Research output: Contribution to journal › Article › peer-review
New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions. / Shmakov, Mikhail M.; Prikhod'ko, Sergey A.; Bardin, Vadim V. et al.
In: Mendeleev Communications, Vol. 28, No. 4, 01.07.2018, p. 369-371.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions
AU - Shmakov, Mikhail M.
AU - Prikhod'ko, Sergey A.
AU - Bardin, Vadim V.
AU - Adonin, Nicolay Yu
N1 - Publisher Copyright: © 2018
PY - 2018/7/1
Y1 - 2018/7/1
N2 - A new approach for preparation of aromatic and fluoroaromatic difluoroboranes via the interaction between corresponding aryltrifluoroborates and ionic liquids containing tetrachloroaluminate-anion and aluminum chloride has been developed. Catalytic properties of obtained aryldifluoroboranes have been investigated in model reactions of phenols alkylation. The dependence of catalytic properties on both the nature of solvent used and the type of substituents in the aromatic ring of difluoroborane has been established.[Figure presented]
AB - A new approach for preparation of aromatic and fluoroaromatic difluoroboranes via the interaction between corresponding aryltrifluoroborates and ionic liquids containing tetrachloroaluminate-anion and aluminum chloride has been developed. Catalytic properties of obtained aryldifluoroboranes have been investigated in model reactions of phenols alkylation. The dependence of catalytic properties on both the nature of solvent used and the type of substituents in the aromatic ring of difluoroborane has been established.[Figure presented]
KW - POLYFLUOROARYL ORGANOMETALLIC COMPOUNDS
UR - http://www.scopus.com/inward/record.url?scp=85051020946&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2018.07.009
DO - 10.1016/j.mencom.2018.07.009
M3 - Article
AN - SCOPUS:85051020946
VL - 28
SP - 369
EP - 371
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 4
ER -
ID: 16074468