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Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state. / Tarasevych, Arkadii V.; Kostyukov, Anton I.; Baronskiy, Mark G. et al.

In: Chirality, Vol. 29, No. 7, 07.2017, p. 332-339.

Research output: Contribution to journal › Article › peer-review

Harvard

Tarasevych, AV, Kostyukov, AI, Baronskiy, MG, Rastorguev, AA, Guillemin, JC & Snytnikov, VN 2017, 'Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state', Chirality, vol. 29, no. 7, pp. 332-339. https://doi.org/10.1002/chir.22707

APA

Tarasevych, A. V., Kostyukov, A. I., Baronskiy, M. G., Rastorguev, A. A., Guillemin, J. C., & Snytnikov, V. N. (2017). Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state. Chirality, 29(7), 332-339. https://doi.org/10.1002/chir.22707

Vancouver

Tarasevych AV, Kostyukov AI, Baronskiy MG, Rastorguev AA, Guillemin JC, Snytnikov VN. Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state. Chirality. 2017 Jul;29(7):332-339. doi: 10.1002/chir.22707

Author

Tarasevych, Arkadii V. ; Kostyukov, Anton I. ; Baronskiy, Mark G. et al. / Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state. In: Chirality. 2017 ; Vol. 29, No. 7. pp. 332-339.

BibTeX

@article{608cdb2d4bb1496d9102d4fd5383a71c,
title = "Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state",
abstract = "Luminescent spectroscopy combined with the technique of luminescent probing with rare earth ions (europium, gadolinium, terbium) and an actinide ion (uranyl) was used to differentiate enantiopure and racemic alanine, the simplest chiral proteinogenic amino acid. Using the achiral luminescent probes, small differences between pure L and DL alanine in the solid state were strongly amplified. Based on the observed electronic transitions of the probes, the position of the triplet level of the coordinated alanine was estimated. Formation of homo- and heterochiral complexes between enantiomers of alanine and the metal ions is discussed as a possible mechanism of chiral self-discrimination.",
keywords = "alanine, enantiopure, europium, gadolinium, luminescent probing, luminescent spectroscopy, racemate, rare earths, terbium, uranyl, α-amino acid, alpha-amino acid, Actinoid Series Elements/chemistry, Stereoisomerism, Lanthanoid Series Elements/chemistry, Luminescent Measurements, Luminescent Agents/chemistry, Alanine/chemistry",
author = "Tarasevych, {Arkadii V.} and Kostyukov, {Anton I.} and Baronskiy, {Mark G.} and Rastorguev, {Alexander A.} and Guillemin, {Jean Claude} and Snytnikov, {Valeriy N.}",
note = "Publisher Copyright: {\textcopyright} 2017 Wiley Periodicals, Inc.",
year = "2017",
month = jul,
doi = "10.1002/chir.22707",
language = "English",
volume = "29",
pages = "332--339",
journal = "Chirality",
issn = "0899-0042",
publisher = "Wiley-Liss Inc.",
number = "7",

}

RIS

TY - JOUR

T1 - Luminescent probing of the simplest chiral α-amino acid–alanine in an enantiopure and racemic state

AU - Tarasevych, Arkadii V.

AU - Kostyukov, Anton I.

AU - Baronskiy, Mark G.

AU - Rastorguev, Alexander A.

AU - Guillemin, Jean Claude

AU - Snytnikov, Valeriy N.

N1 - Publisher Copyright: © 2017 Wiley Periodicals, Inc.

PY - 2017/7

Y1 - 2017/7

N2 - Luminescent spectroscopy combined with the technique of luminescent probing with rare earth ions (europium, gadolinium, terbium) and an actinide ion (uranyl) was used to differentiate enantiopure and racemic alanine, the simplest chiral proteinogenic amino acid. Using the achiral luminescent probes, small differences between pure L and DL alanine in the solid state were strongly amplified. Based on the observed electronic transitions of the probes, the position of the triplet level of the coordinated alanine was estimated. Formation of homo- and heterochiral complexes between enantiomers of alanine and the metal ions is discussed as a possible mechanism of chiral self-discrimination.

AB - Luminescent spectroscopy combined with the technique of luminescent probing with rare earth ions (europium, gadolinium, terbium) and an actinide ion (uranyl) was used to differentiate enantiopure and racemic alanine, the simplest chiral proteinogenic amino acid. Using the achiral luminescent probes, small differences between pure L and DL alanine in the solid state were strongly amplified. Based on the observed electronic transitions of the probes, the position of the triplet level of the coordinated alanine was estimated. Formation of homo- and heterochiral complexes between enantiomers of alanine and the metal ions is discussed as a possible mechanism of chiral self-discrimination.

KW - alanine

KW - enantiopure

KW - europium

KW - gadolinium

KW - luminescent probing

KW - luminescent spectroscopy

KW - racemate

KW - rare earths

KW - terbium

KW - uranyl

KW - α-amino acid

KW - alpha-amino acid

KW - Actinoid Series Elements/chemistry

KW - Stereoisomerism

KW - Lanthanoid Series Elements/chemistry

KW - Luminescent Measurements

KW - Luminescent Agents/chemistry

KW - Alanine/chemistry

UR - http://www.scopus.com/inward/record.url?scp=85019005116&partnerID=8YFLogxK

U2 - 10.1002/chir.22707

DO - 10.1002/chir.22707

M3 - Article

C2 - 28466966

AN - SCOPUS:85019005116

VL - 29

SP - 332

EP - 339

JO - Chirality

JF - Chirality

SN - 0899-0042

IS - 7

ER -

ID: 10194085