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L-Argininium phosphite-a new candidate for NLO materials. / Ghazaryan, Vahram V.; Zakharov, Boris A.; Petrosyan, Aram M. et al.

In: Acta Crystallographica Section C: Structural Chemistry, Vol. 71, 01.05.2015, p. 415-421.

Research output: Contribution to journal › Article › peer-review

Harvard

Ghazaryan, VV, Zakharov, BA, Petrosyan, AM & Boldyreva, EV 2015, 'L-Argininium phosphite-a new candidate for NLO materials', Acta Crystallographica Section C: Structural Chemistry, vol. 71, pp. 415-421. https://doi.org/10.1107/S2053229615006956

APA

Ghazaryan, V. V., Zakharov, B. A., Petrosyan, A. M., & Boldyreva, E. V. (2015). L-Argininium phosphite-a new candidate for NLO materials. Acta Crystallographica Section C: Structural Chemistry, 71, 415-421. https://doi.org/10.1107/S2053229615006956

Vancouver

Ghazaryan VV, Zakharov BA, Petrosyan AM, Boldyreva EV. L-Argininium phosphite-a new candidate for NLO materials. Acta Crystallographica Section C: Structural Chemistry. 2015 May 1;71:415-421. doi: 10.1107/S2053229615006956

Author

Ghazaryan, Vahram V. ; Zakharov, Boris A. ; Petrosyan, Aram M. et al. / L-Argininium phosphite-a new candidate for NLO materials. In: Acta Crystallographica Section C: Structural Chemistry. 2015 ; Vol. 71. pp. 415-421.

BibTeX

@article{395486adcba7482ba74c96d50270b7e1,
title = "L-Argininium phosphite-a new candidate for NLO materials",
abstract = "In order to investigate the possibility of salt formation in the l-Arg-H3PO3-H2O system, single crystals of l-argininium phosphite, C6H15N4O2 +·H2PO3 -, were prepared by evaporation of an aqueous solution containing equimolar quantities of l-arginine and phosphorous acid. The asymmetric unit contains one l-argininium(+) cation and one phosphite [HPO2(OH)]- anion. The phosphite anions form chains parallel to [010] by O-HO hydrogen bonding, with an OO distance of 2.630-14;(3)-14;{\AA}. The protonated amine and guanidyl groups of the l-argininium(+) cations form N-HO hydrogen bonds with the carboxylate groups and anions. The IR and Raman spectra are discussed in relation to the crystal structure. The salt displays nonlinear optical (NLO) properties. Another salt was obtained from a solution with a 1:2 molar ratio of components, but was characterized by vibrational spectra only.",
keywords = "crystal structure, l-argininium phosphite, nonlinear optical (NLO) properties, solution growth, vibrational spectra",
author = "Ghazaryan, {Vahram V.} and Zakharov, {Boris A.} and Petrosyan, {Aram M.} and Boldyreva, {Elena V.}",
year = "2015",
month = may,
day = "1",
doi = "10.1107/S2053229615006956",
language = "English",
volume = "71",
pages = "415--421",
journal = "Acta Crystallographica Section C: Structural Chemistry",
issn = "2053-2296",
publisher = "John Wiley and Sons Inc.",

}

RIS

TY - JOUR

T1 - L-Argininium phosphite-a new candidate for NLO materials

AU - Ghazaryan, Vahram V.

AU - Zakharov, Boris A.

AU - Petrosyan, Aram M.

AU - Boldyreva, Elena V.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - In order to investigate the possibility of salt formation in the l-Arg-H3PO3-H2O system, single crystals of l-argininium phosphite, C6H15N4O2 +·H2PO3 -, were prepared by evaporation of an aqueous solution containing equimolar quantities of l-arginine and phosphorous acid. The asymmetric unit contains one l-argininium(+) cation and one phosphite [HPO2(OH)]- anion. The phosphite anions form chains parallel to [010] by O-HO hydrogen bonding, with an OO distance of 2.630-14;(3)-14;Å. The protonated amine and guanidyl groups of the l-argininium(+) cations form N-HO hydrogen bonds with the carboxylate groups and anions. The IR and Raman spectra are discussed in relation to the crystal structure. The salt displays nonlinear optical (NLO) properties. Another salt was obtained from a solution with a 1:2 molar ratio of components, but was characterized by vibrational spectra only.

AB - In order to investigate the possibility of salt formation in the l-Arg-H3PO3-H2O system, single crystals of l-argininium phosphite, C6H15N4O2 +·H2PO3 -, were prepared by evaporation of an aqueous solution containing equimolar quantities of l-arginine and phosphorous acid. The asymmetric unit contains one l-argininium(+) cation and one phosphite [HPO2(OH)]- anion. The phosphite anions form chains parallel to [010] by O-HO hydrogen bonding, with an OO distance of 2.630-14;(3)-14;Å. The protonated amine and guanidyl groups of the l-argininium(+) cations form N-HO hydrogen bonds with the carboxylate groups and anions. The IR and Raman spectra are discussed in relation to the crystal structure. The salt displays nonlinear optical (NLO) properties. Another salt was obtained from a solution with a 1:2 molar ratio of components, but was characterized by vibrational spectra only.

KW - crystal structure

KW - l-argininium phosphite

KW - nonlinear optical (NLO) properties

KW - solution growth

KW - vibrational spectra

UR - http://www.scopus.com/inward/record.url?scp=84928897932&partnerID=8YFLogxK

U2 - 10.1107/S2053229615006956

DO - 10.1107/S2053229615006956

M3 - Article

C2 - 25940900

AN - SCOPUS:84928897932

VL - 71

SP - 415

EP - 421

JO - Acta Crystallographica Section C: Structural Chemistry

JF - Acta Crystallographica Section C: Structural Chemistry

SN - 2053-2296

ER -

ID: 25462859