Research output: Contribution to journal › Article › peer-review
Low-Temperature Thermodynamic Properties of Cobalt Trisdipivaloyl Methanate. / Chernyaikin, I. S.; Bespyatov, M. A.; Dorovskikh, S. I. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 65, No. 5, 01.05.2020, p. 650-654.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Low-Temperature Thermodynamic Properties of Cobalt Trisdipivaloyl Methanate
AU - Chernyaikin, I. S.
AU - Bespyatov, M. A.
AU - Dorovskikh, S. I.
AU - Kusin, T. M.
AU - Gel’fond, N. V.
AU - Morozova, N. B.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - The heat capacity of cobalt trisdipivaloyl methanate Co(C11H19O2)3 was measured by the adiabatic method within the temperature range 8.18–301.61 K. The analysis of the functional dependence of the heat capacity did not revealed any thermal anomalies in its behavior. The thermodynamic functions (entropy, enthalpy, and reduced Gibbs energy) were calculated from the measured experimental data on the heat capacity within a temperature range of 0–300 K. The absolute entropy was used to calculate the formation entropy of Co(C11H19O2)3 at Т = 298.15 K.
AB - The heat capacity of cobalt trisdipivaloyl methanate Co(C11H19O2)3 was measured by the adiabatic method within the temperature range 8.18–301.61 K. The analysis of the functional dependence of the heat capacity did not revealed any thermal anomalies in its behavior. The thermodynamic functions (entropy, enthalpy, and reduced Gibbs energy) were calculated from the measured experimental data on the heat capacity within a temperature range of 0–300 K. The absolute entropy was used to calculate the formation entropy of Co(C11H19O2)3 at Т = 298.15 K.
KW - calorimetry
KW - cobalt β-diketonates
KW - heat capacity
KW - thermodynamic functions
KW - cobalt beta-diketonates
KW - HEAT-CAPACITY
UR - http://www.scopus.com/inward/record.url?scp=85086005823&partnerID=8YFLogxK
U2 - 10.1134/S0036023620050058
DO - 10.1134/S0036023620050058
M3 - Article
AN - SCOPUS:85086005823
VL - 65
SP - 650
EP - 654
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
SN - 0036-0236
IS - 5
ER -
ID: 24471266