Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds

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Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds. / Dubkov, Konstantin A.; Panov, Gennadii I.; Parmon, Valentin N.

In: Russian Chemical Reviews, Vol. 86, No. 6, 01.01.2017, p. 510-529.

Research output: Contribution to journal › Review article › peer-review

Author

Dubkov, Konstantin A. ; Panov, Gennadii I. ; Parmon, Valentin N. / Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds. In: Russian Chemical Reviews. 2017 ; Vol. 86, No. 6. pp. 510-529.

BibTeX

@article{759fc0b181b64414a5a4b65eace37d6e,

title = "Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds",

abstract = "The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions ofN2Owith carbon ± carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomersDunsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed.",

keywords = "LIQUID-PHASE OXIDATION, 1,3-DIPOLAR CYCLOADDITIONS, AMMONIA OXIDATION, MN/BI/AL CATALYST, CARBON-MONOXIDE, ALKENES, CHEMISTRY, RUBBER, COPOLYMERIZATION, CARBOXIDATION",

author = "Dubkov, {Konstantin A.} and Panov, {Gennadii I.} and Parmon, {Valentin N.}",

year = "2017",

month = jan,

day = "1",

doi = "10.1070/RCR4697",

language = "English",

volume = "86",

pages = "510--529",

journal = "Russian Chemical Reviews",

issn = "0036-021X",

publisher = "Turpion Ltd.",

number = "6",

}

RIS

TY - JOUR

T1 - Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds

AU - Dubkov, Konstantin A.

AU - Panov, Gennadii I.

AU - Parmon, Valentin N.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions ofN2Owith carbon ± carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomersDunsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed.

AB - The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions ofN2Owith carbon ± carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomersDunsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed.

KW - LIQUID-PHASE OXIDATION

KW - 1,3-DIPOLAR CYCLOADDITIONS

KW - AMMONIA OXIDATION

KW - MN/BI/AL CATALYST

KW - CARBON-MONOXIDE

KW - ALKENES

KW - CHEMISTRY

KW - RUBBER

KW - COPOLYMERIZATION

KW - CARBOXIDATION

UR - http://www.scopus.com/inward/record.url?scp=85021422129&partnerID=8YFLogxK

U2 - 10.1070/RCR4697

DO - 10.1070/RCR4697

M3 - Review article

AN - SCOPUS:85021422129

VL - 86

SP - 510

EP - 529

JO - Russian Chemical Reviews

JF - Russian Chemical Reviews

SN - 0036-021X

IS - 6

ER -

ID: 10183181