Research output: Contribution to journal › Article › peer-review
Modifying the La0.6Sr0.4Co0.2Fe0.8O3 – δ Cathodic Material by Ferroactive Molybdenum Cation. / Voloshin, B. V.; Koshevoi, E. I.; Ulihin, A. S. et al.
In: Russian Journal of Electrochemistry, Vol. 58, No. 3, 2, 03.2022, p. 163-167.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Modifying the La0.6Sr0.4Co0.2Fe0.8O3 – δ Cathodic Material by Ferroactive Molybdenum Cation
AU - Voloshin, B. V.
AU - Koshevoi, E. I.
AU - Ulihin, A. S.
AU - Popov, M. P.
AU - Nemudry, A. P.
N1 - Funding Information: This study was supported by the President of the Russian Federation (Grant for Young Scientists MK-550.2020.3). Publisher Copyright: © 2022, Pleiades Publishing, Ltd.
PY - 2022/3
Y1 - 2022/3
N2 - It is shown that the substitution of 5% ferroactive molybdenum cations for iron to the La0.6Sr0.4Co0.2Fe0.8O3 – δ (LSCF) structure leads to a considerable increase in the electric conductivity. Using the powder X-ray diffraction technique, the solubility limit of molybdenum in the structure of rhombohedral perovskite is found. It is noted that the transport characteristics of perovskite with the La0.6Sr0.4Co0.2Fe0.75Mo0.05O3 – δ (LSCFM5) composition are sufficient for using it as the cathode material in intermediate temperature solid oxide fuel cells (IT SOFCs).
AB - It is shown that the substitution of 5% ferroactive molybdenum cations for iron to the La0.6Sr0.4Co0.2Fe0.8O3 – δ (LSCF) structure leads to a considerable increase in the electric conductivity. Using the powder X-ray diffraction technique, the solubility limit of molybdenum in the structure of rhombohedral perovskite is found. It is noted that the transport characteristics of perovskite with the La0.6Sr0.4Co0.2Fe0.75Mo0.05O3 – δ (LSCFM5) composition are sufficient for using it as the cathode material in intermediate temperature solid oxide fuel cells (IT SOFCs).
KW - cathode
KW - electronic conduction
KW - IT SOFC
KW - oxygen exchange
KW - perovskites
UR - http://www.scopus.com/inward/record.url?scp=85127413506&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/cb4e9ab9-9ced-3c2d-b219-80361e878b58/
U2 - 10.1134/S1023193522020112
DO - 10.1134/S1023193522020112
M3 - Article
AN - SCOPUS:85127413506
VL - 58
SP - 163
EP - 167
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 3
M1 - 2
ER -
ID: 35842084