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Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls. / Tretyakov, E. V.; Makhneva, T. V.; Politanskaya, L. V. et al.

In: Journal of Structural Chemistry, Vol. 59, No. 3, 01.05.2018, p. 689-696.

Research output: Contribution to journal › Article › peer-review

Harvard

Tretyakov, EV, Makhneva, TV, Politanskaya, LV, Bagryanskaya, IY & Stass, DV 2018, 'Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls', Journal of Structural Chemistry, vol. 59, no. 3, pp. 689-696. https://doi.org/10.1134/S0022476618030289

APA

Tretyakov, E. V., Makhneva, T. V., Politanskaya, L. V., Bagryanskaya, I. Y., & Stass, D. V. (2018). Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls. Journal of Structural Chemistry, 59(3), 689-696. https://doi.org/10.1134/S0022476618030289

Vancouver

Tretyakov EV, Makhneva TV, Politanskaya LV, Bagryanskaya IY, Stass DV. Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls. Journal of Structural Chemistry. 2018 May 1;59(3):689-696. doi: 10.1134/S0022476618030289

Author

Tretyakov, E. V. ; Makhneva, T. V. ; Politanskaya, L. V. et al. / Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 3. pp. 689-696.

BibTeX

@article{5ca8727b35044d6f82d54d3fae4fedc1,
title = "Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls",
abstract = "By cross-coupling of 2-iodo-polyfluoroanilines with a [AuPPh3NN] complex (where NN is 4,4,5,5- tetramethyl-3-oxide-1-oxyl-2-imidazolin-2-ide) in the presence of [Pd(PPh3)4], nitroxide radicals (2-aminopolyfluorophenyl- 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyls) are synthesized. Their molecular and crystal structures are determined by the X-ray crystallographic analysis. It is shown that in the solid phase there are both intra- and intermolecular hydrogen bonds between NH2 groups and O atoms of paramagnetic fragments, which link the molecules into chains or dimers.",
keywords = "anilines, crystal structure, hydrogen bonds, nitronyl nitroxides, polyfluorine compounds",
author = "Tretyakov, {E. V.} and Makhneva, {T. V.} and Politanskaya, {L. V.} and Bagryanskaya, {I. Yu} and Stass, {D. V.}",
year = "2018",
month = may,
day = "1",
doi = "10.1134/S0022476618030289",
language = "English",
volume = "59",
pages = "689--696",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol- 3-Oxide-1-Oxyls

AU - Tretyakov, E. V.

AU - Makhneva, T. V.

AU - Politanskaya, L. V.

AU - Bagryanskaya, I. Yu

AU - Stass, D. V.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - By cross-coupling of 2-iodo-polyfluoroanilines with a [AuPPh3NN] complex (where NN is 4,4,5,5- tetramethyl-3-oxide-1-oxyl-2-imidazolin-2-ide) in the presence of [Pd(PPh3)4], nitroxide radicals (2-aminopolyfluorophenyl- 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyls) are synthesized. Their molecular and crystal structures are determined by the X-ray crystallographic analysis. It is shown that in the solid phase there are both intra- and intermolecular hydrogen bonds between NH2 groups and O atoms of paramagnetic fragments, which link the molecules into chains or dimers.

AB - By cross-coupling of 2-iodo-polyfluoroanilines with a [AuPPh3NN] complex (where NN is 4,4,5,5- tetramethyl-3-oxide-1-oxyl-2-imidazolin-2-ide) in the presence of [Pd(PPh3)4], nitroxide radicals (2-aminopolyfluorophenyl- 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyls) are synthesized. Their molecular and crystal structures are determined by the X-ray crystallographic analysis. It is shown that in the solid phase there are both intra- and intermolecular hydrogen bonds between NH2 groups and O atoms of paramagnetic fragments, which link the molecules into chains or dimers.

KW - anilines

KW - crystal structure

KW - hydrogen bonds

KW - nitronyl nitroxides

KW - polyfluorine compounds

UR - http://www.scopus.com/inward/record.url?scp=85049660458&partnerID=8YFLogxK

U2 - 10.1134/S0022476618030289

DO - 10.1134/S0022476618030289

M3 - Article

AN - SCOPUS:85049660458

VL - 59

SP - 689

EP - 696

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 14423302