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Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids. / Davydova, M. P.; Nurkenov, O. A.; Bagryanskaya, I. Yu et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 52, No. 7, 13.09.2026.

Research output: Contribution to journal › Article › peer-review

Harvard

Davydova, MP, Nurkenov, OA, Bagryanskaya, IY, Trusova, MA, Vozmitel, NO, Rakhmanova, MI, Nurmaganbetov, ZS, Akhmetkaliev, SZ & Artem’ev, AV 2026, 'Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 52, no. 7. https://doi.org/10.1134/S1070328426600452

APA

Davydova, M. P., Nurkenov, O. A., Bagryanskaya, I. Y., Trusova, M. A., Vozmitel, N. O., Rakhmanova, M. I., Nurmaganbetov, Z. S., Akhmetkaliev, S. Z., & Artem’ev, A. V. (2026). Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 52(7). https://doi.org/10.1134/S1070328426600452

Vancouver

Davydova MP, Nurkenov OA, Bagryanskaya IY, Trusova MA, Vozmitel NO, Rakhmanova MI et al. Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2026 Sept 13;52(7). doi: 10.1134/S1070328426600452

Author

Davydova, M. P. ; Nurkenov, O. A. ; Bagryanskaya, I. Yu et al. / Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2026 ; Vol. 52, No. 7.

BibTeX

@article{92237be0e1894f92957aab6677e9a589,
title = "Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids",
abstract = "Chiral Cu(I) complexes, [Cu2I2(anabasine)2(PPh3)2] (I), [Cu2I2(nicotine)2(PPh3)2] (II), and [CuCl(anabasine)(PPh3)] (III), were synthesized using tobacco alkaloids: (−)-anabasine and (−)-nicotine. The structures of these compounds were determined by X-ray diffraction analysis. Complexes I and III are the first structurally characterized coordination compounds based on anabasine. Complexes I and II exhibit intense blue-cyan photoluminescence at room temperature with emission maxima at 485 and 480 nm, a lifetime of 16 μs, and a quantum yield of up to 31%. The results demonstrate the potential of natural alkaloids for the design of photoactive chiral Cu(I) complexes.",
keywords = "anabasine, copper(I) complexes, crystal structure, luminescence, nicotine, synthesis, комплексы меди(I), анабазин, никотин, люминесценция, синтез, кристаллическая структура",
author = "Davydova, {M. P.} and Nurkenov, {O. A.} and Bagryanskaya, {I. Yu} and Trusova, {M. A.} and Vozmitel, {N. O.} and Rakhmanova, {M. I.} and Nurmaganbetov, {Zh S.} and Akhmetkaliev, {S. Zh} and Artem{\textquoteright}ev, {A. V.}",
note = "Davydova, M.P., Nurkenov, O.A., Bagryanskaya, I.Y. et al. Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids. Russ J Coord Chem 52, 37 (2026). https://doi.org/10.1134/S1070328426600452",
year = "2026",
month = sep,
day = "13",
doi = "10.1134/S1070328426600452",
language = "English",
volume = "52",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids

AU - Davydova, M. P.

AU - Nurkenov, O. A.

AU - Bagryanskaya, I. Yu

AU - Trusova, M. A.

AU - Vozmitel, N. O.

AU - Rakhmanova, M. I.

AU - Nurmaganbetov, Zh S.

AU - Akhmetkaliev, S. Zh

AU - Artem’ev, A. V.

N1 - Davydova, M.P., Nurkenov, O.A., Bagryanskaya, I.Y. et al. Luminescent Cu(I) Complexes Based on Natural Tobacco Alkaloids. Russ J Coord Chem 52, 37 (2026). https://doi.org/10.1134/S1070328426600452

PY - 2026/9/13

Y1 - 2026/9/13

N2 - Chiral Cu(I) complexes, [Cu2I2(anabasine)2(PPh3)2] (I), [Cu2I2(nicotine)2(PPh3)2] (II), and [CuCl(anabasine)(PPh3)] (III), were synthesized using tobacco alkaloids: (−)-anabasine and (−)-nicotine. The structures of these compounds were determined by X-ray diffraction analysis. Complexes I and III are the first structurally characterized coordination compounds based on anabasine. Complexes I and II exhibit intense blue-cyan photoluminescence at room temperature with emission maxima at 485 and 480 nm, a lifetime of 16 μs, and a quantum yield of up to 31%. The results demonstrate the potential of natural alkaloids for the design of photoactive chiral Cu(I) complexes.

AB - Chiral Cu(I) complexes, [Cu2I2(anabasine)2(PPh3)2] (I), [Cu2I2(nicotine)2(PPh3)2] (II), and [CuCl(anabasine)(PPh3)] (III), were synthesized using tobacco alkaloids: (−)-anabasine and (−)-nicotine. The structures of these compounds were determined by X-ray diffraction analysis. Complexes I and III are the first structurally characterized coordination compounds based on anabasine. Complexes I and II exhibit intense blue-cyan photoluminescence at room temperature with emission maxima at 485 and 480 nm, a lifetime of 16 μs, and a quantum yield of up to 31%. The results demonstrate the potential of natural alkaloids for the design of photoactive chiral Cu(I) complexes.

KW - anabasine

KW - copper(I) complexes

KW - crystal structure

KW - luminescence

KW - nicotine

KW - synthesis

KW - комплексы меди(I)

KW - анабазин

KW - никотин

KW - люминесценция

KW - синтез

KW - кристаллическая структура

UR - https://www.mendeley.com/catalogue/9ece9f45-6a99-3778-b875-8ec07e1225df/

UR - https://www.scopus.com/pages/publications/105050414977

U2 - 10.1134/S1070328426600452

DO - 10.1134/S1070328426600452

M3 - Article

VL - 52

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 7

ER -

ID: 85034186