Research output: Contribution to journal › Article › peer-review
Inhibition of organic mechanochemical synthesis by water vapor. / Tumanov, I. A.; Michalchuk, A. A.L.; Politov, A. A. et al.
In: Doklady Chemistry, Vol. 472, No. 1, 01.01.2017, p. 17-19.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Inhibition of organic mechanochemical synthesis by water vapor
AU - Tumanov, I. A.
AU - Michalchuk, A. A.L.
AU - Politov, A. A.
AU - Boldyreva, E. V.
AU - Boldyrev, V. V.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The effect of water on the mechanochemical synthesis in the glycine–malonic acid system has been studied in different types of devices. Comparative studies of the hygroscopicity of the reagents and products made it possible to rationalize the inhibiting effect of water vapor and the difference in the reaction course in impact and shear devices and in devices providing both action modes. The importance of control of ambient humidity for mechanochemical reactions on the laboratory and industrial scales has been illustrated.
AB - The effect of water on the mechanochemical synthesis in the glycine–malonic acid system has been studied in different types of devices. Comparative studies of the hygroscopicity of the reagents and products made it possible to rationalize the inhibiting effect of water vapor and the difference in the reaction course in impact and shear devices and in devices providing both action modes. The importance of control of ambient humidity for mechanochemical reactions on the laboratory and industrial scales has been illustrated.
UR - http://www.scopus.com/inward/record.url?scp=85017587898&partnerID=8YFLogxK
U2 - 10.1134/S0012500817010050
DO - 10.1134/S0012500817010050
M3 - Article
AN - SCOPUS:85017587898
VL - 472
SP - 17
EP - 19
JO - Doklady Chemistry
JF - Doklady Chemistry
SN - 0012-5008
IS - 1
ER -
ID: 9049642