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Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States. / Vorobyev, Vasily; Alferova, Nina I.; Emelyanov, Vyacheslav A.

In: Inorganic Chemistry, Vol. 58, No. 2, 22.01.2019, p. 1007-1011.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorobyev, V, Alferova, NI & Emelyanov, VA 2019, 'Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States', Inorganic Chemistry, vol. 58, no. 2, pp. 1007-1011. https://doi.org/10.1021/acs.inorgchem.8b03067

APA

Vorobyev, V., Alferova, N. I., & Emelyanov, V. A. (2019). Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States. Inorganic Chemistry, 58(2), 1007-1011. https://doi.org/10.1021/acs.inorgchem.8b03067

Vancouver

Vorobyev V, Alferova NI, Emelyanov VA. Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States. Inorganic Chemistry. 2019 Jan 22;58(2):1007-1011. doi: 10.1021/acs.inorgchem.8b03067

Author

Vorobyev, Vasily ; Alferova, Nina I. ; Emelyanov, Vyacheslav A. / Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States. In: Inorganic Chemistry. 2019 ; Vol. 58, No. 2. pp. 1007-1011.

BibTeX

@article{84f249adc56841998bb2b16914a4b93a,
title = "Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States",
abstract = "A novel method is proposed for studying the thermal decay of the oxygen-coordinated nitrosyl metastable states. Having examined 18 different ruthenium nitrosyl complexes, we observed that, upon photoinduced rotation from Ru-NO to Ru-ON coordination, the frequency of the nitrosyl valence bands shifts, on average, by 126 ± 15 cm-1. The thermal stability of the product Ru-ON state is qualitatively characterized (decay temperature, Arrhenius activation energy, and pre-exponential factor) using infrared absorption of the NO group, in comparison with the reference complex(es), which are all heated in the same KBr disk during temperature sweep.",
author = "Vasily Vorobyev and Alferova, {Nina I.} and Emelyanov, {Vyacheslav A.}",
year = "2019",
month = jan,
day = "22",
doi = "10.1021/acs.inorgchem.8b03067",
language = "English",
volume = "58",
pages = "1007--1011",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "2",

}

RIS

TY - JOUR

T1 - Infrared Detection with Temperature Sweep for Stability Determination of Ru-ON Metastable States

AU - Vorobyev, Vasily

AU - Alferova, Nina I.

AU - Emelyanov, Vyacheslav A.

PY - 2019/1/22

Y1 - 2019/1/22

N2 - A novel method is proposed for studying the thermal decay of the oxygen-coordinated nitrosyl metastable states. Having examined 18 different ruthenium nitrosyl complexes, we observed that, upon photoinduced rotation from Ru-NO to Ru-ON coordination, the frequency of the nitrosyl valence bands shifts, on average, by 126 ± 15 cm-1. The thermal stability of the product Ru-ON state is qualitatively characterized (decay temperature, Arrhenius activation energy, and pre-exponential factor) using infrared absorption of the NO group, in comparison with the reference complex(es), which are all heated in the same KBr disk during temperature sweep.

AB - A novel method is proposed for studying the thermal decay of the oxygen-coordinated nitrosyl metastable states. Having examined 18 different ruthenium nitrosyl complexes, we observed that, upon photoinduced rotation from Ru-NO to Ru-ON coordination, the frequency of the nitrosyl valence bands shifts, on average, by 126 ± 15 cm-1. The thermal stability of the product Ru-ON state is qualitatively characterized (decay temperature, Arrhenius activation energy, and pre-exponential factor) using infrared absorption of the NO group, in comparison with the reference complex(es), which are all heated in the same KBr disk during temperature sweep.

UR - http://www.scopus.com/inward/record.url?scp=85060301315&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b03067

DO - 10.1021/acs.inorgchem.8b03067

M3 - Article

C2 - 30608660

AN - SCOPUS:85060301315

VL - 58

SP - 1007

EP - 1011

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 2

ER -

ID: 18297105