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New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes. / Kovtunov, K. V.; Burueva, D. B.; Sviyazov, S. V. et al.

In: Russian Chemical Bulletin, Vol. 70, No. 12, 12.2021, p. 2382-2389.

Research output: Contribution to journal › Article › peer-review

Harvard

Kovtunov, KV, Burueva, DB, Sviyazov, SV, Salnikov, OG, Goodson, BM, Chekmenev, EY & Koptyug, IV 2021, 'New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes', Russian Chemical Bulletin, vol. 70, no. 12, pp. 2382-2389. https://doi.org/10.1007/s11172-021-3357-2

APA

Kovtunov, K. V., Burueva, D. B., Sviyazov, S. V., Salnikov, O. G., Goodson, B. M., Chekmenev, E. Y., & Koptyug, I. V. (2021). New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes. Russian Chemical Bulletin, 70(12), 2382-2389. https://doi.org/10.1007/s11172-021-3357-2

Vancouver

Kovtunov KV, Burueva DB, Sviyazov SV, Salnikov OG, Goodson BM, Chekmenev EY et al. New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes. Russian Chemical Bulletin. 2021 Dec;70(12):2382-2389. doi: 10.1007/s11172-021-3357-2

Author

Kovtunov, K. V. ; Burueva, D. B. ; Sviyazov, S. V. et al. / New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes. In: Russian Chemical Bulletin. 2021 ; Vol. 70, No. 12. pp. 2382-2389.

BibTeX

@article{658f4819eb1f4ae1837aa45c95a06ec8,
title = "New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes",
abstract = "The parahydrogen-induced polarization technique allows one to significantly enhance the NMR signal. Novel results on the parahydrogen-induced polarization of C2—C3 hydrocarbons using metal complexes are presented. Gaseous propane with the nuclear spin polarization level of at least 0.8% can be produced by bubbling parahydrogen through a solution of propylene and a homogeneous hydrogenation catalyst. Hydrogenation of acetylene with parahydrogen over Wilkinson{\textquoteright}s catalyst can result in the formation of hyperpolarized ethylene. The shape of the NMR lines indicates that this reaction proceeds as a syn-addition of molecular hydrogen. The reactions of several ethylene complexes of rhodium and platinum with parahydrogen were studied. The [Rh(η2-C2H4)2Cl]2 complex reacts with parahydrogen to form hyperpolarized ethane, whereas [Pt(η2-C2H4)(PPh3)2] converts to the hyperpolarized dihydride complex cis-[Pt(H)2(PPh3)2].",
keywords = "hydrogenation, hyperpolarization, metal complexes, NMR, parahydrogen, parahydrogen-induced polarization",
author = "Kovtunov, {K. V.} and Burueva, {D. B.} and Sviyazov, {S. V.} and Salnikov, {O. G.} and Goodson, {B. M.} and Chekmenev, {E. Y.} and Koptyug, {I. V.}",
note = "Funding Information: This work was financially supported by the Russian Foundation for Basic Research (Projects No. 19-29-10003 and No. 19-53-12013). Publisher Copyright: {\textcopyright} 2021, Springer Science+Business Media LLC.",
year = "2021",
month = dec,
doi = "10.1007/s11172-021-3357-2",
language = "English",
volume = "70",
pages = "2382--2389",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "12",

}

RIS

TY - JOUR

T1 - New aspects of parahydrogen-induced polarization for C2—C3 hydrocarbons using metal complexes

AU - Kovtunov, K. V.

AU - Burueva, D. B.

AU - Sviyazov, S. V.

AU - Salnikov, O. G.

AU - Goodson, B. M.

AU - Chekmenev, E. Y.

AU - Koptyug, I. V.

N1 - Funding Information: This work was financially supported by the Russian Foundation for Basic Research (Projects No. 19-29-10003 and No. 19-53-12013). Publisher Copyright: © 2021, Springer Science+Business Media LLC.

PY - 2021/12

Y1 - 2021/12

N2 - The parahydrogen-induced polarization technique allows one to significantly enhance the NMR signal. Novel results on the parahydrogen-induced polarization of C2—C3 hydrocarbons using metal complexes are presented. Gaseous propane with the nuclear spin polarization level of at least 0.8% can be produced by bubbling parahydrogen through a solution of propylene and a homogeneous hydrogenation catalyst. Hydrogenation of acetylene with parahydrogen over Wilkinson’s catalyst can result in the formation of hyperpolarized ethylene. The shape of the NMR lines indicates that this reaction proceeds as a syn-addition of molecular hydrogen. The reactions of several ethylene complexes of rhodium and platinum with parahydrogen were studied. The [Rh(η2-C2H4)2Cl]2 complex reacts with parahydrogen to form hyperpolarized ethane, whereas [Pt(η2-C2H4)(PPh3)2] converts to the hyperpolarized dihydride complex cis-[Pt(H)2(PPh3)2].

AB - The parahydrogen-induced polarization technique allows one to significantly enhance the NMR signal. Novel results on the parahydrogen-induced polarization of C2—C3 hydrocarbons using metal complexes are presented. Gaseous propane with the nuclear spin polarization level of at least 0.8% can be produced by bubbling parahydrogen through a solution of propylene and a homogeneous hydrogenation catalyst. Hydrogenation of acetylene with parahydrogen over Wilkinson’s catalyst can result in the formation of hyperpolarized ethylene. The shape of the NMR lines indicates that this reaction proceeds as a syn-addition of molecular hydrogen. The reactions of several ethylene complexes of rhodium and platinum with parahydrogen were studied. The [Rh(η2-C2H4)2Cl]2 complex reacts with parahydrogen to form hyperpolarized ethane, whereas [Pt(η2-C2H4)(PPh3)2] converts to the hyperpolarized dihydride complex cis-[Pt(H)2(PPh3)2].

KW - hydrogenation

KW - hyperpolarization

KW - metal complexes

KW - NMR

KW - parahydrogen

KW - parahydrogen-induced polarization

UR - http://www.scopus.com/inward/record.url?scp=85123539466&partnerID=8YFLogxK

U2 - 10.1007/s11172-021-3357-2

DO - 10.1007/s11172-021-3357-2

M3 - Article

AN - SCOPUS:85123539466

VL - 70

SP - 2382

EP - 2389

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 12

ER -

ID: 35385571