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Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons. / Sobolev, Vladimir I.; Koltunov, Konstantin Yu; Zenkovets, Galina A.

In: Catalysis Letters, Vol. 147, No. 2, 02.2017, p. 310-317.

Research output: Contribution to journal › Article › peer-review

Harvard

Sobolev, VI, Koltunov, KY & Zenkovets, GA 2017, 'Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons', Catalysis Letters, vol. 147, no. 2, pp. 310-317. https://doi.org/10.1007/s10562-016-1947-7

APA

Sobolev, V. I., Koltunov, K. Y., & Zenkovets, G. A. (2017). Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons. Catalysis Letters, 147(2), 310-317. https://doi.org/10.1007/s10562-016-1947-7

Vancouver

Sobolev VI, Koltunov KY, Zenkovets GA. Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons. Catalysis Letters. 2017 Feb;147(2):310-317. doi: 10.1007/s10562-016-1947-7

Author

Sobolev, Vladimir I. ; Koltunov, Konstantin Yu ; Zenkovets, Galina A. / Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons. In: Catalysis Letters. 2017 ; Vol. 147, No. 2. pp. 310-317.

BibTeX

@article{4249355eb89346528d37d631c547ac4c,
title = "Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons",
abstract = "The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons.",
keywords = "1,3-Butadiene, 1-Butene, Concurrent reactions, Multicomponent bismuth molybdate, Oxidative dehydrogenation, SELECTIVE OXIDATION, ISOMERIZATION, REACTIVITY, OXIDE-BASED CATALYSTS, METHACROLEIN, RAFFINATE-3, NICKEL CONTENT, N-BUTENE, KINETICS, MOLYBDENUM OXIDE",
author = "Sobolev, {Vladimir I.} and Koltunov, {Konstantin Yu} and Zenkovets, {Galina A.}",
note = "Publisher Copyright: {\textcopyright} 2016, Springer Science+Business Media New York.",
year = "2017",
month = feb,
doi = "10.1007/s10562-016-1947-7",
language = "English",
volume = "147",
pages = "310--317",
journal = "Catalysis Letters",
issn = "1011-372X",
publisher = "Springer Netherlands",
number = "2",

}

RIS

TY - JOUR

T1 - Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons

AU - Sobolev, Vladimir I.

AU - Koltunov, Konstantin Yu

AU - Zenkovets, Galina A.

N1 - Publisher Copyright: © 2016, Springer Science+Business Media New York.

PY - 2017/2

Y1 - 2017/2

N2 - The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons.

AB - The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons.

KW - 1,3-Butadiene

KW - 1-Butene

KW - Concurrent reactions

KW - Multicomponent bismuth molybdate

KW - Oxidative dehydrogenation

KW - SELECTIVE OXIDATION

KW - ISOMERIZATION

KW - REACTIVITY

KW - OXIDE-BASED CATALYSTS

KW - METHACROLEIN

KW - RAFFINATE-3

KW - NICKEL CONTENT

KW - N-BUTENE

KW - KINETICS

KW - MOLYBDENUM OXIDE

UR - http://www.scopus.com/inward/record.url?scp=85007110527&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/26de8ee9-7f03-37c9-a403-6a28a8e7dafb/

U2 - 10.1007/s10562-016-1947-7

DO - 10.1007/s10562-016-1947-7

M3 - Article

AN - SCOPUS:85007110527

VL - 147

SP - 310

EP - 317

JO - Catalysis Letters

JF - Catalysis Letters

SN - 1011-372X

IS - 2

ER -

ID: 10318167