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Niobium and Tantalum Halocyanide Clusters: The Complete Family. / Shamshurin, Maxim; Gushchin, Artem; Adonin, Sergey et al.

In: Inorganic Chemistry, Vol. 61, No. 42, 24.10.2022, p. 16586-16595.

Research output: Contribution to journal › Article › peer-review

Harvard

Shamshurin, M, Gushchin, A, Adonin, S, Benassi, E & Sokolov, M 2022, 'Niobium and Tantalum Halocyanide Clusters: The Complete Family', Inorganic Chemistry, vol. 61, no. 42, pp. 16586-16595. https://doi.org/10.1021/acs.inorgchem.2c01824

APA

Shamshurin, M., Gushchin, A., Adonin, S., Benassi, E., & Sokolov, M. (2022). Niobium and Tantalum Halocyanide Clusters: The Complete Family. Inorganic Chemistry, 61(42), 16586-16595. https://doi.org/10.1021/acs.inorgchem.2c01824

Vancouver

Shamshurin M, Gushchin A, Adonin S, Benassi E, Sokolov M. Niobium and Tantalum Halocyanide Clusters: The Complete Family. Inorganic Chemistry. 2022 Oct 24;61(42):16586-16595. Epub 2022 Sept 26. doi: 10.1021/acs.inorgchem.2c01824

Author

Shamshurin, Maxim ; Gushchin, Artem ; Adonin, Sergey et al. / Niobium and Tantalum Halocyanide Clusters: The Complete Family. In: Inorganic Chemistry. 2022 ; Vol. 61, No. 42. pp. 16586-16595.

BibTeX

@article{4028611c7682493d8c61207c7d6c2378,
title = "Niobium and Tantalum Halocyanide Clusters: The Complete Family",
abstract = "Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide clusters with terminal cyanide ligands have been developed. Corresponding [M6X12(CN)12]4- (M = Nb, Ta; X = Cl, Br) can be accessed by ligand-exchange procedures from K4Nb6X18 (X = Cl, Br) and Bu4NCN, (Et4N)2[Ta6Cl18] and Bu4NCN and from [Ta6Br12(H2O)4Br2]·4H2O and KCN in moderate to high yields (50-80%). The products were isolated as Bu4N salts. The compounds were investigated both experimentally and by quantum chemistry, revealing correlations between structural, electrochemical, electrostatic, electronic, and topological features as a function of type of metal, halide, and charge.",
author = "Maxim Shamshurin and Artem Gushchin and Sergey Adonin and Enrico Benassi and Maxim Sokolov",
note = "Funding Information: The work has been supported by the Russian Foundation for Basic Research (no. 20-33-90010). The analytical research was supported by the Ministry of Science and Higher Education of the Russian Federation, no. 121031700313-8. Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",
year = "2022",
month = oct,
day = "24",
doi = "10.1021/acs.inorgchem.2c01824",
language = "English",
volume = "61",
pages = "16586--16595",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "42",

}

RIS

TY - JOUR

T1 - Niobium and Tantalum Halocyanide Clusters: The Complete Family

AU - Shamshurin, Maxim

AU - Gushchin, Artem

AU - Adonin, Sergey

AU - Benassi, Enrico

AU - Sokolov, Maxim

N1 - Funding Information: The work has been supported by the Russian Foundation for Basic Research (no. 20-33-90010). The analytical research was supported by the Ministry of Science and Higher Education of the Russian Federation, no. 121031700313-8. Publisher Copyright: © 2022 American Chemical Society.

PY - 2022/10/24

Y1 - 2022/10/24

N2 - Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide clusters with terminal cyanide ligands have been developed. Corresponding [M6X12(CN)12]4- (M = Nb, Ta; X = Cl, Br) can be accessed by ligand-exchange procedures from K4Nb6X18 (X = Cl, Br) and Bu4NCN, (Et4N)2[Ta6Cl18] and Bu4NCN and from [Ta6Br12(H2O)4Br2]·4H2O and KCN in moderate to high yields (50-80%). The products were isolated as Bu4N salts. The compounds were investigated both experimentally and by quantum chemistry, revealing correlations between structural, electrochemical, electrostatic, electronic, and topological features as a function of type of metal, halide, and charge.

AB - Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide clusters with terminal cyanide ligands have been developed. Corresponding [M6X12(CN)12]4- (M = Nb, Ta; X = Cl, Br) can be accessed by ligand-exchange procedures from K4Nb6X18 (X = Cl, Br) and Bu4NCN, (Et4N)2[Ta6Cl18] and Bu4NCN and from [Ta6Br12(H2O)4Br2]·4H2O and KCN in moderate to high yields (50-80%). The products were isolated as Bu4N salts. The compounds were investigated both experimentally and by quantum chemistry, revealing correlations between structural, electrochemical, electrostatic, electronic, and topological features as a function of type of metal, halide, and charge.

UR - http://www.scopus.com/inward/record.url?scp=85139235831&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.2c01824

DO - 10.1021/acs.inorgchem.2c01824

M3 - Article

C2 - 36162107

AN - SCOPUS:85139235831

VL - 61

SP - 16586

EP - 16595

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 42

ER -

ID: 38159325