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Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand. / Vorobyev, Vasily; Emelyanov, Vyacheslav A.; Valuev, Igor A. et al.

In: Inorganic Chemistry Communications, Vol. 76, 01.02.2017, p. 40-43.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorobyev, V, Emelyanov, VA, Valuev, IA & Baidina, IA 2017, 'Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand', Inorganic Chemistry Communications, vol. 76, pp. 40-43. https://doi.org/10.1016/j.inoche.2016.12.004

APA

Vorobyev, V., Emelyanov, V. A., Valuev, I. A., & Baidina, I. A. (2017). Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand. Inorganic Chemistry Communications, 76, 40-43. https://doi.org/10.1016/j.inoche.2016.12.004

Vancouver

Vorobyev V, Emelyanov VA, Valuev IA, Baidina IA. Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand. Inorganic Chemistry Communications. 2017 Feb 1;76:40-43. doi: 10.1016/j.inoche.2016.12.004

Author

Vorobyev, Vasily ; Emelyanov, Vyacheslav A. ; Valuev, Igor A. et al. / Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand. In: Inorganic Chemistry Communications. 2017 ; Vol. 76. pp. 40-43.

BibTeX

@article{ee6e8bb1569e4a0eb97dab6112c2cf67,
title = "Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand",
abstract = "The ruthenium complex with bridging H3O2 − ligand was obtained and the crystal structure was determined. The compound cis-[{RuNO(NH3)2Cl2}2(μ2-H3O2)]Cl crystallizes in the monoclinic space group P21/n with cell parameters a = 15.0651(5), b = 6.3624(2), c = 15.3813(6) {\AA}, β = 94.9690(10)°, Z = 4 and R = 0.0185. The hydroxide hydrate anion is coordinated to the ruthenium atoms of the identical cis-{RuNO(NH3)2Cl2} fragments. The protonation of the starting cis-[RuNO(NH3)2(NO2)2OH] complex leads to the required coordinated aqua/hydroxide ratio if the specific amount of hydrochloric acid is used. The DFT calculations confirm the formation of the dimer structure in the gas phase. However, the presence of water molecules dramatically reduces the dimerization efficiency.",
keywords = "Ammine complex, Aqua-hydroxo ligand, Chloro complex, Nitrosyl, Ruthenium, DIMER, NITRIC-ACID SOLUTIONS, CRYSTAL-STRUCTURE",
author = "Vasily Vorobyev and Emelyanov, {Vyacheslav A.} and Valuev, {Igor A.} and Baidina, {Iraida A.}",
year = "2017",
month = feb,
day = "1",
doi = "10.1016/j.inoche.2016.12.004",
language = "English",
volume = "76",
pages = "40--43",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Nitrosyl cis-dichlorodiammine ruthenium complex with bridging H3O2 − ligand

AU - Vorobyev, Vasily

AU - Emelyanov, Vyacheslav A.

AU - Valuev, Igor A.

AU - Baidina, Iraida A.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - The ruthenium complex with bridging H3O2 − ligand was obtained and the crystal structure was determined. The compound cis-[{RuNO(NH3)2Cl2}2(μ2-H3O2)]Cl crystallizes in the monoclinic space group P21/n with cell parameters a = 15.0651(5), b = 6.3624(2), c = 15.3813(6) Å, β = 94.9690(10)°, Z = 4 and R = 0.0185. The hydroxide hydrate anion is coordinated to the ruthenium atoms of the identical cis-{RuNO(NH3)2Cl2} fragments. The protonation of the starting cis-[RuNO(NH3)2(NO2)2OH] complex leads to the required coordinated aqua/hydroxide ratio if the specific amount of hydrochloric acid is used. The DFT calculations confirm the formation of the dimer structure in the gas phase. However, the presence of water molecules dramatically reduces the dimerization efficiency.

AB - The ruthenium complex with bridging H3O2 − ligand was obtained and the crystal structure was determined. The compound cis-[{RuNO(NH3)2Cl2}2(μ2-H3O2)]Cl crystallizes in the monoclinic space group P21/n with cell parameters a = 15.0651(5), b = 6.3624(2), c = 15.3813(6) Å, β = 94.9690(10)°, Z = 4 and R = 0.0185. The hydroxide hydrate anion is coordinated to the ruthenium atoms of the identical cis-{RuNO(NH3)2Cl2} fragments. The protonation of the starting cis-[RuNO(NH3)2(NO2)2OH] complex leads to the required coordinated aqua/hydroxide ratio if the specific amount of hydrochloric acid is used. The DFT calculations confirm the formation of the dimer structure in the gas phase. However, the presence of water molecules dramatically reduces the dimerization efficiency.

KW - Ammine complex

KW - Aqua-hydroxo ligand

KW - Chloro complex

KW - Nitrosyl

KW - Ruthenium

KW - DIMER

KW - NITRIC-ACID SOLUTIONS

KW - CRYSTAL-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85008336856&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.12.004

DO - 10.1016/j.inoche.2016.12.004

M3 - Article

AN - SCOPUS:85008336856

VL - 76

SP - 40

EP - 43

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 10316406