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New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions. / Vernigora, A. A.; Brunilin, R. V.; Burmistrov, V. V. et al.

In: Doklady Chemistry, Vol. 512, No. 1, 09.2023, p. 260-265.

Research output: Contribution to journal › Article › peer-review

Harvard

Vernigora, AA, Brunilin, RV, Burmistrov, VV, Davidenko, AV, Nawrozkij, MB, Salykin, NA, Chernyshov, VV & Novakov, IA 2023, 'New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions', Doklady Chemistry, vol. 512, no. 1, pp. 260-265. https://doi.org/10.1134/S0012500823600700

APA

Vernigora, A. A., Brunilin, R. V., Burmistrov, V. V., Davidenko, A. V., Nawrozkij, M. B., Salykin, N. A., Chernyshov, V. V., & Novakov, I. A. (2023). New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions. Doklady Chemistry, 512(1), 260-265. https://doi.org/10.1134/S0012500823600700

Vancouver

Vernigora AA, Brunilin RV, Burmistrov VV, Davidenko AV, Nawrozkij MB, Salykin NA et al. New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions. Doklady Chemistry. 2023 Sept;512(1):260-265. doi: 10.1134/S0012500823600700

Author

Vernigora, A. A. ; Brunilin, R. V. ; Burmistrov, V. V. et al. / New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions. In: Doklady Chemistry. 2023 ; Vol. 512, No. 1. pp. 260-265.

BibTeX

@article{40f314602e3e4d7889b24080c12c5833,
title = "New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions",
abstract = "An efficient approach to the synthesis of (+)-camphor and (–)-fenchone anils has been developed, which involves the reaction of the corresponding bicyclic monoterpenoid ketones with substituted anilines in the presence of in situ prepared (i-PrO)2Ti(OTf)2·(i-PrOH)2 complex, as a homogeneous catalyst, and (i-PrO)4Ti, as a dehydrating agent. The advantage of the suggested method lies not only in obtaining target products in good yield and high purity, but also in a simplified procedure for their isolation. These products are of interest as potential pharmacologically active compounds, antioxidants for rubber mixtures, and components of 3D-printing formulations.",
keywords = "(+)-camphor, (–)-fenchone, anils, condensation, homogeneous catalysis",
author = "Vernigora, {A. A.} and Brunilin, {R. V.} and Burmistrov, {V. V.} and Davidenko, {A. V.} and Nawrozkij, {M. B.} and Salykin, {N. A.} and Chernyshov, {V. V.} and Novakov, {I. A.}",
note = "This work was supported by the Russian Science Foundation (project no. 22–13–20062, https://rscf.ru/project/22-13-20062 ) and the Administration of Volgograd oblast according to agreement no. 2 of June 10, 2022. Публикация для корректировки.",
year = "2023",
month = sep,
doi = "10.1134/S0012500823600700",
language = "English",
volume = "512",
pages = "260--265",
journal = "Doklady Chemistry",
issn = "0012-5008",
publisher = "PLEIADES PUBLISHING INC",
number = "1",

}

RIS

TY - JOUR

T1 - New Efficient Approach to the Preparation of (+)-Camphor and (–)-Fenchone Anils under Homogeneous Catalysis Conditions

AU - Vernigora, A. A.

AU - Brunilin, R. V.

AU - Burmistrov, V. V.

AU - Davidenko, A. V.

AU - Nawrozkij, M. B.

AU - Salykin, N. A.

AU - Chernyshov, V. V.

AU - Novakov, I. A.

N1 - This work was supported by the Russian Science Foundation (project no. 22–13–20062, https://rscf.ru/project/22-13-20062 ) and the Administration of Volgograd oblast according to agreement no. 2 of June 10, 2022. Публикация для корректировки.

PY - 2023/9

Y1 - 2023/9

N2 - An efficient approach to the synthesis of (+)-camphor and (–)-fenchone anils has been developed, which involves the reaction of the corresponding bicyclic monoterpenoid ketones with substituted anilines in the presence of in situ prepared (i-PrO)2Ti(OTf)2·(i-PrOH)2 complex, as a homogeneous catalyst, and (i-PrO)4Ti, as a dehydrating agent. The advantage of the suggested method lies not only in obtaining target products in good yield and high purity, but also in a simplified procedure for their isolation. These products are of interest as potential pharmacologically active compounds, antioxidants for rubber mixtures, and components of 3D-printing formulations.

AB - An efficient approach to the synthesis of (+)-camphor and (–)-fenchone anils has been developed, which involves the reaction of the corresponding bicyclic monoterpenoid ketones with substituted anilines in the presence of in situ prepared (i-PrO)2Ti(OTf)2·(i-PrOH)2 complex, as a homogeneous catalyst, and (i-PrO)4Ti, as a dehydrating agent. The advantage of the suggested method lies not only in obtaining target products in good yield and high purity, but also in a simplified procedure for their isolation. These products are of interest as potential pharmacologically active compounds, antioxidants for rubber mixtures, and components of 3D-printing formulations.

KW - (+)-camphor

KW - (–)-fenchone

KW - anils

KW - condensation

KW - homogeneous catalysis

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85180674840&origin=inward&txGid=7183949ff8287f83c528cf521661bb86

UR - https://www.mendeley.com/catalogue/5eb15903-3841-3d8d-b6c1-26f3b58bb63d/

U2 - 10.1134/S0012500823600700

DO - 10.1134/S0012500823600700

M3 - Article

VL - 512

SP - 260

EP - 265

JO - Doklady Chemistry

JF - Doklady Chemistry

SN - 0012-5008

IS - 1

ER -

ID: 59549140