Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine

Standard

Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine. / Gassan, Alena D.; Ivanov, Anton A.; Eltsov, Ilia V. et al.

In: European Journal of Inorganic Chemistry, Vol. 2020, No. 30, 16.08.2020, p. 2896-2899.

Research output: Contribution to journal › Article › peer-review

Harvard

Gassan, AD, Ivanov, AA, Eltsov, IV , Kuratieva, NV & Shestopalov, MA 2020, 'Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine', European Journal of Inorganic Chemistry, vol. 2020, no. 30, pp. 2896-2899. https://doi.org/10.1002/ejic.202000418

APA

Gassan, A. D., Ivanov, A. A., Eltsov, I. V., Kuratieva, N. V., & Shestopalov, M. A. (2020). Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine. European Journal of Inorganic Chemistry, 2020(30), 2896-2899. https://doi.org/10.1002/ejic.202000418

Vancouver

Gassan AD, Ivanov AA, Eltsov IV , Kuratieva NV, Shestopalov MA. Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine. European Journal of Inorganic Chemistry. 2020 Aug 16;2020(30):2896-2899. doi: 10.1002/ejic.202000418

Author

Gassan, Alena D. ; Ivanov, Anton A. ; Eltsov, Ilia V. et al. / Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine. In: European Journal of Inorganic Chemistry. 2020 ; Vol. 2020, No. 30. pp. 2896-2899.

BibTeX

@article{1689b4d9314545e2bb041d9970de9757,

title = "Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine",

abstract = "Despite the great prospects for the use of octahedral metal cluster complexes in various fields, chalcogenide tungsten compounds with functional organic ligands have practically not been studied. In this work, we present the synthesis and detailed characterization of a tungsten cluster with tris(2-cyanoethyl)phosphine [{W6S8}(P(C2H4CN)3)6]. The compound has been obtained directly from (Bu4N)2[{W6Cl8}Cl6] in one step with a good yield. The crystal structure, determined by single-crystal X-ray diffraction analysis, as well as multinuclear NMR analysis have well confirmed the formation of the chalcogenide neutral cluster. Moreover, the electrochemical properties of the complex have been studied.",

keywords = "Cluster compounds, Electrochemistry, Phosphine ligands, Structure elucidation, Tungsten, OXIDE, MOLYBDENUM, COMPLEXES, CELLULAR INTERNALIZATION, CLUSTOMESOGENS, P-31 NMR, LIGANDS, METAL, W6S8L6, HIGH-YIELD SYNTHESIS",

author = "Gassan, {Alena D.} and Ivanov, {Anton A.} and Eltsov, {Ilia V.} and Kuratieva, {Natalia V.} and Shestopalov, {Michael A.}",

year = "2020",

month = aug,

day = "16",

doi = "10.1002/ejic.202000418",

language = "English",

volume = "2020",

pages = "2896--2899",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "30",

}

RIS

TY - JOUR

T1 - Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine

AU - Gassan, Alena D.

AU - Ivanov, Anton A.

AU - Eltsov, Ilia V.

AU - Kuratieva, Natalia V.

AU - Shestopalov, Michael A.

PY - 2020/8/16

Y1 - 2020/8/16

N2 - Despite the great prospects for the use of octahedral metal cluster complexes in various fields, chalcogenide tungsten compounds with functional organic ligands have practically not been studied. In this work, we present the synthesis and detailed characterization of a tungsten cluster with tris(2-cyanoethyl)phosphine [{W6S8}(P(C2H4CN)3)6]. The compound has been obtained directly from (Bu4N)2[{W6Cl8}Cl6] in one step with a good yield. The crystal structure, determined by single-crystal X-ray diffraction analysis, as well as multinuclear NMR analysis have well confirmed the formation of the chalcogenide neutral cluster. Moreover, the electrochemical properties of the complex have been studied.

AB - Despite the great prospects for the use of octahedral metal cluster complexes in various fields, chalcogenide tungsten compounds with functional organic ligands have practically not been studied. In this work, we present the synthesis and detailed characterization of a tungsten cluster with tris(2-cyanoethyl)phosphine [{W6S8}(P(C2H4CN)3)6]. The compound has been obtained directly from (Bu4N)2[{W6Cl8}Cl6] in one step with a good yield. The crystal structure, determined by single-crystal X-ray diffraction analysis, as well as multinuclear NMR analysis have well confirmed the formation of the chalcogenide neutral cluster. Moreover, the electrochemical properties of the complex have been studied.

KW - Cluster compounds

KW - Electrochemistry

KW - Phosphine ligands

KW - Structure elucidation

KW - Tungsten

KW - OXIDE

KW - MOLYBDENUM

KW - COMPLEXES

KW - CELLULAR INTERNALIZATION

KW - CLUSTOMESOGENS

KW - P-31 NMR

KW - LIGANDS

KW - METAL

KW - W6S8L6

KW - HIGH-YIELD SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85087715785&partnerID=8YFLogxK

U2 - 10.1002/ejic.202000418

DO - 10.1002/ejic.202000418

M3 - Article

AN - SCOPUS:85087715785

VL - 2020

SP - 2896

EP - 2899

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 30

ER -

ID: 24753628