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Low-temperature thermodynamic properties of holmium selenide (2 : 3). / Bespyatov, M. A.; Musikhin, A. E.; Naumov, V. N. et al.

In: Journal of Chemical Thermodynamics, Vol. 118, 01.03.2018, p. 21-25.

Research output: Contribution to journalArticlepeer-review

Harvard

Bespyatov, MA, Musikhin, AE, Naumov, VN, Zelenina, LN, Chusova, TP, Nikolaev, RE & Naumov, NG 2018, 'Low-temperature thermodynamic properties of holmium selenide (2: 3)', Journal of Chemical Thermodynamics, vol. 118, pp. 21-25. https://doi.org/10.1016/j.jct.2017.10.013

APA

Bespyatov, M. A., Musikhin, A. E., Naumov, V. N., Zelenina, L. N., Chusova, T. P., Nikolaev, R. E., & Naumov, N. G. (2018). Low-temperature thermodynamic properties of holmium selenide (2: 3). Journal of Chemical Thermodynamics, 118, 21-25. https://doi.org/10.1016/j.jct.2017.10.013

Vancouver

Bespyatov MA, Musikhin AE, Naumov VN, Zelenina LN, Chusova TP, Nikolaev RE et al. Low-temperature thermodynamic properties of holmium selenide (2: 3). Journal of Chemical Thermodynamics. 2018 Mar 1;118:21-25. doi: 10.1016/j.jct.2017.10.013

Author

Bespyatov, M. A. ; Musikhin, A. E. ; Naumov, V. N. et al. / Low-temperature thermodynamic properties of holmium selenide (2 : 3). In: Journal of Chemical Thermodynamics. 2018 ; Vol. 118. pp. 21-25.

BibTeX

@article{f9b160669c654c01a596bc70713887e5,
title = "Low-temperature thermodynamic properties of holmium selenide (2: 3)",
abstract = "Holmium selenide Ho2Se3(cr) was synthesized and characterized by powder X-ray diffraction and energy dispersive analysis. The heat capacity of Ho2Se3(cr) has been measured by adiabatic method in the temperature range of (4.75–302.60) K. The pronounced λ-anomalies were found in Cp,m(T) dependence with the maxima at temperatures TC1 = 6.03 K and TC2 = 228.40 K. A conclusion was drawn that the phase transition associated with antiferromagnetic ordering is observed at TC1. The values of thermodynamic function (entropy, enthalpy and Gibbs reduced energy) were calculated from the experimental Cp(T) dependence. Absolute entropy value was used for calculation of Ho2Se3(cr) formation entropy at T = 298.15 K.",
keywords = "Heat capacity, Holmium selenide, Thermodynamic functions, GLASS, CALORIMETRY, RARE-EARTH CHALCOGENIDES, HEAT-CAPACITY",
author = "Bespyatov, {M. A.} and Musikhin, {A. E.} and Naumov, {V. N.} and Zelenina, {L. N.} and Chusova, {T. P.} and Nikolaev, {R. E.} and Naumov, {N. G.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",
year = "2018",
month = mar,
day = "1",
doi = "10.1016/j.jct.2017.10.013",
language = "English",
volume = "118",
pages = "21--25",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - Low-temperature thermodynamic properties of holmium selenide (2

T2 - 3)

AU - Bespyatov, M. A.

AU - Musikhin, A. E.

AU - Naumov, V. N.

AU - Zelenina, L. N.

AU - Chusova, T. P.

AU - Nikolaev, R. E.

AU - Naumov, N. G.

N1 - Publisher Copyright: © 2017 Elsevier Ltd

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Holmium selenide Ho2Se3(cr) was synthesized and characterized by powder X-ray diffraction and energy dispersive analysis. The heat capacity of Ho2Se3(cr) has been measured by adiabatic method in the temperature range of (4.75–302.60) K. The pronounced λ-anomalies were found in Cp,m(T) dependence with the maxima at temperatures TC1 = 6.03 K and TC2 = 228.40 K. A conclusion was drawn that the phase transition associated with antiferromagnetic ordering is observed at TC1. The values of thermodynamic function (entropy, enthalpy and Gibbs reduced energy) were calculated from the experimental Cp(T) dependence. Absolute entropy value was used for calculation of Ho2Se3(cr) formation entropy at T = 298.15 K.

AB - Holmium selenide Ho2Se3(cr) was synthesized and characterized by powder X-ray diffraction and energy dispersive analysis. The heat capacity of Ho2Se3(cr) has been measured by adiabatic method in the temperature range of (4.75–302.60) K. The pronounced λ-anomalies were found in Cp,m(T) dependence with the maxima at temperatures TC1 = 6.03 K and TC2 = 228.40 K. A conclusion was drawn that the phase transition associated with antiferromagnetic ordering is observed at TC1. The values of thermodynamic function (entropy, enthalpy and Gibbs reduced energy) were calculated from the experimental Cp(T) dependence. Absolute entropy value was used for calculation of Ho2Se3(cr) formation entropy at T = 298.15 K.

KW - Heat capacity

KW - Holmium selenide

KW - Thermodynamic functions

KW - GLASS

KW - CALORIMETRY

KW - RARE-EARTH CHALCOGENIDES

KW - HEAT-CAPACITY

UR - http://www.scopus.com/inward/record.url?scp=85032481720&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2017.10.013

DO - 10.1016/j.jct.2017.10.013

M3 - Article

AN - SCOPUS:85032481720

VL - 118

SP - 21

EP - 25

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

ER -

ID: 9158181