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Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties. / Simonova, E. A.; Kuznetsov, A. B.; Svetlichnyi, V. A. et al.

In: Materials Chemistry and Physics, Vol. 247, 122612, 01.06.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Simonova, EA, Kuznetsov, AB, Svetlichnyi, VA, Kononova, NG, Shevchenko, VS, Nigmatulina, EN, Kolesnichenko, MV, Kokh, KA, Rashchenko, SV & Kokh, AE 2020, 'Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties', Materials Chemistry and Physics, vol. 247, 122612. https://doi.org/10.1016/j.matchemphys.2019.122612

APA

Simonova, E. A., Kuznetsov, A. B., Svetlichnyi, V. A., Kononova, N. G., Shevchenko, V. S., Nigmatulina, E. N., Kolesnichenko, M. V., Kokh, K. A., Rashchenko, S. V., & Kokh, A. E. (2020). Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties. Materials Chemistry and Physics, 247, [122612]. https://doi.org/10.1016/j.matchemphys.2019.122612

Vancouver

Simonova EA, Kuznetsov AB, Svetlichnyi VA, Kononova NG, Shevchenko VS, Nigmatulina EN et al. Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties. Materials Chemistry and Physics. 2020 Jun 1;247:122612. doi: 10.1016/j.matchemphys.2019.122612

Author

Simonova, E. A. ; Kuznetsov, A. B. ; Svetlichnyi, V. A. et al. / Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties. In: Materials Chemistry and Physics. 2020 ; Vol. 247.

BibTeX

@article{992cf518e5374539827114b361337fb9,
title = "Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties",
abstract = "The LiBa12(BO3)7F4 crystals doped Nd3+ and Pr3+ were grown from high-temperature solution melts, using the TSSG method. All the samples have the wide absorption band in the visible range of 350–650 nm related to the dichroism, which is typical for other colored “antizeolites”. Strong radiation bands are associated with well known electronic transitions of Pr3+ (3P0 → 3H6 at 630 nm, 3P0 → 2F2 at 670 nm) and Nd3+ (4F3/2 → 4I9/2 at 875 nm, 4F3/2 → 4I11/2 at 1054 nm). In addition crystals of Nd-doped barium fluoride borate solid solutions NdxBa12(BO3)8-xF6x were grown from high temperature solution. Using X-ray single-crystal diffraction, the structure was solved and refined in I4/mcm space group that are similar to other colored “antizeolites” built with the positively charged framework of [Ba12(BO3)6]6+ cation pattern which contains channels built of alternating barium cubes and anticubes. According to the structure refinement of NdxBa12(BO3)8−xF6x, cube channel segments are populated mainly by [F4]4– and [NdF4]– clusters, whereas anticube ones – by (BO3)3– anions.",
keywords = "Crystal structure, Luminescence, Luminophores, Rare earth compounds, SYSTEM, EARTH, BORATE, NONLINEAR-OPTICAL PROPERTIES, GROWTH, BETA-BAB2O4, LAYER",
author = "Simonova, {E. A.} and Kuznetsov, {A. B.} and Svetlichnyi, {V. A.} and Kononova, {N. G.} and Shevchenko, {V. S.} and Nigmatulina, {E. N.} and Kolesnichenko, {M. V.} and Kokh, {K. A.} and Rashchenko, {S. V.} and Kokh, {A. E.}",
year = "2020",
month = jun,
day = "1",
doi = "10.1016/j.matchemphys.2019.122612",
language = "English",
volume = "247",
journal = "Materials Chemistry and Physics",
issn = "0254-0584",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties

AU - Simonova, E. A.

AU - Kuznetsov, A. B.

AU - Svetlichnyi, V. A.

AU - Kononova, N. G.

AU - Shevchenko, V. S.

AU - Nigmatulina, E. N.

AU - Kolesnichenko, M. V.

AU - Kokh, K. A.

AU - Rashchenko, S. V.

AU - Kokh, A. E.

PY - 2020/6/1

Y1 - 2020/6/1

N2 - The LiBa12(BO3)7F4 crystals doped Nd3+ and Pr3+ were grown from high-temperature solution melts, using the TSSG method. All the samples have the wide absorption band in the visible range of 350–650 nm related to the dichroism, which is typical for other colored “antizeolites”. Strong radiation bands are associated with well known electronic transitions of Pr3+ (3P0 → 3H6 at 630 nm, 3P0 → 2F2 at 670 nm) and Nd3+ (4F3/2 → 4I9/2 at 875 nm, 4F3/2 → 4I11/2 at 1054 nm). In addition crystals of Nd-doped barium fluoride borate solid solutions NdxBa12(BO3)8-xF6x were grown from high temperature solution. Using X-ray single-crystal diffraction, the structure was solved and refined in I4/mcm space group that are similar to other colored “antizeolites” built with the positively charged framework of [Ba12(BO3)6]6+ cation pattern which contains channels built of alternating barium cubes and anticubes. According to the structure refinement of NdxBa12(BO3)8−xF6x, cube channel segments are populated mainly by [F4]4– and [NdF4]– clusters, whereas anticube ones – by (BO3)3– anions.

AB - The LiBa12(BO3)7F4 crystals doped Nd3+ and Pr3+ were grown from high-temperature solution melts, using the TSSG method. All the samples have the wide absorption band in the visible range of 350–650 nm related to the dichroism, which is typical for other colored “antizeolites”. Strong radiation bands are associated with well known electronic transitions of Pr3+ (3P0 → 3H6 at 630 nm, 3P0 → 2F2 at 670 nm) and Nd3+ (4F3/2 → 4I9/2 at 875 nm, 4F3/2 → 4I11/2 at 1054 nm). In addition crystals of Nd-doped barium fluoride borate solid solutions NdxBa12(BO3)8-xF6x were grown from high temperature solution. Using X-ray single-crystal diffraction, the structure was solved and refined in I4/mcm space group that are similar to other colored “antizeolites” built with the positively charged framework of [Ba12(BO3)6]6+ cation pattern which contains channels built of alternating barium cubes and anticubes. According to the structure refinement of NdxBa12(BO3)8−xF6x, cube channel segments are populated mainly by [F4]4– and [NdF4]– clusters, whereas anticube ones – by (BO3)3– anions.

KW - Crystal structure

KW - Luminescence

KW - Luminophores

KW - Rare earth compounds

KW - SYSTEM

KW - EARTH

KW - BORATE

KW - NONLINEAR-OPTICAL PROPERTIES

KW - GROWTH

KW - BETA-BAB2O4

KW - LAYER

UR - http://www.scopus.com/inward/record.url?scp=85080883546&partnerID=8YFLogxK

U2 - 10.1016/j.matchemphys.2019.122612

DO - 10.1016/j.matchemphys.2019.122612

M3 - Article

AN - SCOPUS:85080883546

VL - 247

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

M1 - 122612

ER -

ID: 23735867