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Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments. / Kokina, T. E.; Ustimenko, Yu P.; Rakhmanova, M. I. et al.

In: Russian Journal of General Chemistry, Vol. 89, No. 1, 01.01.2019, p. 87-95.

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Kokina TE, Ustimenko YP, Rakhmanova MI, Sheludyakova LA, Agafontsev AM, Plyusnin PE et al. Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments. Russian Journal of General Chemistry. 2019 Jan 1;89(1):87-95. doi: 10.1134/S107036321901016X

Author

Kokina, T. E. ; Ustimenko, Yu P. ; Rakhmanova, M. I. et al. / Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments. In: Russian Journal of General Chemistry. 2019 ; Vol. 89, No. 1. pp. 87-95.

BibTeX

@article{c0f0a9bb7c924563a076a1dd947be45b,
title = "Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments",
abstract = " New chiral 1,10-phenanthroline-derived ligands containing fragments of (+)-3-carene (L 1 ) and (+)-limonene (L2) natural monoterpenoids and their complexes Zn(L 1,2 )Cl 2 ·1.5H 2 O, Cd(L 1,2 )Cl 2 ·nH 2 O, Zn(L 1 )Br 2 ·2H 2 O, and Cd(L1)Br2·2H2O were synthesized. According to NMR and IR spectroscopy data, a conclusion was made about the polynuclear structure of the compounds obtained. Luminescent properties of the compounds obtained were investigated. Lifetimes of the excited states and luminescence quantum yields (φ f ) were determined. For free ligands, blue fluorescence was observed. In the case of Zn(II) and Cd(II) complexes, luminescence appeared in the green region of the spectrum. ",
keywords = "cadmium, complexes, luminescence, terpenes, zinc, PHOTOLUMINESCENCE, CRYSTAL-STRUCTURE, PYRIDINE, PYRAZOLYLQUINOLINE, ZINC(II), METAL-COMPLEXES",
author = "Kokina, {T. E.} and Ustimenko, {Yu P.} and Rakhmanova, {M. I.} and Sheludyakova, {L. A.} and Agafontsev, {A. M.} and Plyusnin, {P. E.} and Tkachev, {A. V.} and Larionov, {S. V.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1134/S107036321901016X",
language = "English",
volume = "89",
pages = "87--95",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

RIS

TY - JOUR

T1 - Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments

AU - Kokina, T. E.

AU - Ustimenko, Yu P.

AU - Rakhmanova, M. I.

AU - Sheludyakova, L. A.

AU - Agafontsev, A. M.

AU - Plyusnin, P. E.

AU - Tkachev, A. V.

AU - Larionov, S. V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - New chiral 1,10-phenanthroline-derived ligands containing fragments of (+)-3-carene (L 1 ) and (+)-limonene (L2) natural monoterpenoids and their complexes Zn(L 1,2 )Cl 2 ·1.5H 2 O, Cd(L 1,2 )Cl 2 ·nH 2 O, Zn(L 1 )Br 2 ·2H 2 O, and Cd(L1)Br2·2H2O were synthesized. According to NMR and IR spectroscopy data, a conclusion was made about the polynuclear structure of the compounds obtained. Luminescent properties of the compounds obtained were investigated. Lifetimes of the excited states and luminescence quantum yields (φ f ) were determined. For free ligands, blue fluorescence was observed. In the case of Zn(II) and Cd(II) complexes, luminescence appeared in the green region of the spectrum.

AB - New chiral 1,10-phenanthroline-derived ligands containing fragments of (+)-3-carene (L 1 ) and (+)-limonene (L2) natural monoterpenoids and their complexes Zn(L 1,2 )Cl 2 ·1.5H 2 O, Cd(L 1,2 )Cl 2 ·nH 2 O, Zn(L 1 )Br 2 ·2H 2 O, and Cd(L1)Br2·2H2O were synthesized. According to NMR and IR spectroscopy data, a conclusion was made about the polynuclear structure of the compounds obtained. Luminescent properties of the compounds obtained were investigated. Lifetimes of the excited states and luminescence quantum yields (φ f ) were determined. For free ligands, blue fluorescence was observed. In the case of Zn(II) and Cd(II) complexes, luminescence appeared in the green region of the spectrum.

KW - cadmium

KW - complexes

KW - luminescence

KW - terpenes

KW - zinc

KW - PHOTOLUMINESCENCE

KW - CRYSTAL-STRUCTURE

KW - PYRIDINE

KW - PYRAZOLYLQUINOLINE

KW - ZINC(II)

KW - METAL-COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85064008854&partnerID=8YFLogxK

U2 - 10.1134/S107036321901016X

DO - 10.1134/S107036321901016X

M3 - Article

AN - SCOPUS:85064008854

VL - 89

SP - 87

EP - 95

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 1

ER -

ID: 19334812