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In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis. / Lagunova, V. I.; Filatov, E. Yu; Plyusnin, P. E. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 65, No. 10, 01.10.2020, p. 1566-1570.

Research output: Contribution to journal › Article › peer-review

Harvard

Lagunova, VI, Filatov, EY, Plyusnin, PE & Korenev, SV 2020, 'In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis', Russian Journal of Inorganic Chemistry, vol. 65, no. 10, pp. 1566-1570. https://doi.org/10.1134/S0036023620100150

APA

Lagunova, V. I., Filatov, E. Y., Plyusnin, P. E., & Korenev, S. V. (2020). In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis. Russian Journal of Inorganic Chemistry, 65(10), 1566-1570. https://doi.org/10.1134/S0036023620100150

Vancouver

Lagunova VI, Filatov EY, Plyusnin PE, Korenev SV. In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis. Russian Journal of Inorganic Chemistry. 2020 Oct 1;65(10):1566-1570. doi: 10.1134/S0036023620100150

Author

Lagunova, V. I. ; Filatov, E. Yu ; Plyusnin, P. E. et al. / In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis. In: Russian Journal of Inorganic Chemistry. 2020 ; Vol. 65, No. 10. pp. 1566-1570.

BibTeX

@article{e71e5471d6c74dd09de797c12e36ca8b,
title = "In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis",
abstract = "Comparative analysis have shown that the thermolysis of complex salt [Pt(NH3)4]CrO4 in synthetic air atmosphere under in situ and ex situ conditions proceeds in different routes. In contrast to in situ experiment, ex situ decomposition leads to formation of intermediate PtCrO2 phase with delafossite structure. Final decomposition product is a homogeneous mixture of platinum metal and chromium(III) oxide. Complex [Pt(NH3)4]CrO4 has been shown to have negative volumetric coefficient of thermal expansion in the temperature range 30–200°C (–1.9 × 10–5 1/K). Ex situ experiments have shown stability of the complex on consecutive cyclic heating to 200°C and cooling to ambient temperature",
keywords = "in situ X-ray diffraction, nanoparticles, negative volumetric coefficient of thermal expansion, platinum, thermal analysis, OXIDATION, PROFILE, DOUBLE COMPLEX SALTS, CO, PRECURSORS, CATALYSTS, FE",
author = "Lagunova, {V. I.} and Filatov, {E. Yu} and Plyusnin, {P. E.} and Korenev, {S. V.}",
year = "2020",
month = oct,
day = "1",
doi = "10.1134/S0036023620100150",
language = "English",
volume = "65",
pages = "1566--1570",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - In Situ and Ex Situ Studies of Tetrammineplatinum(II) Chromate Thermolysis

AU - Lagunova, V. I.

AU - Filatov, E. Yu

AU - Plyusnin, P. E.

AU - Korenev, S. V.

PY - 2020/10/1

Y1 - 2020/10/1

N2 - Comparative analysis have shown that the thermolysis of complex salt [Pt(NH3)4]CrO4 in synthetic air atmosphere under in situ and ex situ conditions proceeds in different routes. In contrast to in situ experiment, ex situ decomposition leads to formation of intermediate PtCrO2 phase with delafossite structure. Final decomposition product is a homogeneous mixture of platinum metal and chromium(III) oxide. Complex [Pt(NH3)4]CrO4 has been shown to have negative volumetric coefficient of thermal expansion in the temperature range 30–200°C (–1.9 × 10–5 1/K). Ex situ experiments have shown stability of the complex on consecutive cyclic heating to 200°C and cooling to ambient temperature

AB - Comparative analysis have shown that the thermolysis of complex salt [Pt(NH3)4]CrO4 in synthetic air atmosphere under in situ and ex situ conditions proceeds in different routes. In contrast to in situ experiment, ex situ decomposition leads to formation of intermediate PtCrO2 phase with delafossite structure. Final decomposition product is a homogeneous mixture of platinum metal and chromium(III) oxide. Complex [Pt(NH3)4]CrO4 has been shown to have negative volumetric coefficient of thermal expansion in the temperature range 30–200°C (–1.9 × 10–5 1/K). Ex situ experiments have shown stability of the complex on consecutive cyclic heating to 200°C and cooling to ambient temperature

KW - in situ X-ray diffraction

KW - nanoparticles

KW - negative volumetric coefficient of thermal expansion

KW - platinum

KW - thermal analysis

KW - OXIDATION

KW - PROFILE

KW - DOUBLE COMPLEX SALTS

KW - CO

KW - PRECURSORS

KW - CATALYSTS

KW - FE

UR - http://www.scopus.com/inward/record.url?scp=85094846264&partnerID=8YFLogxK

U2 - 10.1134/S0036023620100150

DO - 10.1134/S0036023620100150

M3 - Article

AN - SCOPUS:85094846264

VL - 65

SP - 1566

EP - 1570

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 10

ER -

ID: 25851175