Oxalatocuprate(ii) hexaammincobalt(iii) as a precursor of metastable solid solutions in the Co-Cu system

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Oxalatocuprate(ii) hexaammincobalt(iii) as a precursor of metastable solid solutions in the Co-Cu system. / Lagunova, Varvara; Rubilkin, Pavel; Filatov, Evgeny et al.

In: New Journal of Chemistry, Vol. 48, No. 4, 03.01.2024, p. 1578-1586.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{8f3d9f0a8a944bbfbc18b1532f816fa5,

title = "Oxalatocuprate(ii) hexaammincobalt(iii) as a precursor of metastable solid solutions in the Co-Cu system",

abstract = "The synthesis and characterization of the double complex salts [Co(NH3)6]2[Cu(C2O4)2]3·4H2O and [Co(NH3)6]2[Cu(C2O4)2]3·6H2O was carried out. The process of thermal decomposition of synthesized compounds in reducing and inert atmospheres was studied with determination of the released gases composition, as well as intermediate and final decomposition products by ex situ XRD. The thermal decomposition of complex salts in reducing and inert atmospheres was studied by in situ powder X-ray diffraction on a laboratory diffractometer. The possibility of the formation of metastable solid solutions in the Co-Cu system with a maximum copper content up to 37 at% was demonstrated.",

author = "Varvara Lagunova and Pavel Rubilkin and Evgeny Filatov and Pavel Plyusnin and Natalia Kuratieva and Sergey Korenev",

note = "This research was funded by the Russian Science Foundation, grant number 21-73-20203. The authors thank the Ministry of Science and Education of the Russian Federation (project numbers 121031700315-2 and 121031700313-8) for their support.",

year = "2024",

month = jan,

day = "3",

doi = "10.1039/d3nj05311c",

language = "English",

volume = "48",

pages = "1578--1586",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "ROYAL SOC CHEMISTRY",

number = "4",

}

RIS

TY - JOUR

T1 - Oxalatocuprate(ii) hexaammincobalt(iii) as a precursor of metastable solid solutions in the Co-Cu system

AU - Lagunova, Varvara

AU - Rubilkin, Pavel

AU - Filatov, Evgeny

AU - Plyusnin, Pavel

AU - Kuratieva, Natalia

AU - Korenev, Sergey

N1 - This research was funded by the Russian Science Foundation, grant number 21-73-20203. The authors thank the Ministry of Science and Education of the Russian Federation (project numbers 121031700315-2 and 121031700313-8) for their support.

PY - 2024/1/3

Y1 - 2024/1/3

N2 - The synthesis and characterization of the double complex salts [Co(NH3)6]2[Cu(C2O4)2]3·4H2O and [Co(NH3)6]2[Cu(C2O4)2]3·6H2O was carried out. The process of thermal decomposition of synthesized compounds in reducing and inert atmospheres was studied with determination of the released gases composition, as well as intermediate and final decomposition products by ex situ XRD. The thermal decomposition of complex salts in reducing and inert atmospheres was studied by in situ powder X-ray diffraction on a laboratory diffractometer. The possibility of the formation of metastable solid solutions in the Co-Cu system with a maximum copper content up to 37 at% was demonstrated.

AB - The synthesis and characterization of the double complex salts [Co(NH3)6]2[Cu(C2O4)2]3·4H2O and [Co(NH3)6]2[Cu(C2O4)2]3·6H2O was carried out. The process of thermal decomposition of synthesized compounds in reducing and inert atmospheres was studied with determination of the released gases composition, as well as intermediate and final decomposition products by ex situ XRD. The thermal decomposition of complex salts in reducing and inert atmospheres was studied by in situ powder X-ray diffraction on a laboratory diffractometer. The possibility of the formation of metastable solid solutions in the Co-Cu system with a maximum copper content up to 37 at% was demonstrated.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85181834809&origin=inward&txGid=d944c4cc828d080a0bd93dfe0f9409dc

UR - https://www.mendeley.com/catalogue/55fa18a9-417f-3c37-81fc-1ada99bab21d/

U2 - 10.1039/d3nj05311c

DO - 10.1039/d3nj05311c

M3 - Article

VL - 48

SP - 1578

EP - 1586

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 4

ER -

ID: 60497974