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Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone. / Sankova, Natalya; Semeykina, Viktoriya; Selishchev, Dmitry et al.

In: Reaction Kinetics, Mechanisms and Catalysis, Vol. 127, No. 1, 15.06.2019, p. 53-67.

Research output: Contribution to journal › Article › peer-review

Harvard

Sankova, N, Semeykina, V, Selishchev, D, Glazneva, T, Parkhomchuk, E & Kolinko, P 2019, 'Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone', Reaction Kinetics, Mechanisms and Catalysis, vol. 127, no. 1, pp. 53-67. https://doi.org/10.1007/s11144-019-01539-3

APA

Sankova, N., Semeykina, V., Selishchev, D., Glazneva, T., Parkhomchuk, E., & Kolinko, P. (2019). Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone. Reaction Kinetics, Mechanisms and Catalysis, 127(1), 53-67. https://doi.org/10.1007/s11144-019-01539-3

Vancouver

Sankova N, Semeykina V, Selishchev D, Glazneva T, Parkhomchuk E, Kolinko P. Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone. Reaction Kinetics, Mechanisms and Catalysis. 2019 Jun 15;127(1):53-67. doi: 10.1007/s11144-019-01539-3

Author

Sankova, Natalya ; Semeykina, Viktoriya ; Selishchev, Dmitry et al. / Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone. In: Reaction Kinetics, Mechanisms and Catalysis. 2019 ; Vol. 127, No. 1. pp. 53-67.

BibTeX

@article{62f41842c267419ea36e37cb10597ace,
title = "Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone",
abstract = "Macroporous oxides are often prepared by template method with polymeric spheres, however, these polymeric spheres synthesized by emulsion polymerization using different initiators, most commonly contain S or/and N chemical residues. We have found that these template-originated impurities are not completely removed after thermal treatment of composites at ~ 500 °C, thus, influencing surface acidic properties and photocatalytic performance of the catalysts. The research is focused on the influence of different types of chemical residues left after incomplete polymer elimination on photocatalytic activity.",
keywords = "Gas-phase oxidation, Macroporous TiO, Photocatalysis, Template-assisted method, Visible light, CARBON, FILMS, DOPED TIO2, Macroporous TiO2, OPAL, FABRICATION, OXIDES",
author = "Natalya Sankova and Viktoriya Semeykina and Dmitry Selishchev and Tatyana Glazneva and Ekaterina Parkhomchuk and Pavel Kolinko",
note = "Publisher Copyright: {\textcopyright} 2019, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",
year = "2019",
month = jun,
day = "15",
doi = "10.1007/s11144-019-01539-3",
language = "English",
volume = "127",
pages = "53--67",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
issn = "1878-5190",
publisher = "Springer Netherlands",
number = "1",

}

RIS

TY - JOUR

T1 - Influence of polymeric template impurities on photocatalytic properties of bulk macroporous TiO2 under visible light irradiation in the gas phase oxidation of acetone

AU - Sankova, Natalya

AU - Semeykina, Viktoriya

AU - Selishchev, Dmitry

AU - Glazneva, Tatyana

AU - Parkhomchuk, Ekaterina

AU - Kolinko, Pavel

N1 - Publisher Copyright: © 2019, Akadémiai Kiadó, Budapest, Hungary.

PY - 2019/6/15

Y1 - 2019/6/15

N2 - Macroporous oxides are often prepared by template method with polymeric spheres, however, these polymeric spheres synthesized by emulsion polymerization using different initiators, most commonly contain S or/and N chemical residues. We have found that these template-originated impurities are not completely removed after thermal treatment of composites at ~ 500 °C, thus, influencing surface acidic properties and photocatalytic performance of the catalysts. The research is focused on the influence of different types of chemical residues left after incomplete polymer elimination on photocatalytic activity.

AB - Macroporous oxides are often prepared by template method with polymeric spheres, however, these polymeric spheres synthesized by emulsion polymerization using different initiators, most commonly contain S or/and N chemical residues. We have found that these template-originated impurities are not completely removed after thermal treatment of composites at ~ 500 °C, thus, influencing surface acidic properties and photocatalytic performance of the catalysts. The research is focused on the influence of different types of chemical residues left after incomplete polymer elimination on photocatalytic activity.

KW - Gas-phase oxidation

KW - Macroporous TiO

KW - Photocatalysis

KW - Template-assisted method

KW - Visible light

KW - CARBON

KW - FILMS

KW - DOPED TIO2

KW - Macroporous TiO2

KW - OPAL

KW - FABRICATION

KW - OXIDES

UR - http://www.scopus.com/inward/record.url?scp=85060814569&partnerID=8YFLogxK

U2 - 10.1007/s11144-019-01539-3

DO - 10.1007/s11144-019-01539-3

M3 - Article

AN - SCOPUS:85060814569

VL - 127

SP - 53

EP - 67

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

SN - 1878-5190

IS - 1

ER -

ID: 18489260