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Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs. / Borovkov, V. I.; Bagryansky, V. A.; Letyagin, G. A. et al.

In: Chemical Physics Letters, Vol. 712, 16.11.2018, p. 208-213.

Research output: Contribution to journal › Article › peer-review

Harvard

Borovkov, VI, Bagryansky, VA, Letyagin, GA, Beregovaya, IV, Shchegoleva, LN & Molin, YN 2018, 'Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs', Chemical Physics Letters, vol. 712, pp. 208-213. https://doi.org/10.1016/j.cplett.2018.10.004

APA

Borovkov, V. I., Bagryansky, V. A., Letyagin, G. A., Beregovaya, I. V., Shchegoleva, L. N., & Molin, Y. N. (2018). Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs. Chemical Physics Letters, 712, 208-213. https://doi.org/10.1016/j.cplett.2018.10.004

Vancouver

Borovkov VI, Bagryansky VA, Letyagin GA, Beregovaya IV, Shchegoleva LN, Molin YN. Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs. Chemical Physics Letters. 2018 Nov 16;712:208-213. doi: 10.1016/j.cplett.2018.10.004

Author

Borovkov, V. I. ; Bagryansky, V. A. ; Letyagin, G. A. et al. / Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs. In: Chemical Physics Letters. 2018 ; Vol. 712. pp. 208-213.

BibTeX

@article{0dc76dfc21cc4a788a715463dc26b80f,
title = "Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs",
abstract = "The effect of an external magnetic field on the radiation-induced fluorescence of tricosane (n-C23H48), doped with luminophore, was studied on the nanosecond timescale. It was found that the characteristic frequency of quantum beats caused by the difference between the Zeeman interactions of dopant radical anions and tricosane radical cations increased substantially upon transition from the liquid to the crystal phase. Experimental data were in agreement with both the quantum-chemical calculations and theoretical spin evolution simulations, assuming that hyperfine couplings and transverse components of the tricosane radical cation g-tensor were averaged out by degenerate positive charge transfer in the tricosane crystal.",
keywords = "N-ALKANES, CATIONS",
author = "Borovkov, {V. I.} and Bagryansky, {V. A.} and Letyagin, {G. A.} and Beregovaya, {I. V.} and Shchegoleva, {L. N.} and Molin, {Y. N.}",
note = "Publisher Copyright: {\textcopyright} 2018",
year = "2018",
month = nov,
day = "16",
doi = "10.1016/j.cplett.2018.10.004",
language = "English",
volume = "712",
pages = "208--213",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Manifestation of g-tensor anisotropy in the quantum beats of spin-correlated radical ion pairs

AU - Borovkov, V. I.

AU - Bagryansky, V. A.

AU - Letyagin, G. A.

AU - Beregovaya, I. V.

AU - Shchegoleva, L. N.

AU - Molin, Y. N.

N1 - Publisher Copyright: © 2018

PY - 2018/11/16

Y1 - 2018/11/16

N2 - The effect of an external magnetic field on the radiation-induced fluorescence of tricosane (n-C23H48), doped with luminophore, was studied on the nanosecond timescale. It was found that the characteristic frequency of quantum beats caused by the difference between the Zeeman interactions of dopant radical anions and tricosane radical cations increased substantially upon transition from the liquid to the crystal phase. Experimental data were in agreement with both the quantum-chemical calculations and theoretical spin evolution simulations, assuming that hyperfine couplings and transverse components of the tricosane radical cation g-tensor were averaged out by degenerate positive charge transfer in the tricosane crystal.

AB - The effect of an external magnetic field on the radiation-induced fluorescence of tricosane (n-C23H48), doped with luminophore, was studied on the nanosecond timescale. It was found that the characteristic frequency of quantum beats caused by the difference between the Zeeman interactions of dopant radical anions and tricosane radical cations increased substantially upon transition from the liquid to the crystal phase. Experimental data were in agreement with both the quantum-chemical calculations and theoretical spin evolution simulations, assuming that hyperfine couplings and transverse components of the tricosane radical cation g-tensor were averaged out by degenerate positive charge transfer in the tricosane crystal.

KW - N-ALKANES

KW - CATIONS

UR - http://www.scopus.com/inward/record.url?scp=85054589177&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2018.10.004

DO - 10.1016/j.cplett.2018.10.004

M3 - Article

AN - SCOPUS:85054589177

VL - 712

SP - 208

EP - 213

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

ER -

ID: 17039784