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Oxidative addition of verdazyl halogenides to Pd(PPh3)4. / Petunin, Pavel V.; Votkina, Darya E.; Trusova, Marina E. et al.

In: New Journal of Chemistry, Vol. 43, No. 38, 14.10.2019, p. 15293-15301.

Research output: Contribution to journal › Article › peer-review

Harvard

Petunin, PV, Votkina, DE, Trusova, ME, Rybalova, TV, Amosov, EV, Uvarov, MN, Postnikov, PS, Kazantsev, MS & Mostovich, EA 2019, 'Oxidative addition of verdazyl halogenides to Pd(PPh3)4', New Journal of Chemistry, vol. 43, no. 38, pp. 15293-15301. https://doi.org/10.1039/c9nj03361k

APA

Petunin, P. V., Votkina, D. E., Trusova, M. E., Rybalova, T. V., Amosov, E. V., Uvarov, M. N., Postnikov, P. S., Kazantsev, M. S., & Mostovich, E. A. (2019). Oxidative addition of verdazyl halogenides to Pd(PPh3)4. New Journal of Chemistry, 43(38), 15293-15301. https://doi.org/10.1039/c9nj03361k

Vancouver

Petunin PV, Votkina DE, Trusova ME, Rybalova TV, Amosov EV, Uvarov MN et al. Oxidative addition of verdazyl halogenides to Pd(PPh3)4. New Journal of Chemistry. 2019 Oct 14;43(38):15293-15301. doi: 10.1039/c9nj03361k

Author

Petunin, Pavel V. ; Votkina, Darya E. ; Trusova, Marina E. et al. / Oxidative addition of verdazyl halogenides to Pd(PPh3)4. In: New Journal of Chemistry. 2019 ; Vol. 43, No. 38. pp. 15293-15301.

BibTeX

@article{3c05679b92a1406a916f1fcf6b0cb362,
title = "Oxidative addition of verdazyl halogenides to Pd(PPh3)4",
abstract = "Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(ii) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities.",
keywords = "FUNCTIONAL-GROUP TRANSFORMATIONS, SUZUKI COUPLING REACTIONS, NITRONYL NITROXIDE, RADICALS SYNTHESIS, PD(II) COMPLEXES, SYNTHETIC METHOD, REDOX REACTIONS, PALLADIUM, DERIVATIVES, DIRADICALS",
author = "Petunin, {Pavel V.} and Votkina, {Darya E.} and Trusova, {Marina E.} and Rybalova, {Tatyana V.} and Amosov, {Evgeny V.} and Uvarov, {Mikhail N.} and Postnikov, {Pavel S.} and Kazantsev, {Maxim S.} and Mostovich, {Evgeny A.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2019",
month = oct,
day = "14",
doi = "10.1039/c9nj03361k",
language = "English",
volume = "43",
pages = "15293--15301",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "38",

}

RIS

TY - JOUR

T1 - Oxidative addition of verdazyl halogenides to Pd(PPh3)4

AU - Petunin, Pavel V.

AU - Votkina, Darya E.

AU - Trusova, Marina E.

AU - Rybalova, Tatyana V.

AU - Amosov, Evgeny V.

AU - Uvarov, Mikhail N.

AU - Postnikov, Pavel S.

AU - Kazantsev, Maxim S.

AU - Mostovich, Evgeny A.

N1 - Publisher Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2019/10/14

Y1 - 2019/10/14

N2 - Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(ii) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities.

AB - Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(ii) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities.

KW - FUNCTIONAL-GROUP TRANSFORMATIONS

KW - SUZUKI COUPLING REACTIONS

KW - NITRONYL NITROXIDE

KW - RADICALS SYNTHESIS

KW - PD(II) COMPLEXES

KW - SYNTHETIC METHOD

KW - REDOX REACTIONS

KW - PALLADIUM

KW - DERIVATIVES

KW - DIRADICALS

UR - http://www.scopus.com/inward/record.url?scp=85072819925&partnerID=8YFLogxK

U2 - 10.1039/c9nj03361k

DO - 10.1039/c9nj03361k

M3 - Article

AN - SCOPUS:85072819925

VL - 43

SP - 15293

EP - 15301

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 38

ER -

ID: 21792086