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Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units. / Jamous, A. Y.; Svetlichnyi, V. A.; Kuznetsov, A. B. et al.

In: Journal of Alloys and Compounds, Vol. 935, 167912, 15.02.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Jamous, AY, Svetlichnyi, VA, Kuznetsov, AB, Kokh, KA, Kononova, NG, Lapin, IN, Bolatov, A, Zholdas, YA & Kokh, AE 2023, 'Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units', Journal of Alloys and Compounds, vol. 935, 167912. https://doi.org/10.1016/j.jallcom.2022.167912

APA

Jamous, A. Y., Svetlichnyi, V. A., Kuznetsov, A. B., Kokh, K. A., Kononova, N. G., Lapin, I. N., Bolatov, A., Zholdas, Y. A., & Kokh, A. E. (2023). Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units. Journal of Alloys and Compounds, 935, [167912]. https://doi.org/10.1016/j.jallcom.2022.167912

Vancouver

Jamous AY, Svetlichnyi VA, Kuznetsov AB, Kokh KA, Kononova NG, Lapin IN et al. Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units. Journal of Alloys and Compounds. 2023 Feb 15;935:167912. doi: 10.1016/j.jallcom.2022.167912

Author

Jamous, A. Y. ; Svetlichnyi, V. A. ; Kuznetsov, A. B. et al. / Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units. In: Journal of Alloys and Compounds. 2023 ; Vol. 935.

BibTeX

@article{a35a4cb494aa420c8b265ea4ed91b7f2,
title = "Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units",
abstract = "Noncentrosymmetric borates K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) were synthesized by the solid state reaction and the crystals were successfully grown by the top seeded solution growth method using the K2O-B2O3-MF2 flux. According to Rietveld refinement, the crystal structure belongs to the noncentrosymmetric R32 space group. Also, the octahedrally coordinated In atoms are located at wide ranges ∼8 {\AA} which may be promising for phosphor and laser applications. Samples with ytterbium show a characteristic emission band in the range of 950–1050 nm related to the 2F5/2 → 2F7/2 transition of Yb3+ ions that is commonly used for laser generation. IR, Raman and absorption spectra were obtained for the samples as well. The short cut edge of UV absorption, SHG intensity comparable with KDP and low concentration quenching of luminescence suggest that the K7MIn2−xYbx(B5O10)3 borates are promising self-frequency doubling materials.",
keywords = "Borate, Crystal structure, Photoluminescence, Raman, Second harmonic generation (SHG), Self-frequency doubling (SFD)",
author = "Jamous, {A. Y.} and Svetlichnyi, {V. A.} and Kuznetsov, {A. B.} and Kokh, {K. A.} and Kononova, {N. G.} and Lapin, {I. N.} and A. Bolatov and Zholdas, {Y. A.} and Kokh, {A. E.}",
note = "Funding Information: This work was supported by Russian Science Foundation [№ 22-73-00007 ], project GF MES RK {"}Crystallochemical design of the new alkali and rare earth-based borate phosphors{"} [ IRN AP08855427 ], and state assigned project of IGM SB RAS . Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",
year = "2023",
month = feb,
day = "15",
doi = "10.1016/j.jallcom.2022.167912",
language = "English",
volume = "935",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Linear and nonlinear optical properties of trigonal borate crystals K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) with isolated B5O10 units

AU - Jamous, A. Y.

AU - Svetlichnyi, V. A.

AU - Kuznetsov, A. B.

AU - Kokh, K. A.

AU - Kononova, N. G.

AU - Lapin, I. N.

AU - Bolatov, A.

AU - Zholdas, Y. A.

AU - Kokh, A. E.

N1 - Funding Information: This work was supported by Russian Science Foundation [№ 22-73-00007 ], project GF MES RK "Crystallochemical design of the new alkali and rare earth-based borate phosphors" [ IRN AP08855427 ], and state assigned project of IGM SB RAS . Publisher Copyright: © 2022 Elsevier B.V.

PY - 2023/2/15

Y1 - 2023/2/15

N2 - Noncentrosymmetric borates K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) were synthesized by the solid state reaction and the crystals were successfully grown by the top seeded solution growth method using the K2O-B2O3-MF2 flux. According to Rietveld refinement, the crystal structure belongs to the noncentrosymmetric R32 space group. Also, the octahedrally coordinated In atoms are located at wide ranges ∼8 Å which may be promising for phosphor and laser applications. Samples with ytterbium show a characteristic emission band in the range of 950–1050 nm related to the 2F5/2 → 2F7/2 transition of Yb3+ ions that is commonly used for laser generation. IR, Raman and absorption spectra were obtained for the samples as well. The short cut edge of UV absorption, SHG intensity comparable with KDP and low concentration quenching of luminescence suggest that the K7MIn2−xYbx(B5O10)3 borates are promising self-frequency doubling materials.

AB - Noncentrosymmetric borates K7MIn2−xYbx(B5O10)3 (M = Ca, Sr, Ba; x = 0…2) were synthesized by the solid state reaction and the crystals were successfully grown by the top seeded solution growth method using the K2O-B2O3-MF2 flux. According to Rietveld refinement, the crystal structure belongs to the noncentrosymmetric R32 space group. Also, the octahedrally coordinated In atoms are located at wide ranges ∼8 Å which may be promising for phosphor and laser applications. Samples with ytterbium show a characteristic emission band in the range of 950–1050 nm related to the 2F5/2 → 2F7/2 transition of Yb3+ ions that is commonly used for laser generation. IR, Raman and absorption spectra were obtained for the samples as well. The short cut edge of UV absorption, SHG intensity comparable with KDP and low concentration quenching of luminescence suggest that the K7MIn2−xYbx(B5O10)3 borates are promising self-frequency doubling materials.

KW - Borate

KW - Crystal structure

KW - Photoluminescence

KW - Raman

KW - Second harmonic generation (SHG)

KW - Self-frequency doubling (SFD)

UR - http://www.scopus.com/inward/record.url?scp=85142156378&partnerID=8YFLogxK

UR - https://elibrary.ru/item.asp?id=49849533

U2 - 10.1016/j.jallcom.2022.167912

DO - 10.1016/j.jallcom.2022.167912

M3 - Article

AN - SCOPUS:85142156378

VL - 935

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

M1 - 167912

ER -

ID: 39665088