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Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst. / Uskov, S. I.; Enikeeva, L. V.; Potemkin, D. I. et al.

In: Catalysis in Industry, Vol. 9, No. 2, 04.2017, p. 104-109.

Research output: Contribution to journal › Article › peer-review

Harvard

Uskov, SI, Enikeeva, LV, Potemkin, DI, Belyaev, VD, Snytnikov, PV, Gubaidullin, IM, Kirillov, VA & Sobyanin, VA 2017, 'Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst', Catalysis in Industry, vol. 9, no. 2, pp. 104-109. https://doi.org/10.1134/S2070050417020118

APA

Uskov, S. I., Enikeeva, L. V., Potemkin, D. I., Belyaev, V. D., Snytnikov, P. V., Gubaidullin, I. M., Kirillov, V. A., & Sobyanin, V. A. (2017). Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst. Catalysis in Industry, 9(2), 104-109. https://doi.org/10.1134/S2070050417020118

Vancouver

Uskov SI, Enikeeva LV, Potemkin DI, Belyaev VD, Snytnikov PV, Gubaidullin IM et al. Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst. Catalysis in Industry. 2017 Apr;9(2):104-109. doi: 10.1134/S2070050417020118

Author

Uskov, S. I. ; Enikeeva, L. V. ; Potemkin, D. I. et al. / Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst. In: Catalysis in Industry. 2017 ; Vol. 9, No. 2. pp. 104-109.

BibTeX

@article{0116a5e5859e4aaeb8910f7578256459,
title = "Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst",
abstract = "Systematic studies were performed on low-temperature steam conversion or low-temperature steam reforming (LTSR) of propane in an excess of methane on a Ni-based catalyst. The LTSR of the methane–propane mixture is a two-stage process involving the irreversible steam conversion of propane into carbon dioxide and hydrogen and reversible methanation of carbon dioxide. Above ~250°C, the methanation of carbon dioxide is quasi-equilibrium. The rate of propane conversion during the LTSR of the methane–propane mixture is first-order based on propane; its activation energy is ~120 kJ/mol and is almost independent of the methane, carbon dioxide, hydrogen, and steam concentrations. This very simple macrokinetic scheme allows us to correctly describe the experimental data and predict the temperature and flow rate of the mixture at which complete conversion of propane is achieved.",
keywords = "associated petroleum gas, kinetics of catalytic reactions, low-temperature steam reforming, low-temperature vapor conversion, methane, nickel catalyst, propane, SYNTHESIS GAS, RICH GAS",
author = "Uskov, {S. I.} and Enikeeva, {L. V.} and Potemkin, {D. I.} and Belyaev, {V. D.} and Snytnikov, {P. V.} and Gubaidullin, {I. M.} and Kirillov, {V. A.} and Sobyanin, {V. A.}",
year = "2017",
month = apr,
doi = "10.1134/S2070050417020118",
language = "English",
volume = "9",
pages = "104--109",
journal = "Catalysis in Industry",
issn = "2070-0504",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Kinetics of low-temperature steam reforming of propane in a methane excess on a Ni-based catalyst

AU - Uskov, S. I.

AU - Enikeeva, L. V.

AU - Potemkin, D. I.

AU - Belyaev, V. D.

AU - Snytnikov, P. V.

AU - Gubaidullin, I. M.

AU - Kirillov, V. A.

AU - Sobyanin, V. A.

PY - 2017/4

Y1 - 2017/4

N2 - Systematic studies were performed on low-temperature steam conversion or low-temperature steam reforming (LTSR) of propane in an excess of methane on a Ni-based catalyst. The LTSR of the methane–propane mixture is a two-stage process involving the irreversible steam conversion of propane into carbon dioxide and hydrogen and reversible methanation of carbon dioxide. Above ~250°C, the methanation of carbon dioxide is quasi-equilibrium. The rate of propane conversion during the LTSR of the methane–propane mixture is first-order based on propane; its activation energy is ~120 kJ/mol and is almost independent of the methane, carbon dioxide, hydrogen, and steam concentrations. This very simple macrokinetic scheme allows us to correctly describe the experimental data and predict the temperature and flow rate of the mixture at which complete conversion of propane is achieved.

AB - Systematic studies were performed on low-temperature steam conversion or low-temperature steam reforming (LTSR) of propane in an excess of methane on a Ni-based catalyst. The LTSR of the methane–propane mixture is a two-stage process involving the irreversible steam conversion of propane into carbon dioxide and hydrogen and reversible methanation of carbon dioxide. Above ~250°C, the methanation of carbon dioxide is quasi-equilibrium. The rate of propane conversion during the LTSR of the methane–propane mixture is first-order based on propane; its activation energy is ~120 kJ/mol and is almost independent of the methane, carbon dioxide, hydrogen, and steam concentrations. This very simple macrokinetic scheme allows us to correctly describe the experimental data and predict the temperature and flow rate of the mixture at which complete conversion of propane is achieved.

KW - associated petroleum gas

KW - kinetics of catalytic reactions

KW - low-temperature steam reforming

KW - low-temperature vapor conversion

KW - methane

KW - nickel catalyst

KW - propane

KW - SYNTHESIS GAS

KW - RICH GAS

UR - http://www.scopus.com/inward/record.url?scp=85021678732&partnerID=8YFLogxK

U2 - 10.1134/S2070050417020118

DO - 10.1134/S2070050417020118

M3 - Article

AN - SCOPUS:85021678732

VL - 9

SP - 104

EP - 109

JO - Catalysis in Industry

JF - Catalysis in Industry

SN - 2070-0504

IS - 2

ER -

ID: 9641479