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Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo. / Syryamina, Victoria N.; Rogozhnikova, Olga Yu; Tormyshev, Victor M. et al.

In: Applied Magnetic Resonance, 02.09.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Syryamina, VN, Rogozhnikova, OY, Tormyshev, VM & Dzuba, SA 2024, 'Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo', Applied Magnetic Resonance. https://doi.org/10.1007/s00723-024-01707-2

APA

Syryamina, V. N., Rogozhnikova, O. Y., Tormyshev, V. M., & Dzuba, S. A. (2024). Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo. Applied Magnetic Resonance. https://doi.org/10.1007/s00723-024-01707-2

Vancouver

Syryamina VN, Rogozhnikova OY, Tormyshev VM, Dzuba SA. Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo. Applied Magnetic Resonance. 2024 Sept 2. doi: 10.1007/s00723-024-01707-2

Author

Syryamina, Victoria N. ; Rogozhnikova, Olga Yu ; Tormyshev, Victor M. et al. / Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo. In: Applied Magnetic Resonance. 2024.

BibTeX

@article{3229d080fa9f48bab90a92af92f397e7,
title = "Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo",
abstract = "Triarylmethyl (TAM) radicals and TAM-based biradicals are often used as spin labels in different applications. Pulsed dipolar spectroscopy (PDS) is developed for studying interspin distances in the important nanoscale range. Here, we describe synthesis of bis-triarylmethyl biradical and its study using a simple PDS approach based on two-pulse electron spin echo (2p ESE) spectroscopy. It is shown that despite the well-known problems of dead time, interference of electron–nuclear interactions, and fast signal decay, this approach can provide reliable information for the interspin distances. In this approach, strong dipole–dipole coupling can be easily accounted for in the data analysis.",
author = "Syryamina, {Victoria N.} and Rogozhnikova, {Olga Yu} and Tormyshev, {Victor M.} and Dzuba, {Sergei A.}",
note = "V.N.S. and S.A.D. acknowledge the core funding from the Russian Federal Ministry of Science and Higher Education (FWGF-2021-0003), O.Yu.R. and V.M.T. acknowledge the core funding from the Russian Federal Ministry of Science and Higher Education (FWUE-2022-0012).",
year = "2024",
month = sep,
day = "2",
doi = "10.1007/s00723-024-01707-2",
language = "English",
journal = "Applied Magnetic Resonance",
issn = "0937-9347",
publisher = "Springer-Verlag GmbH and Co. KG",

}

RIS

TY - JOUR

T1 - Interspin Distances in a Triarylmethyl Biradical from Two-Pulse Electron Spin Echo

AU - Syryamina, Victoria N.

AU - Rogozhnikova, Olga Yu

AU - Tormyshev, Victor M.

AU - Dzuba, Sergei A.

N1 - V.N.S. and S.A.D. acknowledge the core funding from the Russian Federal Ministry of Science and Higher Education (FWGF-2021-0003), O.Yu.R. and V.M.T. acknowledge the core funding from the Russian Federal Ministry of Science and Higher Education (FWUE-2022-0012).

PY - 2024/9/2

Y1 - 2024/9/2

N2 - Triarylmethyl (TAM) radicals and TAM-based biradicals are often used as spin labels in different applications. Pulsed dipolar spectroscopy (PDS) is developed for studying interspin distances in the important nanoscale range. Here, we describe synthesis of bis-triarylmethyl biradical and its study using a simple PDS approach based on two-pulse electron spin echo (2p ESE) spectroscopy. It is shown that despite the well-known problems of dead time, interference of electron–nuclear interactions, and fast signal decay, this approach can provide reliable information for the interspin distances. In this approach, strong dipole–dipole coupling can be easily accounted for in the data analysis.

AB - Triarylmethyl (TAM) radicals and TAM-based biradicals are often used as spin labels in different applications. Pulsed dipolar spectroscopy (PDS) is developed for studying interspin distances in the important nanoscale range. Here, we describe synthesis of bis-triarylmethyl biradical and its study using a simple PDS approach based on two-pulse electron spin echo (2p ESE) spectroscopy. It is shown that despite the well-known problems of dead time, interference of electron–nuclear interactions, and fast signal decay, this approach can provide reliable information for the interspin distances. In this approach, strong dipole–dipole coupling can be easily accounted for in the data analysis.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85202502628&origin=inward&txGid=b2c43ad29a8e822b36f416e85697c2a6

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:001299695100001

UR - https://www.mendeley.com/catalogue/b40a7feb-f500-3b7a-b4ce-851dc0b9106a/

U2 - 10.1007/s00723-024-01707-2

DO - 10.1007/s00723-024-01707-2

M3 - Article

JO - Applied Magnetic Resonance

JF - Applied Magnetic Resonance

SN - 0937-9347

ER -

ID: 61204314