. Bubbling of parahydrogen through their solutions resulted in the formation of several hydride complexes. In the presence of pyridine, this process is accompanied by transfer of spin order from the molecular hydrogen to pyridine molecules undergoing dynamic exchange between free and complex-bound states.",
keywords = "carbene ligands, hyperpolarization, iridium complexes, NMR spectroscopy, parahydrogen",
author = "Spiridonov, {Kirill A.} and Kozinenko, {Vitaly P.} and Nikovsky, {Igor A.} and Pavlov, {Alexander A.} and Vol'khina, {Tatyana N.} and Nelyubina, {Yulia V.} and Kiryutin, {Alexey S.} and Yurkovskaya, {Alexandra V.} and Polezhaev, {Alexander A.} and Novikov, {Valentin V.} and Ivanov, {Konstantin L.}",
note = "Publisher Copyright: {\textcopyright} 2021",
year = "2021",
month = jul,
day = "1",
doi = "10.1016/j.mencom.2021.07.012",
language = "English",
volume = "31",
pages = "475--477",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "4",

}

RIS

TY - JOUR

T1 - Phosphite-containing iridium polarization transfer catalysts for NMR signal amplification by reversible exchange

AU - Spiridonov, Kirill A.

AU - Kozinenko, Vitaly P.

AU - Nikovsky, Igor A.

AU - Pavlov, Alexander A.

AU - Vol'khina, Tatyana N.

AU - Nelyubina, Yulia V.

AU - Kiryutin, Alexey S.

AU - Yurkovskaya, Alexandra V.

AU - Polezhaev, Alexander A.

AU - Novikov, Valentin V.

AU - Ivanov, Konstantin L.

N1 - Publisher Copyright: © 2021

PY - 2021/7/1

Y1 - 2021/7/1

N2 - Two new iridium complexes with an N-heterocyclic carbine and phosphite ligands have been synthesized and characterized. Bubbling of parahydrogen through their solutions resulted in the formation of several hydride complexes. In the presence of pyridine, this process is accompanied by transfer of spin order from the molecular hydrogen to pyridine molecules undergoing dynamic exchange between free and complex-bound states.

AB - Two new iridium complexes with an N-heterocyclic carbine and phosphite ligands have been synthesized and characterized. Bubbling of parahydrogen through their solutions resulted in the formation of several hydride complexes. In the presence of pyridine, this process is accompanied by transfer of spin order from the molecular hydrogen to pyridine molecules undergoing dynamic exchange between free and complex-bound states.

KW - carbene ligands

KW - hyperpolarization

KW - iridium complexes

KW - NMR spectroscopy

KW - parahydrogen

UR - http://www.scopus.com/inward/record.url?scp=85113637700&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2021.07.012

DO - 10.1016/j.mencom.2021.07.012

M3 - Article

AN - SCOPUS:85113637700

VL - 31

SP - 475

EP - 477

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 4

ER -

ID: 34094417