Standard

Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions. / Shushakov, Anton A.; Matveeva, Svetlana G.; Pozdnyakov, Ivan P. et al.

In: Photochemical and Photobiological Sciences, Vol. 19, No. 9, 09.2020, p. 1222-1229.

Research output: Contribution to journal › Article › peer-review

Harvard

Shushakov, AA, Matveeva, SG, Pozdnyakov, IP, Grivin, VP, Plyusnin, VF, Vasilchenko, DB, Melnikov, AA, Chekalin, SV & Glebov, EM 2020, 'Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions', Photochemical and Photobiological Sciences, vol. 19, no. 9, pp. 1222-1229. https://doi.org/10.1039/d0pp00178c

APA

Shushakov, A. A., Matveeva, S. G., Pozdnyakov, I. P., Grivin, V. P., Plyusnin, V. F., Vasilchenko, D. B., Melnikov, A. A., Chekalin, S. V., & Glebov, E. M. (2020). Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions. Photochemical and Photobiological Sciences, 19(9), 1222-1229. https://doi.org/10.1039/d0pp00178c

Vancouver

Shushakov AA, Matveeva SG, Pozdnyakov IP, Grivin VP, Plyusnin VF, Vasilchenko DB et al. Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions. Photochemical and Photobiological Sciences. 2020 Sept;19(9):1222-1229. doi: 10.1039/d0pp00178c

Author

Shushakov, Anton A. ; Matveeva, Svetlana G. ; Pozdnyakov, Ivan P. et al. / Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions. In: Photochemical and Photobiological Sciences. 2020 ; Vol. 19, No. 9. pp. 1222-1229.

BibTeX

@article{eeeb83ca703d4f6ea40c64339f32217b,
title = "Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions",
abstract = "It is known thattrans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution oftrans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.",
keywords = "RUTHENIUM(III), PHOTOPHYSICS, FE(III)",
author = "Shushakov, {Anton A.} and Matveeva, {Svetlana G.} and Pozdnyakov, {Ivan P.} and Grivin, {Vjacheslav P.} and Plyusnin, {Victor F.} and Vasilchenko, {Danila B.} and Melnikov, {Alexei A.} and Chekalin, {Sergei V.} and Glebov, {Evgeni M.}",
year = "2020",
month = sep,
doi = "10.1039/d0pp00178c",
language = "English",
volume = "19",
pages = "1222--1229",
journal = "Photochemical and Photobiological Sciences",
issn = "1474-905X",
publisher = "Royal Society of Chemistry",
number = "9",

}

RIS

TY - JOUR

T1 - Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions

AU - Shushakov, Anton A.

AU - Matveeva, Svetlana G.

AU - Pozdnyakov, Ivan P.

AU - Grivin, Vjacheslav P.

AU - Plyusnin, Victor F.

AU - Vasilchenko, Danila B.

AU - Melnikov, Alexei A.

AU - Chekalin, Sergei V.

AU - Glebov, Evgeni M.

PY - 2020/9

Y1 - 2020/9

N2 - It is known thattrans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution oftrans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.

AB - It is known thattrans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution oftrans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.

KW - RUTHENIUM(III)

KW - PHOTOPHYSICS

KW - FE(III)

UR - http://www.scopus.com/inward/record.url?scp=85091127293&partnerID=8YFLogxK

U2 - 10.1039/d0pp00178c

DO - 10.1039/d0pp00178c

M3 - Article

C2 - 32748912

AN - SCOPUS:85091127293

VL - 19

SP - 1222

EP - 1229

JO - Photochemical and Photobiological Sciences

JF - Photochemical and Photobiological Sciences

SN - 1474-905X

IS - 9

ER -

ID: 25648806