Research output: Contribution to journal › Article › peer-review
Insight into Hydrate Film Growth : Unusual Growth of Methane Hydrate Film at the Interface of Methane and the Aqueous Solution of Malonic Acid. / Stoporev, Andrey S.; Adamova, Tatyana P.; Manakov, Andrey Yu.
In: Crystal Growth and Design, Vol. 20, No. 3, 04.03.2020, p. 1927-1934.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Insight into Hydrate Film Growth
T2 - Unusual Growth of Methane Hydrate Film at the Interface of Methane and the Aqueous Solution of Malonic Acid
AU - Stoporev, Andrey S.
AU - Adamova, Tatyana P.
AU - Manakov, Andrey Yu
PY - 2020/3/4
Y1 - 2020/3/4
N2 - In this paper, we argue there is a new way of growing hydrate film other than two currently known ones, namely, a hydrate shell on the water surface without a surfactant and various hydrate dendrimers in the presence of surfactants. A previously unknown growth form of hydrate film occurs at the boundary between an aqueous solution of malonic acid and methane gas. These are gas-filled rounded bodies (like bubbles) of irregular shape which intergrow into the bulk aqueous phase. A possible phenomenological mechanism of the growth of these bodies is discussed. It is assumed such phenomena may take place in real systems during the formation of gas hydrates in water-in-oil dispersions.
AB - In this paper, we argue there is a new way of growing hydrate film other than two currently known ones, namely, a hydrate shell on the water surface without a surfactant and various hydrate dendrimers in the presence of surfactants. A previously unknown growth form of hydrate film occurs at the boundary between an aqueous solution of malonic acid and methane gas. These are gas-filled rounded bodies (like bubbles) of irregular shape which intergrow into the bulk aqueous phase. A possible phenomenological mechanism of the growth of these bodies is discussed. It is assumed such phenomena may take place in real systems during the formation of gas hydrates in water-in-oil dispersions.
UR - http://www.scopus.com/inward/record.url?scp=85081159296&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.9b01605
DO - 10.1021/acs.cgd.9b01605
M3 - Article
AN - SCOPUS:85081159296
VL - 20
SP - 1927
EP - 1934
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 3
ER -
ID: 23738370