Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
Nanocomposite catalysts for transformation of biofuels into syngas and hydrogen : Fundamentals of design and performance, application in structured reactors and catalytic membranes. / Sadykov, V. A.; Arapova, M. V.; Smal, E. A. et al.
Catalysis. ed. / James J. Spivey; Yi-Fan Han; Dushyant Shekhawat. Royal Society of Chemistry, 2019. p. 216-241 (Catalysis; Vol. 31).Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
}
TY - CHAP
T1 - Nanocomposite catalysts for transformation of biofuels into syngas and hydrogen
T2 - Fundamentals of design and performance, application in structured reactors and catalytic membranes
AU - Sadykov, V. A.
AU - Arapova, M. V.
AU - Smal, E. A.
AU - Pavlova, S. N.
AU - Bobrova, L. N.
AU - Eremeev, N. F.
AU - Mezentseva, N. V.
AU - Simonov, M. N.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - In this review problems related to design and performance of stable and efficient catalysts of biogas/biofuels transformation into syngas and hydrogen based on nanocrystalline oxides with fluorite, perovskite and spinel oxides and their nanocomposites promoted by nanoparticles of Pt group metals and Ni-based alloys are considered. Tailor-made design of these catalysts is based upon elucidation of the relationships between their synthesis procedure, composition, real structure/microstructure, surface properties, oxygen mobility and reactivity determined in a great extent by the metal-support interaction, which requires application of modern sophisticated structural, spectroscopic, kinetic (including in situ FTIRS and isotope transients) methods and mathematical modeling. Thin layers of these optimized catalysts supported on structured heat-conducting substrates, asymmetric supported oxygen or hydrogen separation membranes demonstrated high and stable performance in transformation of biogas and biofuels into syngas and hydrogen.
AB - In this review problems related to design and performance of stable and efficient catalysts of biogas/biofuels transformation into syngas and hydrogen based on nanocrystalline oxides with fluorite, perovskite and spinel oxides and their nanocomposites promoted by nanoparticles of Pt group metals and Ni-based alloys are considered. Tailor-made design of these catalysts is based upon elucidation of the relationships between their synthesis procedure, composition, real structure/microstructure, surface properties, oxygen mobility and reactivity determined in a great extent by the metal-support interaction, which requires application of modern sophisticated structural, spectroscopic, kinetic (including in situ FTIRS and isotope transients) methods and mathematical modeling. Thin layers of these optimized catalysts supported on structured heat-conducting substrates, asymmetric supported oxygen or hydrogen separation membranes demonstrated high and stable performance in transformation of biogas and biofuels into syngas and hydrogen.
UR - http://www.scopus.com/inward/record.url?scp=85062423611&partnerID=8YFLogxK
U2 - 10.1039/9781788016971-00216
DO - 10.1039/9781788016971-00216
M3 - Chapter
AN - SCOPUS:85062423611
T3 - Catalysis
SP - 216
EP - 241
BT - Catalysis
A2 - Spivey, James J.
A2 - Han, Yi-Fan
A2 - Shekhawat, Dushyant
PB - Royal Society of Chemistry
ER -
ID: 18678139