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Insight into Hydrate Film Growth : Unusual Growth of Methane Hydrate Film at the Interface of Methane and the Aqueous Solution of Malonic Acid. / Stoporev, Andrey S.; Adamova, Tatyana P.; Manakov, Andrey Yu.

In: Crystal Growth and Design, Vol. 20, No. 3, 04.03.2020, p. 1927-1934.

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@article{0169e0896aef4a0ebe9bebe77345ef67,
title = "Insight into Hydrate Film Growth: Unusual Growth of Methane Hydrate Film at the Interface of Methane and the Aqueous Solution of Malonic Acid",
abstract = "In this paper, we argue there is a new way of growing hydrate film other than two currently known ones, namely, a hydrate shell on the water surface without a surfactant and various hydrate dendrimers in the presence of surfactants. A previously unknown growth form of hydrate film occurs at the boundary between an aqueous solution of malonic acid and methane gas. These are gas-filled rounded bodies (like bubbles) of irregular shape which intergrow into the bulk aqueous phase. A possible phenomenological mechanism of the growth of these bodies is discussed. It is assumed such phenomena may take place in real systems during the formation of gas hydrates in water-in-oil dispersions.",
author = "Stoporev, {Andrey S.} and Adamova, {Tatyana P.} and Manakov, {Andrey Yu}",
year = "2020",
month = mar,
day = "4",
doi = "10.1021/acs.cgd.9b01605",
language = "English",
volume = "20",
pages = "1927--1934",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Insight into Hydrate Film Growth

T2 - Unusual Growth of Methane Hydrate Film at the Interface of Methane and the Aqueous Solution of Malonic Acid

AU - Stoporev, Andrey S.

AU - Adamova, Tatyana P.

AU - Manakov, Andrey Yu

PY - 2020/3/4

Y1 - 2020/3/4

N2 - In this paper, we argue there is a new way of growing hydrate film other than two currently known ones, namely, a hydrate shell on the water surface without a surfactant and various hydrate dendrimers in the presence of surfactants. A previously unknown growth form of hydrate film occurs at the boundary between an aqueous solution of malonic acid and methane gas. These are gas-filled rounded bodies (like bubbles) of irregular shape which intergrow into the bulk aqueous phase. A possible phenomenological mechanism of the growth of these bodies is discussed. It is assumed such phenomena may take place in real systems during the formation of gas hydrates in water-in-oil dispersions.

AB - In this paper, we argue there is a new way of growing hydrate film other than two currently known ones, namely, a hydrate shell on the water surface without a surfactant and various hydrate dendrimers in the presence of surfactants. A previously unknown growth form of hydrate film occurs at the boundary between an aqueous solution of malonic acid and methane gas. These are gas-filled rounded bodies (like bubbles) of irregular shape which intergrow into the bulk aqueous phase. A possible phenomenological mechanism of the growth of these bodies is discussed. It is assumed such phenomena may take place in real systems during the formation of gas hydrates in water-in-oil dispersions.

UR - http://www.scopus.com/inward/record.url?scp=85081159296&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.9b01605

DO - 10.1021/acs.cgd.9b01605

M3 - Article

AN - SCOPUS:85081159296

VL - 20

SP - 1927

EP - 1934

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 3

ER -

ID: 23738370