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On Gold(I) Thiomalate Complexes in Aqueous Solution. / Mironov, I. V.; Kharlamova, V. Yu.

In: Russian Journal of Inorganic Chemistry, Vol. 63, No. 7, 01.07.2018, p. 978-982.

Research output: Contribution to journal › Article › peer-review

Harvard

Mironov, IV & Kharlamova, VY 2018, 'On Gold(I) Thiomalate Complexes in Aqueous Solution', Russian Journal of Inorganic Chemistry, vol. 63, no. 7, pp. 978-982. https://doi.org/10.1134/S0036023618070173

APA

Mironov, I. V., & Kharlamova, V. Y. (2018). On Gold(I) Thiomalate Complexes in Aqueous Solution. Russian Journal of Inorganic Chemistry, 63(7), 978-982. https://doi.org/10.1134/S0036023618070173

Vancouver

Mironov IV, Kharlamova VY. On Gold(I) Thiomalate Complexes in Aqueous Solution. Russian Journal of Inorganic Chemistry. 2018 Jul 1;63(7):978-982. doi: 10.1134/S0036023618070173

Author

Mironov, I. V. ; Kharlamova, V. Yu. / On Gold(I) Thiomalate Complexes in Aqueous Solution. In: Russian Journal of Inorganic Chemistry. 2018 ; Vol. 63, No. 7. pp. 978-982.

BibTeX

@article{773fe2a1de68426699195e34eb889373,
title = "On Gold(I) Thiomalate Complexes in Aqueous Solution",
abstract = "Certain equilibria involving polymeric gold(I) thiomalate complexes have been studied by spectrophotometry and pH measurements in aqueous solution at 25°С and I = 0.2 M (NaCl). Thiomalate protonation constants Hi–1Tm3– + H+ = HiTmi–3 have been found to be logKH1 = 10.23, logKH2 = 4.51, logKH3 = 3.01. Efficient functions have been used to allow for multiple protonation of polymeric complexes Aun Tmm n-3 m Equilibrium constants for reactions Au4Tm4 8− + Tm3– = Au4Tm5 11− (logK45 = 10.1 ± 0.5) and 0.25 Au4Tm4 8− + Tm3– = AuTm2 5− (logK12 = 4.9 ± 0.2) have been determined. Standard potential for AuTm2 5− has been found to be equal to E1/0 0 =–0.260 ± 0.025 V.",
keywords = "THIOUREA, DRUG",
author = "Mironov, {I. V.} and Kharlamova, {V. Yu}",
year = "2018",
month = jul,
day = "1",
doi = "10.1134/S0036023618070173",
language = "English",
volume = "63",
pages = "978--982",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - On Gold(I) Thiomalate Complexes in Aqueous Solution

AU - Mironov, I. V.

AU - Kharlamova, V. Yu

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Certain equilibria involving polymeric gold(I) thiomalate complexes have been studied by spectrophotometry and pH measurements in aqueous solution at 25°С and I = 0.2 M (NaCl). Thiomalate protonation constants Hi–1Tm3– + H+ = HiTmi–3 have been found to be logKH1 = 10.23, logKH2 = 4.51, logKH3 = 3.01. Efficient functions have been used to allow for multiple protonation of polymeric complexes Aun Tmm n-3 m Equilibrium constants for reactions Au4Tm4 8− + Tm3– = Au4Tm5 11− (logK45 = 10.1 ± 0.5) and 0.25 Au4Tm4 8− + Tm3– = AuTm2 5− (logK12 = 4.9 ± 0.2) have been determined. Standard potential for AuTm2 5− has been found to be equal to E1/0 0 =–0.260 ± 0.025 V.

AB - Certain equilibria involving polymeric gold(I) thiomalate complexes have been studied by spectrophotometry and pH measurements in aqueous solution at 25°С and I = 0.2 M (NaCl). Thiomalate protonation constants Hi–1Tm3– + H+ = HiTmi–3 have been found to be logKH1 = 10.23, logKH2 = 4.51, logKH3 = 3.01. Efficient functions have been used to allow for multiple protonation of polymeric complexes Aun Tmm n-3 m Equilibrium constants for reactions Au4Tm4 8− + Tm3– = Au4Tm5 11− (logK45 = 10.1 ± 0.5) and 0.25 Au4Tm4 8− + Tm3– = AuTm2 5− (logK12 = 4.9 ± 0.2) have been determined. Standard potential for AuTm2 5− has been found to be equal to E1/0 0 =–0.260 ± 0.025 V.

KW - THIOUREA

KW - DRUG

UR - http://www.scopus.com/inward/record.url?scp=85051803030&partnerID=8YFLogxK

U2 - 10.1134/S0036023618070173

DO - 10.1134/S0036023618070173

M3 - Article

AN - SCOPUS:85051803030

VL - 63

SP - 978

EP - 982

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 7

ER -

ID: 16112783