Research output: Contribution to journal › Article › peer-review
Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex. / Vinogradova, Katerina A.; Pishchur, Denis P.; Korolkov, Ilya V. et al.
In: Inorganic Chemistry Communications, Vol. 105, 01.07.2019, p. 82-85.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex
AU - Vinogradova, Katerina A.
AU - Pishchur, Denis P.
AU - Korolkov, Ilya V.
AU - Bushuev, Mark B.
N1 - Publisher Copyright: © 2019 Elsevier B.V.
PY - 2019/7/1
Y1 - 2019/7/1
N2 - A polymeric iron(II) complex, Fe(ATrz) 3 (NO 3 ) 2 ·nH 2 O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH 3 , HNO 3 and HBr vapors.
AB - A polymeric iron(II) complex, Fe(ATrz) 3 (NO 3 ) 2 ·nH 2 O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH 3 , HNO 3 and HBr vapors.
KW - TRANSITION
KW - POLYMERS
KW - FILMS
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85065069335&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2019.04.035
DO - 10.1016/j.inoche.2019.04.035
M3 - Article
AN - SCOPUS:85065069335
VL - 105
SP - 82
EP - 85
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -
ID: 20049265