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Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform. / Matveeva, Svetlana G.; Grivin, Vjacheslav P.; Plyusnin, Victor F. et al.

In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 359, 15.05.2018, p. 80-86.

Research output: Contribution to journal › Article › peer-review

Harvard

Matveeva, SG, Grivin, VP, Plyusnin, VF, Vasilchenko, DB & Glebov, EM 2018, 'Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform', Journal of Photochemistry and Photobiology A: Chemistry, vol. 359, pp. 80-86. https://doi.org/10.1016/j.jphotochem.2018.03.038

APA

Matveeva, S. G., Grivin, V. P., Plyusnin, V. F., Vasilchenko, D. B., & Glebov, E. M. (2018). Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform. Journal of Photochemistry and Photobiology A: Chemistry, 359, 80-86. https://doi.org/10.1016/j.jphotochem.2018.03.038

Vancouver

Matveeva SG, Grivin VP, Plyusnin VF, Vasilchenko DB, Glebov EM. Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform. Journal of Photochemistry and Photobiology A: Chemistry. 2018 May 15;359:80-86. doi: 10.1016/j.jphotochem.2018.03.038

Author

Matveeva, Svetlana G. ; Grivin, Vjacheslav P. ; Plyusnin, Victor F. et al. / Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform. In: Journal of Photochemistry and Photobiology A: Chemistry. 2018 ; Vol. 359. pp. 80-86.

BibTeX

@article{264c381e5abf486a8e594d925d3c5b40,
title = "Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform",
abstract = "Photochemistry of the (n-Bu4N)2[PtCl6] complex in chloroform was studied by means of stationary photolysis and nanosecond laser flash photolysis. The results were explained in the framework of the chain photosolvation. The chain character of photolysis was supported by the quantum yield dependencies on the concentration of the initial complex and light intensity. Spectra of two successive Pt(III) intermediates were registered, their spectral and kinetic characteristics were determined. Based on the obtained experimental data, the literature mechanism of photolysis was revised.",
keywords = "Chain photochemical reactions, Chloroform, Laser flash photolysis, Photochemistry, Photosolvation, Platinum(IV) complexes, AQUEOUS-SOLUTIONS, METHANOL, FLASH-PHOTOLYSIS, REDUCTION, PHOTOREDUCTION, SOLVENT-INITIATED PHOTOCHEMISTRY, PTCL62-COMPLEX, HEXACHLOROPLATINATE(IV), CHLORIDE, PHOTOOXIDATION",
author = "Matveeva, {Svetlana G.} and Grivin, {Vjacheslav P.} and Plyusnin, {Victor F.} and Vasilchenko, {Danila B.} and Glebov, {Evgeni M.}",
year = "2018",
month = may,
day = "15",
doi = "10.1016/j.jphotochem.2018.03.038",
language = "English",
volume = "359",
pages = "80--86",
journal = "Journal of Photochemistry and Photobiology A: Chemistry",
issn = "1010-6030",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform

AU - Matveeva, Svetlana G.

AU - Grivin, Vjacheslav P.

AU - Plyusnin, Victor F.

AU - Vasilchenko, Danila B.

AU - Glebov, Evgeni M.

PY - 2018/5/15

Y1 - 2018/5/15

N2 - Photochemistry of the (n-Bu4N)2[PtCl6] complex in chloroform was studied by means of stationary photolysis and nanosecond laser flash photolysis. The results were explained in the framework of the chain photosolvation. The chain character of photolysis was supported by the quantum yield dependencies on the concentration of the initial complex and light intensity. Spectra of two successive Pt(III) intermediates were registered, their spectral and kinetic characteristics were determined. Based on the obtained experimental data, the literature mechanism of photolysis was revised.

AB - Photochemistry of the (n-Bu4N)2[PtCl6] complex in chloroform was studied by means of stationary photolysis and nanosecond laser flash photolysis. The results were explained in the framework of the chain photosolvation. The chain character of photolysis was supported by the quantum yield dependencies on the concentration of the initial complex and light intensity. Spectra of two successive Pt(III) intermediates were registered, their spectral and kinetic characteristics were determined. Based on the obtained experimental data, the literature mechanism of photolysis was revised.

KW - Chain photochemical reactions

KW - Chloroform

KW - Laser flash photolysis

KW - Photochemistry

KW - Photosolvation

KW - Platinum(IV) complexes

KW - AQUEOUS-SOLUTIONS

KW - METHANOL

KW - FLASH-PHOTOLYSIS

KW - REDUCTION

KW - PHOTOREDUCTION

KW - SOLVENT-INITIATED PHOTOCHEMISTRY

KW - PTCL62-COMPLEX

KW - HEXACHLOROPLATINATE(IV)

KW - CHLORIDE

KW - PHOTOOXIDATION

UR - http://www.scopus.com/inward/record.url?scp=85044946121&partnerID=8YFLogxK

U2 - 10.1016/j.jphotochem.2018.03.038

DO - 10.1016/j.jphotochem.2018.03.038

M3 - Article

AN - SCOPUS:85044946121

VL - 359

SP - 80

EP - 86

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

SN - 1010-6030

ER -

ID: 12415909