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Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates. / Lyakin, Oleg Y.; Bryliakov, Konstantin P.; Talsi, Evgenii P.

In: Coordination Chemistry Reviews, Vol. 384, 01.04.2019, p. 126-139.

Research output: Contribution to journal › Review article › peer-review

Harvard

Lyakin, OY, Bryliakov, KP & Talsi, EP 2019, 'Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates', Coordination Chemistry Reviews, vol. 384, pp. 126-139. https://doi.org/10.1016/j.ccr.2019.01.010

APA

Lyakin, O. Y., Bryliakov, K. P., & Talsi, E. P. (2019). Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates. Coordination Chemistry Reviews, 384, 126-139. https://doi.org/10.1016/j.ccr.2019.01.010

Vancouver

Lyakin OY, Bryliakov KP, Talsi EP. Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates. Coordination Chemistry Reviews. 2019 Apr 1;384:126-139. doi: 10.1016/j.ccr.2019.01.010

Author

Lyakin, Oleg Y. ; Bryliakov, Konstantin P. ; Talsi, Evgenii P. / Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates. In: Coordination Chemistry Reviews. 2019 ; Vol. 384. pp. 126-139.

BibTeX

@article{90e70cda5557410b9e04a79a2f08e65e,
title = "Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates",
abstract = "In the last two decades, a number of synthetic iron-based biomimetic catalyst systems for the selective oxidation of organic compounds, such as epoxidations of alkenes and C–H oxidations of alkanes and arenes, have been reported and extensively investigated. In some cases, the mechanisms of their catalytic action have been hypothesized, and the nature of their catalytically active, oxygen-transferring species, has been established. This review is dedicated to the synthetic non-heme perferryl intermediates, formal analogs of Compound I in the catalytic cycle of cytochrome P450. The discovery of perferryl species, their structure and spectroscopic properties, as well as the effect of oxidant nature, ligand structure, and additives on their reactivity and selectivity are discussed.",
keywords = "Active site, Biomimetics, Iron, Mechanism, Oxidation, Perferryl, OXYGEN-ATOM TRANSFER, C-H BONDS, FE-V=O, IRON-CATALYSTS, AROMATIC HYDROXYLATION, HIGHLY ENANTIOSELECTIVE EPOXIDATION, ASYMMETRIC EPOXIDATION, CIS-DIHYDROXYLATION, HYDROGEN-PEROXIDE, STEREOSPECIFIC ALKANE HYDROXYLATION",
author = "Lyakin, {Oleg Y.} and Bryliakov, {Konstantin P.} and Talsi, {Evgenii P.}",
year = "2019",
month = apr,
day = "1",
doi = "10.1016/j.ccr.2019.01.010",
language = "English",
volume = "384",
pages = "126--139",
journal = "Coordination Chemistry Reviews",
issn = "0010-8545",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates

AU - Lyakin, Oleg Y.

AU - Bryliakov, Konstantin P.

AU - Talsi, Evgenii P.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - In the last two decades, a number of synthetic iron-based biomimetic catalyst systems for the selective oxidation of organic compounds, such as epoxidations of alkenes and C–H oxidations of alkanes and arenes, have been reported and extensively investigated. In some cases, the mechanisms of their catalytic action have been hypothesized, and the nature of their catalytically active, oxygen-transferring species, has been established. This review is dedicated to the synthetic non-heme perferryl intermediates, formal analogs of Compound I in the catalytic cycle of cytochrome P450. The discovery of perferryl species, their structure and spectroscopic properties, as well as the effect of oxidant nature, ligand structure, and additives on their reactivity and selectivity are discussed.

AB - In the last two decades, a number of synthetic iron-based biomimetic catalyst systems for the selective oxidation of organic compounds, such as epoxidations of alkenes and C–H oxidations of alkanes and arenes, have been reported and extensively investigated. In some cases, the mechanisms of their catalytic action have been hypothesized, and the nature of their catalytically active, oxygen-transferring species, has been established. This review is dedicated to the synthetic non-heme perferryl intermediates, formal analogs of Compound I in the catalytic cycle of cytochrome P450. The discovery of perferryl species, their structure and spectroscopic properties, as well as the effect of oxidant nature, ligand structure, and additives on their reactivity and selectivity are discussed.

KW - Active site

KW - Biomimetics

KW - Iron

KW - Mechanism

KW - Oxidation

KW - Perferryl

KW - OXYGEN-ATOM TRANSFER

KW - C-H BONDS

KW - FE-V=O

KW - IRON-CATALYSTS

KW - AROMATIC HYDROXYLATION

KW - HIGHLY ENANTIOSELECTIVE EPOXIDATION

KW - ASYMMETRIC EPOXIDATION

KW - CIS-DIHYDROXYLATION

KW - HYDROGEN-PEROXIDE

KW - STEREOSPECIFIC ALKANE HYDROXYLATION

UR - http://www.scopus.com/inward/record.url?scp=85060599661&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2019.01.010

DO - 10.1016/j.ccr.2019.01.010

M3 - Review article

AN - SCOPUS:85060599661

VL - 384

SP - 126

EP - 139

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -

ID: 18485720