Nonclassical Adsorption of Methanol on Palladium

Standard

Nonclassical Adsorption of Methanol on Palladium : The Competition between Adsorption of Single Molecules and Clusters. / Kaichev, Vasily V.; Selivanova, Aleksandra V.; Tsapina, Anna M. et al.

In: Journal of Physical Chemistry C, Vol. 123, No. 12, 28.03.2019, p. 7259-7265.

Research output: Contribution to journal › Article › peer-review

Author

Kaichev, Vasily V. ; Selivanova, Aleksandra V. ; Tsapina, Anna M. et al. / Nonclassical Adsorption of Methanol on Palladium : The Competition between Adsorption of Single Molecules and Clusters. In: Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 12. pp. 7259-7265.

BibTeX

@article{2c53e5de1619482c945d92083e95e2e9,

title = "Nonclassical Adsorption of Methanol on Palladium: The Competition between Adsorption of Single Molecules and Clusters",

abstract = " The adsorption of methanol on the Pd(111) surface at 80, 90, and 100 K has been studied by polarization modulation infrared reflection-absorption spectroscopy. It is found that the adsorption of methanol on the palladium surface does not proceed via the layer-by-layer mechanism. At temperatures below 100 K, methanol adsorbs molecularly to form clusters containing several hydrogen-bonded CH 3 OH molecules. These clusters have low thermal stability and decompose even at 100 K to form isolated methanol molecules bonded with palladium atoms. As a result, at a temperature between 100 and 120 K, methanol adsorbs intact to produce adsorbed isolated molecules. These adsorbed species fast desorb at a temperature above 120 K. The dehydration of methanol is not observed under used conditions. ",

author = "Kaichev, {Vasily V.} and Selivanova, {Aleksandra V.} and Tsapina, {Anna M.} and Saraev, {Andrey A.} and Bukhtiyarov, {Valerii I.}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = mar,

day = "28",

doi = "10.1021/acs.jpcc.9b00840",

language = "English",

volume = "123",

pages = "7259--7265",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "12",

}

RIS

TY - JOUR

T1 - Nonclassical Adsorption of Methanol on Palladium

T2 - The Competition between Adsorption of Single Molecules and Clusters

AU - Kaichev, Vasily V.

AU - Selivanova, Aleksandra V.

AU - Tsapina, Anna M.

AU - Saraev, Andrey A.

AU - Bukhtiyarov, Valerii I.

PY - 2019/3/28

Y1 - 2019/3/28

N2 - The adsorption of methanol on the Pd(111) surface at 80, 90, and 100 K has been studied by polarization modulation infrared reflection-absorption spectroscopy. It is found that the adsorption of methanol on the palladium surface does not proceed via the layer-by-layer mechanism. At temperatures below 100 K, methanol adsorbs molecularly to form clusters containing several hydrogen-bonded CH 3 OH molecules. These clusters have low thermal stability and decompose even at 100 K to form isolated methanol molecules bonded with palladium atoms. As a result, at a temperature between 100 and 120 K, methanol adsorbs intact to produce adsorbed isolated molecules. These adsorbed species fast desorb at a temperature above 120 K. The dehydration of methanol is not observed under used conditions.

AB - The adsorption of methanol on the Pd(111) surface at 80, 90, and 100 K has been studied by polarization modulation infrared reflection-absorption spectroscopy. It is found that the adsorption of methanol on the palladium surface does not proceed via the layer-by-layer mechanism. At temperatures below 100 K, methanol adsorbs molecularly to form clusters containing several hydrogen-bonded CH 3 OH molecules. These clusters have low thermal stability and decompose even at 100 K to form isolated methanol molecules bonded with palladium atoms. As a result, at a temperature between 100 and 120 K, methanol adsorbs intact to produce adsorbed isolated molecules. These adsorbed species fast desorb at a temperature above 120 K. The dehydration of methanol is not observed under used conditions.

UR - http://www.scopus.com/inward/record.url?scp=85063140960&partnerID=8YFLogxK

U2 - 10.1021/acs.jpcc.9b00840

DO - 10.1021/acs.jpcc.9b00840

M3 - Article

AN - SCOPUS:85063140960

VL - 123

SP - 7259

EP - 7265

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 12

ER -

ID: 18949114