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Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence. / Mikhaylov, M. A.; Sukhikh, T. S.; Sheven’, D. G. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 50, No. 7, 07.2024, p. 492-499.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhaylov, MA, Sukhikh, TS, Sheven’, DG, Berezin, AS, Sokolov, MN & Kompan’kov, NB 2024, 'Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 50, no. 7, pp. 492-499. https://doi.org/10.1134/S1070328424600190

APA

Mikhaylov, M. A., Sukhikh, T. S., Sheven’, D. G., Berezin, A. S., Sokolov, M. N., & Kompan’kov, N. B. (2024). Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 50(7), 492-499. https://doi.org/10.1134/S1070328424600190

Vancouver

Mikhaylov MA, Sukhikh TS, Sheven’ DG, Berezin AS, Sokolov MN, Kompan’kov NB. Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2024 Jul;50(7):492-499. doi: 10.1134/S1070328424600190

Author

Mikhaylov, M. A. ; Sukhikh, T. S. ; Sheven’, D. G. et al. / Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2024 ; Vol. 50, No. 7. pp. 492-499.

BibTeX

@article{5fa01439c8f441bc9e70f61a3d95ca4c,
title = "Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence",
abstract = "Abstract: New methylsulfate complex (Bu4N)2[Мо6I8(O3SOCH3)6] (I) is synthesized by the reaction of (Bu4N)2[Mo6I8(C≡C–C(O)OCH3)6] with dimethyl sulfate (CH3)2SO4. According to the XRD data, the molybdenum atoms are coordinated by the monodentate methylsulfate ligands. In a DMSO solution, the complex undergoes solvolysis accompanied by the complete substitution of the methylsulfate ligands by the solvent molecules. A powder sample of cluster I luminesces (phosphorescence) with the emission maximum at a wavelength of 620 nm (77 K). Increasing temperature to 300 K results in the shift of the emission maximum to 650 nm and a decrease in the integral intensity by 1.6 times.",
keywords = "clusters, crystal structure, luminescence properties, methyl sulfate, molybdenum, solvolysis",
author = "Mikhaylov, {M. A.} and Sukhikh, {T. S.} and Sheven{\textquoteright}, {D. G.} and Berezin, {A. S.} and Sokolov, {M. N.} and Kompan{\textquoteright}kov, {N. B.}",
note = "This work was supported by the Ministry of Science and Higher Education of the Russian Federation, project no. 121031700313-8.",
year = "2024",
month = jul,
doi = "10.1134/S1070328424600190",
language = "English",
volume = "50",
pages = "492--499",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - Methylsulfate Complex (Bu4N)2[Мo6I8(O3SOCH3)6]: Synthesis, Structure, Lability of Ligands, and Phosphorescence

AU - Mikhaylov, M. A.

AU - Sukhikh, T. S.

AU - Sheven’, D. G.

AU - Berezin, A. S.

AU - Sokolov, M. N.

AU - Kompan’kov, N. B.

N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation, project no. 121031700313-8.

PY - 2024/7

Y1 - 2024/7

N2 - Abstract: New methylsulfate complex (Bu4N)2[Мо6I8(O3SOCH3)6] (I) is synthesized by the reaction of (Bu4N)2[Mo6I8(C≡C–C(O)OCH3)6] with dimethyl sulfate (CH3)2SO4. According to the XRD data, the molybdenum atoms are coordinated by the monodentate methylsulfate ligands. In a DMSO solution, the complex undergoes solvolysis accompanied by the complete substitution of the methylsulfate ligands by the solvent molecules. A powder sample of cluster I luminesces (phosphorescence) with the emission maximum at a wavelength of 620 nm (77 K). Increasing temperature to 300 K results in the shift of the emission maximum to 650 nm and a decrease in the integral intensity by 1.6 times.

AB - Abstract: New methylsulfate complex (Bu4N)2[Мо6I8(O3SOCH3)6] (I) is synthesized by the reaction of (Bu4N)2[Mo6I8(C≡C–C(O)OCH3)6] with dimethyl sulfate (CH3)2SO4. According to the XRD data, the molybdenum atoms are coordinated by the monodentate methylsulfate ligands. In a DMSO solution, the complex undergoes solvolysis accompanied by the complete substitution of the methylsulfate ligands by the solvent molecules. A powder sample of cluster I luminesces (phosphorescence) with the emission maximum at a wavelength of 620 nm (77 K). Increasing temperature to 300 K results in the shift of the emission maximum to 650 nm and a decrease in the integral intensity by 1.6 times.

KW - clusters

KW - crystal structure

KW - luminescence properties

KW - methyl sulfate

KW - molybdenum

KW - solvolysis

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85201696914&origin=inward&txGid=af08bcb9787d651580831badb7d9f982

UR - https://www.mendeley.com/catalogue/f792105d-9f6b-3989-8b9c-55e6687f1e6e/

U2 - 10.1134/S1070328424600190

DO - 10.1134/S1070328424600190

M3 - Article

VL - 50

SP - 492

EP - 499

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 7

ER -

ID: 60862319