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Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes. / Bakulina, Olga D.; Ivanov, Mikhail Yu; Prikhod’ko, Sergey A. et al.

In: Journal of Physical Chemistry C, 04.02.2025.

Research output: Contribution to journal › Article › peer-review

Harvard

Bakulina, OD, Ivanov, MY, Prikhod’ko, SA, Smirnova, KA, Sagdeev, RZ, Adonin, NY & Fedin, MV 2025, 'Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes', Journal of Physical Chemistry C. https://doi.org/10.1021/acs.jpcc.4c08031

APA

Bakulina, O. D., Ivanov, M. Y., Prikhod’ko, S. A., Smirnova, K. A., Sagdeev, R. Z., Adonin, N. Y., & Fedin, M. V. (2025). Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes. Journal of Physical Chemistry C. https://doi.org/10.1021/acs.jpcc.4c08031

Vancouver

Bakulina OD, Ivanov MY, Prikhod’ko SA, Smirnova KA, Sagdeev RZ, Adonin NY et al. Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes. Journal of Physical Chemistry C. 2025 Feb 4. doi: 10.1021/acs.jpcc.4c08031

Author

Bakulina, Olga D. ; Ivanov, Mikhail Yu ; Prikhod’ko, Sergey A. et al. / Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes. In: Journal of Physical Chemistry C. 2025.

BibTeX

@article{d76eb246a5c14fe0bd3ae0dbd87bdacb,
title = "Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes",
abstract = "Encapsulation of guest molecules into the voids of microporous media is a potent physicochemical strategy to obtain new functional materials. However, achieving durable confinement and mobility/flexibility of the guests simultaneously is often a challenging task. We report a straightforward approach to obtain such materials based on ionic liquids/solids and to study them using molecular probes. In these ionic solids, guest molecules are found encapsulated in closed micropores, allowing both free rotational motion and flexibility. This was approved by using stable nitroxide radicals as guest molecules and electron-paramagnetic resonance (EPR) spectroscopy and further exemplified by showcasing the photoisomerization reaction of azobenzene encapsulated in the materials. Since such ionic solids with entrapped mobile guests are crystalline, transparent for light, and easy to prepare, they represent promising platforms for the design of functional coatings, materials, and other media.",
author = "Bakulina, {Olga D.} and Ivanov, {Mikhail Yu} and Prikhod{\textquoteright}ko, {Sergey A.} and Smirnova, {Kristina A.} and Sagdeev, {Renad Z.} and Adonin, {Nicolay Yu} and Fedin, {Matvey V.}",
note = "This work was supported by the Russian Science Foundation (Grant No. 24-13-00119). The authors thank Dr. Igor A. Kirilyuk (NIOCh SB RAS) for providing them with the nitroxide spin probes.",
year = "2025",
month = feb,
day = "4",
doi = "10.1021/acs.jpcc.4c08031",
language = "English",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",

}

RIS

TY - JOUR

T1 - Permanent Encapsulation of Mobile Molecules in Ionic Solids: Unraveling the Local Microstructure Using Molecular Probes

AU - Bakulina, Olga D.

AU - Ivanov, Mikhail Yu

AU - Prikhod’ko, Sergey A.

AU - Smirnova, Kristina A.

AU - Sagdeev, Renad Z.

AU - Adonin, Nicolay Yu

AU - Fedin, Matvey V.

N1 - This work was supported by the Russian Science Foundation (Grant No. 24-13-00119). The authors thank Dr. Igor A. Kirilyuk (NIOCh SB RAS) for providing them with the nitroxide spin probes.

PY - 2025/2/4

Y1 - 2025/2/4

N2 - Encapsulation of guest molecules into the voids of microporous media is a potent physicochemical strategy to obtain new functional materials. However, achieving durable confinement and mobility/flexibility of the guests simultaneously is often a challenging task. We report a straightforward approach to obtain such materials based on ionic liquids/solids and to study them using molecular probes. In these ionic solids, guest molecules are found encapsulated in closed micropores, allowing both free rotational motion and flexibility. This was approved by using stable nitroxide radicals as guest molecules and electron-paramagnetic resonance (EPR) spectroscopy and further exemplified by showcasing the photoisomerization reaction of azobenzene encapsulated in the materials. Since such ionic solids with entrapped mobile guests are crystalline, transparent for light, and easy to prepare, they represent promising platforms for the design of functional coatings, materials, and other media.

AB - Encapsulation of guest molecules into the voids of microporous media is a potent physicochemical strategy to obtain new functional materials. However, achieving durable confinement and mobility/flexibility of the guests simultaneously is often a challenging task. We report a straightforward approach to obtain such materials based on ionic liquids/solids and to study them using molecular probes. In these ionic solids, guest molecules are found encapsulated in closed micropores, allowing both free rotational motion and flexibility. This was approved by using stable nitroxide radicals as guest molecules and electron-paramagnetic resonance (EPR) spectroscopy and further exemplified by showcasing the photoisomerization reaction of azobenzene encapsulated in the materials. Since such ionic solids with entrapped mobile guests are crystalline, transparent for light, and easy to prepare, they represent promising platforms for the design of functional coatings, materials, and other media.

UR - https://www.mendeley.com/catalogue/2eec6b3b-8b32-3842-a6b7-cab0e3bb6654/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85217047371&origin=inward&txGid=3bd8b58342aa508c639e4dff04be839b

U2 - 10.1021/acs.jpcc.4c08031

DO - 10.1021/acs.jpcc.4c08031

M3 - Article

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

ER -

ID: 64693680