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New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands. / Kostin, Gennadiy A; Kozlov, Ruslan; Bogomyakov, Artem et al.

In: International Journal of Molecular Sciences, Vol. 24, No. 17, 13371, 29.08.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Kostin, GA, Kozlov, R, Bogomyakov, A, Tolstikov, S, Sheven, D & Korenev, S 2023, 'New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands', International Journal of Molecular Sciences, vol. 24, no. 17, 13371. https://doi.org/10.3390/ijms241713371

APA

Kostin, G. A., Kozlov, R., Bogomyakov, A., Tolstikov, S., Sheven, D., & Korenev, S. (2023). New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands. International Journal of Molecular Sciences, 24(17), [13371]. https://doi.org/10.3390/ijms241713371

Vancouver

Kostin GA, Kozlov R, Bogomyakov A, Tolstikov S, Sheven D, Korenev S. New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands. International Journal of Molecular Sciences. 2023 Aug 29;24(17):13371. doi: 10.3390/ijms241713371

Author

Kostin, Gennadiy A ; Kozlov, Ruslan ; Bogomyakov, Artem et al. / New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands. In: International Journal of Molecular Sciences. 2023 ; Vol. 24, No. 17.

BibTeX

@article{cfe5a7da1da9413cb8b1a6f602831943,
title = "New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands",
abstract = "Two ruthenium nitrosyl complexes of Na[RuNOCl4L] with nitronyl nitroxide radicals coordinated to ruthenium with N-donor pyridine rings were prepared and described. The crystal structure of both complexes is 1D or 2D polymeric, due to the additional coordination of sodium cation by bridging the chloride ligands or oxygen atoms of nitroxides. Partially, the oligomeric forms remain in the solutions of the complexes in acetonitrile. The magnetic measurements in the solid state demonstrate the presence of antiferromagnetic interactions through the exchange channels, with the distance between paramagnetic centers equal to 3.1-3.9 {\AA}. The electrochemical behavior of the prepared complexes was investigated in acetonitrile solutions.",
keywords = "Ruthenium, Ligands, Nitric Oxide, Acetonitriles, Magnetic Phenomena",
author = "Kostin, {Gennadiy A} and Ruslan Kozlov and Artem Bogomyakov and Svyatoslav Tolstikov and Dmitriy Sheven and Sergey Korenev",
note = "Funding: This research was funded by the Russian Science Foundation (no. 22-23-00407) and supported by the Ministry of Science and Higher Education of the Russian Federation (no. 121031700313-8).",
year = "2023",
month = aug,
day = "29",
doi = "10.3390/ijms241713371",
language = "English",
volume = "24",
journal = "International Journal of Molecular Sciences",
issn = "1661-6596",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "17",

}

RIS

TY - JOUR

T1 - New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands

AU - Kostin, Gennadiy A

AU - Kozlov, Ruslan

AU - Bogomyakov, Artem

AU - Tolstikov, Svyatoslav

AU - Sheven, Dmitriy

AU - Korenev, Sergey

N1 - Funding: This research was funded by the Russian Science Foundation (no. 22-23-00407) and supported by the Ministry of Science and Higher Education of the Russian Federation (no. 121031700313-8).

PY - 2023/8/29

Y1 - 2023/8/29

N2 - Two ruthenium nitrosyl complexes of Na[RuNOCl4L] with nitronyl nitroxide radicals coordinated to ruthenium with N-donor pyridine rings were prepared and described. The crystal structure of both complexes is 1D or 2D polymeric, due to the additional coordination of sodium cation by bridging the chloride ligands or oxygen atoms of nitroxides. Partially, the oligomeric forms remain in the solutions of the complexes in acetonitrile. The magnetic measurements in the solid state demonstrate the presence of antiferromagnetic interactions through the exchange channels, with the distance between paramagnetic centers equal to 3.1-3.9 Å. The electrochemical behavior of the prepared complexes was investigated in acetonitrile solutions.

AB - Two ruthenium nitrosyl complexes of Na[RuNOCl4L] with nitronyl nitroxide radicals coordinated to ruthenium with N-donor pyridine rings were prepared and described. The crystal structure of both complexes is 1D or 2D polymeric, due to the additional coordination of sodium cation by bridging the chloride ligands or oxygen atoms of nitroxides. Partially, the oligomeric forms remain in the solutions of the complexes in acetonitrile. The magnetic measurements in the solid state demonstrate the presence of antiferromagnetic interactions through the exchange channels, with the distance between paramagnetic centers equal to 3.1-3.9 Å. The electrochemical behavior of the prepared complexes was investigated in acetonitrile solutions.

KW - Ruthenium

KW - Ligands

KW - Nitric Oxide

KW - Acetonitriles

KW - Magnetic Phenomena

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85170345219&origin=inward&txGid=c83715d6024a64a3637acb0908eaffb7

U2 - 10.3390/ijms241713371

DO - 10.3390/ijms241713371

M3 - Article

C2 - 37686176

VL - 24

JO - International Journal of Molecular Sciences

JF - International Journal of Molecular Sciences

SN - 1661-6596

IS - 17

M1 - 13371

ER -

ID: 55269062