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[Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−. / Mironova, Alina; Gushchin, Artem; Abramov, Pavel et al.

In: Polyhedron, Vol. 205, 115282, 01.09.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Mironova, A, Gushchin, A, Abramov, P, Eltsov, I, Ryadun, A & Sokolov, M 2021, '[Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−', Polyhedron, vol. 205, 115282. https://doi.org/10.1016/j.poly.2021.115282

APA

Mironova, A., Gushchin, A., Abramov, P., Eltsov, I., Ryadun, A., & Sokolov, M. (2021). [Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−. Polyhedron, 205, [115282]. https://doi.org/10.1016/j.poly.2021.115282

Vancouver

Mironova A, Gushchin A, Abramov P, Eltsov I, Ryadun A, Sokolov M. [Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−. Polyhedron. 2021 Sept 1;205:115282. doi: 10.1016/j.poly.2021.115282

Author

Mironova, Alina ; Gushchin, Artem ; Abramov, Pavel et al. / [Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−. In: Polyhedron. 2021 ; Vol. 205.

BibTeX

@article{8142341105364e6c9272d10b976c5196,
title = "[Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−",
abstract = "(Bu4N)2[Mo6I8(N3)6] undergoes [3+2] cycloaddition with benzonitrile or 2,3,4,5,6-pentafluorobenzonitrile in the presence of I2 catalyst with the formation of novel hexakis(tetrazolate)complexes, (Bu4N)2[Mo6I8(N4C-Ar)6] (Ar = C6H5 (1), C6F5 (2)) with coordinated 2,5-tetrazolyl ligands. The products were characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. The complexes undergo quasi reversible oxidation and are red-light emissive upon UV photoexcitation.",
keywords = "Luminescence, NMR, Octahedral cluster, Tetrazolate complex, X-ray single crystal diffraction, [3+2]-Cycloaddition",
author = "Alina Mironova and Artem Gushchin and Pavel Abramov and Ilia Eltsov and Alexey Ryadun and Maxim Sokolov",
note = "Funding Information: Financial support from RFBR (20-03-00410) for the synthetic work is gratefully acknowledged. Publisher Copyright: {\textcopyright} 2021 Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = sep,
day = "1",
doi = "10.1016/j.poly.2021.115282",
language = "English",
volume = "205",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - [Mo6I8]4+ complexes with tetrazolate ligands6 [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2−

AU - Mironova, Alina

AU - Gushchin, Artem

AU - Abramov, Pavel

AU - Eltsov, Ilia

AU - Ryadun, Alexey

AU - Sokolov, Maxim

N1 - Funding Information: Financial support from RFBR (20-03-00410) for the synthetic work is gratefully acknowledged. Publisher Copyright: © 2021 Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/9/1

Y1 - 2021/9/1

N2 - (Bu4N)2[Mo6I8(N3)6] undergoes [3+2] cycloaddition with benzonitrile or 2,3,4,5,6-pentafluorobenzonitrile in the presence of I2 catalyst with the formation of novel hexakis(tetrazolate)complexes, (Bu4N)2[Mo6I8(N4C-Ar)6] (Ar = C6H5 (1), C6F5 (2)) with coordinated 2,5-tetrazolyl ligands. The products were characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. The complexes undergo quasi reversible oxidation and are red-light emissive upon UV photoexcitation.

AB - (Bu4N)2[Mo6I8(N3)6] undergoes [3+2] cycloaddition with benzonitrile or 2,3,4,5,6-pentafluorobenzonitrile in the presence of I2 catalyst with the formation of novel hexakis(tetrazolate)complexes, (Bu4N)2[Mo6I8(N4C-Ar)6] (Ar = C6H5 (1), C6F5 (2)) with coordinated 2,5-tetrazolyl ligands. The products were characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. The complexes undergo quasi reversible oxidation and are red-light emissive upon UV photoexcitation.

KW - Luminescence

KW - NMR

KW - Octahedral cluster

KW - Tetrazolate complex

KW - X-ray single crystal diffraction

KW - [3+2]-Cycloaddition

UR - http://www.scopus.com/inward/record.url?scp=85107080064&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/0632418a-955b-37a3-92af-86de8f84c617/

U2 - 10.1016/j.poly.2021.115282

DO - 10.1016/j.poly.2021.115282

M3 - Article

AN - SCOPUS:85107080064

VL - 205

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 115282

ER -

ID: 29237510